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Control of Structural Ordering in Crystalline Lamellar Aluminophosphates with Periodicity from 51 to 62 Å Pingyun Feng, Xianhui Bu, and Galen D. Stucky pp 2 - 3; DOI: 10.1021/ic991026y |
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Solid-State 25Mg NMR Study of Inner-Sphere Mg2+ Binding Complexes Simon Sham and Gang Wu pp 4 - 5; DOI: 10.1021/ic991060c |
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Chemistry of the Rhenium-Azopyridine Family: An Oxo Parent and Derivatives Thereof Including a Novel Oxo-Imido Dimer Sangeeta Banerjee, Sibaprasad Bhattacharyya, Bimal Kumar Dirghangi, Mahua Menon, and Animesh Chakravorty pp 6 - 13; DOI: 10.1021/ic990465u |
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Metal-Assisted Unusual Hydroxylation at the Carbon Atom of the Triazine Ring in Dinuclear Ruthenium(II) and Osmium(II) Complexes Bridged by 2,4,6-Tris(2-pyridyl)-1,3,5-triazine: Synthesis, Structural Characterization, Stereochemistry, and Electrochemical Studies Parimal Paul, Beena Tyagi, Anvarhusen K. Bilakhiya, Parthasarathi Dastidar, and Eringathodi Suresh pp 14 - 22; DOI: 10.1021/ic990938x |
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Metal Alkoxides as Versatile Precursors for Group 4 Phosphonates: Synthesis and X-ray Structure of a Novel Organosoluble Zirconium Phosphonate Debashis Chakraborty, Vadapalli Chandrasekhar, Manish Bhattacharjee, Ralph Krätzner, Herbert W. Roesky, Mathias Noltemeyer, and Hans-Georg Schmidt pp 23 - 26; DOI: 10.1021/ic9907361 |
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Synthesis and Characterization of 8-(Dimethylamino)-1-naphthyl Derivatives of Aluminum, Gallium, and Indium Gregory S. Hair, Scott L. Battle, Andreas Decken, Alan H. Cowley, and Richard A. Jones pp 27 - 31; DOI: 10.1021/ic990707q |
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Carbidohexarhenate Cluster Cores Bicapped by Mercury with Acetate or Thiolate Ligands Udo Brand and John R. Shapley pp 32 - 36; DOI: 10.1021/ic990722v |
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Structure, Bonding, and Dipole Moment of (CH3)3N-SO3. A Microwave Study D. L. Fiacco, A. Toro, and K. R. Leopold pp 37 - 43; DOI: 10.1021/ic990925j |
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Redox Pathways in DNA Oxidation: Kinetic Studies of Guanine and Sugar Oxidation by Para-Substituted Derivatives of Oxoruthenium(IV) Brian T. Farrer and H. Holden Thorp pp 44 - 49; DOI: 10.1021/ic990833u |
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Influence of DNA on the Rate of Ligand Substitution in Platinum(II) Terpyridine Complexes Matteo Cusumano, Maria Letizia Di Pietro, Antonino Giannetto, and Francesco Romano pp 50 - 55; DOI: 10.1021/ic990747u |
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High-Pressure Synthesis of a New Silicon Clathrate Superconductor, Ba8Si46 Shoji Yamanaka, Eiji Enishi, Hiroshi Fukuoka, and Masahiro Yasukawa pp 56 - 58; DOI: 10.1021/ic990778p |
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Syntheses and Spectroscopic and Structural Characterization of Molybdenum(VI) Citrato Monomeric Raceme and Dimer, K4[MoO3(cit)]·2H2O and K4[(MoO2)2O(Hcit)2]·4H2O Zhao-Hui Zhou, Hui-Lin Wan, and Khi-Rui Tsai pp 59 - 64; DOI: 10.1021/ic990042s |
Magnetic Properties of Diruthenium(II,III) Carboxylate Compounds. Crystal Structures of Ru2Cl( -O2CCH=CHCH=CHMe)4 and Ru2Cl(-O2CCH2OMe)4M. C. Barral, R. Jiménez-Aparicio, D. Pérez-Quintanilla, J. L. Priego, E. C. Royer, M. R. Torres, and F. A. Urbanos pp 65 - 70; DOI: 10.1021/ic9907462 |
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One-Pot Synthesis and Characterization of a Chromophore-Donor-Acceptor Assembly Kimberly A. Maxwell, Milan Sykora, Joseph M. DeSimone, and Thomas J. Meyer pp 71 - 75; DOI: 10.1021/ic990512i |
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Luminescent Ruthenium(II) Bipyridyl-Phosphonic Acid Complexes: pH Dependent Photophysical Behavior and Quenching with Divalent Metal Ions Marco Montalti, Seema Wadhwa, Won Y. Kim, Rachael A. Kipp, and Russell H. Schmehl pp 76 - 84; DOI: 10.1021/ic991143t |
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Oligomerization and Oxide Formation in Bismuth Aryl Alkoxides: Synthesis and Characterization of Bi4(4-O)(-OC6F5)6{3-OBi(-OC6F5)3}2(C6H5CH3), Bi8(4-O)2(3-O)2(-OC6F5)16, Bi6(3-O)4(3-OC6F5){3-OBi(OC6F5)4}3, NaBi4(3-O)2(OC6F5)9(THF)2, and Na2Bi4(3-O)2(OC6F5)10(THF)2 Kenton H. Whitmire, Silke Hoppe, Orson Sydora, Jennifer L. Jolas, and Carolyn M. Jones pp 85 - 97; DOI: 10.1021/ic990431m |
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La48Br81Os8: Isolated Clusters in an Unusual Superstructure with Significantly Greater Intercluster Bonding Seung-Tae Hong, Laura M. Hoistad, and John D. Corbett pp 98 - 104; DOI: 10.1021/ic990692w |
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Synthesis and Characterization of Tris(bipyridyl)ruthenium(II)-Modified Mono-, Di-, and Trinuclear Manganese Complexes as Electron-Transfer Models for Photosystem II Dirk Burdinski, Eberhard Bothe, and Karl Wieghardt pp 105 - 116; DOI: 10.1021/ic990755a |
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Novel and Versatile Reactions of Trifluoroamine Oxide: A New Route to Polyfluorinated Ethers O. D. Gupta, Robert L. Kirchmeier, and Jean'ne M. Shreeve pp 117 - 120; DOI: 10.1021/ic9911567 |
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Gold(I) and Silver(I) Metallocryptates Based on 2,9-Bis(diphenylphosphino)-1,8-naphthyridine Vincent J. Catalano, Heidi M. Kar, and Byron L. Bennett pp 121 - 127; DOI: 10.1021/ic9908827 |
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Comparative Spectroscopic and Electrochemical Properties of Bis(octakis(dodecylthio)naphthalocyaninato)europium(III) and Bis(tetra-tert-butylnaphthalocyaninato)europium(III) Complexes Tebello Nyokong, Fumio Furuya, Nagao Kobayashi, Daming Du, Wei Liu, and Jianzhuang Jiang pp 128 - 135; DOI: 10.1021/ic990483b |
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Site-Specific Vanadates Co4Fe3.33(VO4)6 and Mn3Fe4(VO4)6 Xiandong Wang, Douglas A. Vander Griend, Charlotte L. Stern, and Kenneth R. Poeppelmeier pp 136 - 140; DOI: 10.1021/ic9909274 |
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Binuclear 1,2,4,5-Tetraimino-3,6-diketocyclohexane Bis[bis(Bipyridine)ruthenium(II)] Redox Series Hitoshi Masui, Assunta L. Freda, Michael C. Zerner, and A. B. P. Lever pp 141 - 152; DOI: 10.1021/ic980826q |
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Stereochemical Activity of the Metal-Centered Lone Electron Pair in Group 14 Metallocenes. Crystal Structure of the Linear Sandwich Complex [C5(iPr)3H2]2Pb David J. Burkey, Timothy P. Hanusa, and John C. Huffman pp 153 - 155; DOI: 10.1021/ic9905401 |
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Hyperfine Tensors of [Bis(maleonitriledithioleato)nickel]- Robert G. Hayes pp 156 - 158; DOI: 10.1021/ic9908726 |
Issue 2
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Direct Determination of the Single-Ion Anisotropy in a One-Dimensional Magnetic System by High-Field EPR Spectroscopy; Synthesis, EPR, and X-ray Structure of NixZn1-x(C2O4)(dmiz)2 [x = 0.07] Luca A. Pardi, Alia K. Hassan, Frans B. Hulsbergen, Jan Reedijk, Anthony L. Spek, and Louis-Claude Brunel pp 159 - 164; DOI: 10.1021/ic990167x |
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Influence of Anionic Ligands (X) on the Nature and Magnetic Properties of Dinuclear LCuGdX3·nH2O Complexes (LH2 Standing for Tetradentate Schiff Base Ligands Deriving from 2-Hydroxy-3-methoxybenzaldehyde and X Being Cl, N3C2, and CF3COO) Jean-Pierre Costes, Françoise Dahan, and Arnaud Dupuis pp 165 - 168; DOI: 10.1021/ic990865h |
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Is Ferromagnetism an Intrinsic Property of the CuII/GdIII Couple? 1. Structures and Magnetic Properties of Two Novel Dinuclear Complexes with a -Phenolato--Oximato (Cu,Gd) Core Jean-Pierre Costes, Françoise Dahan, Arnaud Dupuis, and Jean-Pierre Laurent pp 169 - 173; DOI: 10.1021/ic990864p |
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In Pursuit of the Molybdenum(III) Tris(thiolate) Fragment: Unusual Structure of a Dimolybdenum -Nitrido Complex Theodor Agapie, Aaron L. Odom, and Christopher C. Cummins pp 174 - 179; DOI: 10.1021/ic9904891 |
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Substitution and Hydrogenation Reactions on Rhodium(I)-Ethylene Complexes of the Hydrotris(pyrazolyl)borate Ligands Tp' (Tp' = Tp, TpMe2) M. Carmen Nicasio, Margarita Paneque, Pedro J. Pérez, Antonio Pizzano, Manuel L. Poveda, Luis Rey, Sabine Sirol, Soraya Taboada, Marianela Trujillo, Angeles Monge, Caridad Ruiz, and Ernesto Carmona pp 180 - 188; DOI: 10.1021/ic990419u |
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Tuning Metal-to-Metal Charge Transfer of Mixed-Valence Complexes Containing Ferrocenylpyridine and Rutheniumammines via Solvent Donicity and Substituent Effects Yuan Jang Chen, Ching-Hong Kao, She Jing Lin, Chih-Cheng Tai, and Keh Shin Kwan pp 189 - 194; DOI: 10.1021/ic990839j |
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Azo Anion Radical Complexes of Osmium and Related Nonradical Species Kausikisankar Pramanik, Maya Shivakumar, Prasanta Ghosh, and Animesh Chakravorty pp 195 - 199; DOI: 10.1021/ic9908322 |
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Preparations and Electrochemical Properties of Pyrazine-Bridged Ruthenium-Binuclear Complexes Exhibiting Molecular Hysteresis Atsuko Tomita and Mitsuru Sano pp 200 - 205; DOI: 10.1021/ic9814219 |
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Stereoselective Formation of Seven-Coordinate Titanium(IV) Monomer and Dimer Complexes of Ethylenebis(o-hydroxyphenyl)glycine Maolin Guo, Hongzhe Sun, Shailja Bihari, John A. Parkinson, Robert O. Gould, Simon Parsons, and Peter J. Sadler pp 206 - 215; DOI: 10.1021/ic990669a |
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Iminoacylation. 3. Formation of Platinum(IV)-Based Metallaligands Due to Facile One-End Addition of vic-Dioximes to Coordinated Organonitriles1-3 Vadim Yu. Kukushkin, Tatyana B. Pakhomova, Nadezhda A. Bokach, Gabriele Wagner, Maxim L. Kuznetsov, Markus Galanski, and Armando J. L. Pombeiro pp 216 - 225; DOI: 10.1021/ic990552m |
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A Cu(II)-Mediated C-H Oxygenation of Sterically Hindered Tripyridine Ligands To Form Triangular Cu(II)3 Complexes Masahito Kodera, Yoshimitsu Tachi, Toshio Kita, Hiromu Kobushi, Yoshinori Sumi, Koji Kano, Motoo Shiro, Masayuki Koikawa, Tadashi Tokii, Masaaki Ohba, and Hisashi Okawa pp 226 - 234; DOI: 10.1021/ic990331g |
Polynuclear Magnesium and Magnesium-Titanium Species. Syntheses and Crystal Structures of [Mg4(3, 2-ddbfo)2(,2-ddbfo)2(,1-ddbfo)2(1-ddbfo)2], [Mg4(3-OMe)2(,2-ddbfo)2(,1-ddbfo)2(1-ddbfo)2(CH3OH)5], and [Mg4(3,2-thffo)2(,2-thffo)2(,1-thffo)2{-OTi(DIPP)3}2] AggregatesPiotr Sobota, Józef Utko, Katarzyna Sztajnowska, Jolanta Ejfler, and Lucjan B. Jerzykiewicz pp 235 - 239; DOI: 10.1021/ic990542l |
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Synthesis, Characterization, and Substitution Chemistry of [Bu4N]2[W6Cl8(OSO2CF3)6]. A Versatile Precursor for Axially Substituted Clusters Containing the {W6Cl8}4+ Core Charles S. Weinert, Charlotte L. Stern, and Duward F. Shriver pp 240 - 246; DOI: 10.1021/ic990791+ |
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Pentasulfide S52- as the First Tridentate Chelating Ligand in Ru(P(OE)3)3S5(E = Me and Et) Md. Munkir Hossain and Kazuko Matsumoto pp 247 - 250; DOI: 10.1021/ic990764j |
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Optical Spectroscopy and Density Functional Calculations of Chromium(V)-Doped YVO4 and YPO4: Influence of the Second Coordination Sphere M. F. Hazenkamp, A. C. Stückl, E. Cavalli, and H. U. Güdel pp 251 - 254; DOI: 10.1021/ic990949q |
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Luminescent Mononuclear and Binuclear Cyclometalated Palladium(II) Complexes of 6-Phenyl-2,2'-bipyridines: Spectroscopic and Structural Comparisons with Platinum(II) Analogues Siu-Wai Lai, Tsz-Chun Cheung, Michael C. W. Chan, Kung-Kai Cheung, Shie-Ming Peng, and Chi-Ming Che pp 255 - 262; DOI: 10.1021/ic991089g |
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Synthesis and Structures of Bis(dithiolene)molybdenum Complexes Related to the Active Sites of the DMSO Reductase Enzyme Family Booyong S. Lim, James P. Donahue, and R. H. Holm pp 263 - 273; DOI: 10.1021/ic9908672 |
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Electrochemical Properties of Vanadium(III,IV,V)-Salen Complexes in Acetonitrile. Four-Electron Reduction of O2 by V(III)-Salen Zenghe Liu and Fred C. Anson pp 274 - 280; DOI: 10.1021/ic990958z |
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High-Frequency EPR Study of the Ferrous Ion in the Reduced Rubredoxin Model [Fe(SPh)4]2- Michael J. Knapp, J. Krzystek, Louis-Claude Brunel, and David N. Hendrickson pp 281 - 288; DOI: 10.1021/ic9910054 |
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Catalytic Two-Electron Reductions of N2O and N3- by Myoglobin in Surfactant Films Mekki Bayachou, Lhadi Elkbir, and Patrick J. Farmer pp 289 - 293; DOI: 10.1021/ic990672u |
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Understanding the Orientation and Dynamic Motion of Planar Heterocyclic N-Donor Ligands by Exploiting the Symmetry Properties of Mixed-Ligand -Oxorhenium(V) Dinuclear Complexes [ReOCl2(L)(L')]-O-[ReOCl2(L)(L')]: A Combined X-ray Structural and Dynamic NMR Investigation Enzo Alessio, Ennio Zangrando, Elisabetta Iengo, Michela Macchi, Patricia A. Marzilli, and Luigi G. Marzilli pp 294 - 303; DOI: 10.1021/ic990858t |
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Mechanism of CO Exchange on cis-[M(CO)2X2]- Complexes (M = Rh, Ir; X = Cl, Br, or I) Raphaël Churlaud, Urban Frey, François Metz, and André E. Merbach pp 304 - 307; DOI: 10.1021/ic9910763 |
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Novel Synthetic Routes to Several New, Differentially Substituted Ruthenium Tris(4,4'-disubstituted-2,2-bipyridine) Complexes Dusan Hesek, Yoshihisa Inoue, Simon R. L. Everitt, Hitoshi Ishida, Mieko Kunieda, and Michael G. B. Drew pp 308 - 316; DOI: 10.1021/ic990840i |
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Diastereoselective Preparation and Characterization of Ruthenium Bis(bipyridine) Sulfoxide Complexes Dusan Hesek, Yoshihisa Inoue, Simon R. L. Everitt, Hitoshi Ishida, Mieko Kunieda, and Michael G. B. Drew pp 317 - 324; DOI: 10.1021/ic991059d |
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Charge Effects on Oxygen Atom Transfer Sean B. Seymore and Seth N. Brown pp 325 - 332; DOI: 10.1021/ic990851b |
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Synthesis, Characterization, and Chiral Properties of CoIII2AgI3 Pentanuclear, CoIII4ZnII4 Octanuclear, and CoIII Mononuclear Complexes with Aza-Capped Hexadentate-N3S3 Thiolate Ligands: Crystal Structures of [Ag3{Co(L)}2][PF6]3 and [Zn4O{Co(L)}4][PF6]6 (L = N(CH2NHCH2CH2S-)3) Keiji Tokuda, Ken-ichi Okamoto, and Takumi Konno pp 333 - 339; DOI: 10.1021/ic9906407 |
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Neocuproine-Extended Porphyrin Coordination Complexes. 2. Spectroscopic Properties of the Metalloporphyrin Derivatives and Investigations into the HOMO Ordering Tommaso A. Vannelli and Timothy B. Karpishin pp 340 - 347; DOI: 10.1021/ic990914q |
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Toward Ligand Identification within a CCHHC Zinc-Binding Domain from the NZF/MyT1 Family Cheryl A. Blasie and Jeremy M. Berg pp 348 - 351; DOI: 10.1021/ic990913y |
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Electron Transfer. 140. Reactions of Riboflavin with Metal Center Reductants Shawn Swavey and Edwin S. Gould pp 352 - 356; DOI: 10.1021/ic990392e |
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Co(III) Complexes with Coordinated Carboxamido Nitrogens and Thiolato Sulfurs as Models for Co-Containing Nitrile Hydratase and Their Conversion to the Corresponding Sulfinato Species Laurie A. Tyler, Juan C. Noveron, Marilyn M. Olmstead, and Pradip K. Mascharak pp 357 - 362; DOI: 10.1021/ic990794m |
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Addition of Ammonia to AlH3 and BH3. Why Does Only Aluminum Form 2:1 Adducts? Margaret Czerw, Alan S. Goldman, and Karsten Krogh-Jespersen pp 363 - 369; DOI: 10.1021/ic990961i |
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Electronic Absorption and MCD Spectra for Pt(AuPPh3)82+ and Au(AuPPh3)83+ Cluster Complexes in Poly(methyl methacrylate) Thin Films at 295 and 10 K W. Roy Mason pp 370 - 374; DOI: 10.1021/ic991088o |
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A Novel Synthesis of Hexakis(trifluoromethyl)cyclotriphosphazene. Single-Crystal X-ray Structures of N3P3(CF3)6 and N3P3F6 Rajendra Prasad Singh, Ashwani Vij, Robert L. Kirchmeier, and Jean'ne M. Shreeve pp 375 - 377; DOI: 10.1021/ic9909781 |
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Oxidative Azavinylidene Formation in the Reaction of 1,3-Diphenylisobenzofuran with Osmium Nitride Complexes Seth N. Brown pp 378 - 381; DOI: 10.1021/ic990815c |
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Comparing the Isoelectronic Complexes [RuTp(CH3CN)3]PF6 (Tp = Hydridotris(pyrazolyl)borate) and [RuCp(CH3CN)3]PF6. Structure and Acetonitrile Exchange Kinetics Eva Rüba, Walter Simanko, Kurt Mereiter, Roland Schmid, and Karl Kirchner pp 382 - 384; DOI: 10.1021/ic991013k |
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Redox Chemistry of (1,4,7-Tris(4-tert-butyl-2-mercaptobenzyl)-1,4,7-triazacyclononane)ruthenium(III), [RuIIIL]: Synthesis and Characterization of [RuII2(L-L)](BPh4)4·10CH3CN and [LRuRuRuL](PF6)2·H2O. Belén Albela, Eberhard Bothe, Oliver Brosch,KatsuraMochizuki, Thomas Weyhermüller, Karl Wieg-hardt, and Michael G. B. Drew pp 384 - 384; DOI: 10.1021/ic991357a |
Issue 3
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Disproportionation and Nuclease Activity of Bis[2-ethyl-2-hydroxybutanoato(2-)]oxochromate(V) in Neutral Aqueous Solutions Aviva Levina, Peter A. Lay, and Nicholas E. Dixon pp 385 - 395; DOI: 10.1021/ic990729c |
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New Alternating Ferro- and Antiferromagnetic One-Dimensional Complexes. Synthesis, Characterization, Crystal Structure, and Magnetic Properties of [M(4,4'-dimethylbipyridine)(N3)2]n [M = Cu(II), Mn(II), Ni(II), Fe(II)] Hao-Yu Shen, Wei-Ming Bu, En-Qing Gao, Dai-Zheng Liao, Zong-Hui Jiang, Shi-Ping Yan, and Geng-Lin Wang pp 396 - 400; DOI: 10.1021/ic990338y |
Crystal Supramolecular Motifs: Columns of Embracing Ph3PMe+ or Ph3PCl+ Cations Controlling Formation of [Cu3X82- %@be@%1%@rsf@%%@sxx@%%@mx@%Susan Lorenzo, Caitlin Horn, Donald Craig, Marcia Scudder, and Ian Dance pp 401 - 405; DOI: 10.1021/ic990803r |
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Chemistry and Insulin-Mimetic Properties of Bis(acetylacetonate)oxovanadium(IV) and Derivatives Sean S. Amin, Kirk Cryer, Boyan Zhang, Subodh K. Dutta, Sandra S. Eaton, Oren P. Anderson, Susie M. Miller, Benedicte A. Reul, Sonia M. Brichard, and Debbie C. Crans pp 406 - 416; DOI: 10.1021/ic9905897 |
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Heterometallic Polymeric Clusters Containing Tetraselenotungstate Anion: One-Dimensional Helical Chain {[La(Me2SO)8][(-WSe4)3Ag3]}n and Cyanide-Bridged Three-Dimensional Cross-Framework {[Et4N]2[(4-WSe4)Cu4(CN)4]}n Qian-Feng Zhang, Wa-Hung Leung, Xin-Quan Xin, and Hoong-Kun Fun pp 417 - 426; DOI: 10.1021/ic990780g |
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Ligand to Ligand Charge Transfer in (Hydrotris(pyrazolyl)borato)(triphenylarsine)copper(I) Ana Acosta, Jeffrey I. Zink, and Jinwoo Cheon pp 427 - 432; DOI: 10.1021/ic9908773 |
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In-Situ Gas-Phase Luminescence and Time-of-Flight Mass Spectroscopic Detection of Photofragments during Photochemical Synthesis of Copper Particles from Bis(tert-butylacetoacetato)copper Jinwoo Cheon and Jeffrey I. Zink pp 433 - 436; DOI: 10.1021/ic990962a |
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Vibronic Coupling in Dicyano-Complex-Bridged Mixed-Valence Complexes. Relaxation of Vibronic Constraints in Systems with Degenerate Bridging-Ligand and Electron-Transfer Excited States Ariel V. Macatangay and John F. Endicott pp 437 - 446; DOI: 10.1021/ic9900713 |
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Platinum Diimine Bis(acetylide) Complexes: Synthesis, Characterization, and Luminescence Properties Muriel Hissler, William B. Connick, David K. Geiger, James E. McGarrah, Donald Lipa, Rene J. Lachicotte, and Richard Eisenberg pp 447 - 457; DOI: 10.1021/ic991250n |
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Synthesis and Magnetic and Transport Properties of Sr6V9S22O2: "AM2S5" Phases Revisited J. B. Litteer, B.-H. Chen, James C. Fettinger, B. W. Eichhorn, H. L. Ju, and R. L. Greene pp 458 - 462; DOI: 10.1021/ic990356f |
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Synthesis and Characterization of New 19-Vertex Macropolyhedral Boron Hydrides Joel A. Dopke, Douglas R. Powell, and Donald F. Gaines pp 463 - 467; DOI: 10.1021/ic990896c |
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Time-Resolved Electron Spin Resonance of Gallium and Germanium Porphyrins in the Excited Triplet State Kazuyuki Ishii, Satoko Abiko, and Nagao Kobayashi pp 468 - 472; DOI: 10.1021/ic990783t |
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Solution 31P and 113Cd NMR Studies of Phosphine Adducts of Monomeric Cadmium (Bisphenoxide) Complexes and the Solid-State Structures of (2,6-Di-tert-butylphenoxide)2Cd(PCy3) and (2,6-Di-tert-butylphenoxide)2Cd(PMe3)2 Donald J. Darensbourg, Patrick Rainey, David L. Larkins, and Joseph H. Reibenspies pp 473 - 479; DOI: 10.1021/ic991008g |
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Heterobimetallics of Nickel-Iron Dinitrosyl: Electronic Control by Chelate and Diatomic Ligands Wen-Feng Liaw, Chao-Yi Chiang, Gene-Hsiang Lee, Shie-Ming Peng, Chia-Huei Lai, and Marcetta Y. Darensbourg pp 480 - 484; DOI: 10.1021/ic990631y |
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Picosecond Dynamics of Photoinduced Interligand Electron Transfer in [Re(MQ+)(CO)3(dmb)]2+ (dmb = 4,4'-Dimethyl-2,2'-bipyridine, MQ+ = N-Methyl-4,4'-bipyridinium) Davina J. Liard and Antonín Vl  ek, Jr.pp 485 - 490; DOI: 10.1021/ic990770f |
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Magnetic Exchange in [Mn2(-O)3(tmtacn)2]2+: Metal-Metal Bonding or Superexchange? Christopher D. Delfs and Robert Stranger pp 491 - 495; DOI: 10.1021/ic990790h |
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Homotrinuclear Lanthanide(III) Arrays: Assembly of and Conversion from Mononuclear and Dinuclear Units Ika A. Setyawati, Shuang Liu, Steven J. Rettig, and Chris Orvig pp 496 - 507; DOI: 10.1021/ic991170j |
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Coaggregation of Paramagnetic d- and f-Block Metal Ions with a Podand-Framework Amine Phenol Ligand Zhiqiang Xu, Paul W. Read, David E. Hibbs, Michael B. Hursthouse, K. M. Abdul Malik, Brian O. Patrick, Steven J. Rettig, Mehran Seid, David A. Summers, Maren Pink, Robert C. Thompson, and Chris Orvig pp 508 - 516; DOI: 10.1021/ic991171b |
A Density Functional Study of Open-Shell Cyclopentadienyl-Molybdenum(II) Complexes. A Comparison of Stabilizing Factors: Spin-Pairing, Mo-X  Bonding, and Release of Steric PressureIvo Cacelli, Rinaldo Poli, Elsje Alessandra Quadrelli, Antonio Rizzo, and Kevin M. Smith pp 517 - 524; DOI: 10.1021/ic990875i |
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Analogues for the Molybdenum Center of Sulfite Oxidase: Oxomolybdenum(V) Complexes with Three Thiolate Sulfur Donor Atoms M. L. Mader, Michael D. Carducci, and John H. Enemark pp 525 - 531; DOI: 10.1021/ic990768o |
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Electronic Effects in Transition Metal Porphyrins. 10. Effect of Ortho Substituents on the Temperature Dependence of the NMR Spectra of a Series of Spin-Admixed Perchloratoiron(III) Tetrakis(2,6- or 2,4,6-phenyl substituted)porphyrinates Marlys J. M. Nesset, Sheng Cai, Tatjana Kh. Shokhireva, Nikolai V. Shokhirev, Simone E. Jacobson, K. Jayaraj, Avram Gold, and F. Ann Walker pp 532 - 540; DOI: 10.1021/ic9907866 |
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Wavelength-Dependent Photochemistry in Cr(CNPh)6: A Study of Photosubstitution and Photoinduced Electron Transfer Using Time-Resolved Spectroscopy Lawton E. Shaw and Cooper H. Langford pp 541 - 546; DOI: 10.1021/ic9905650 |
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The Elusive Structures of Pentakis[(triphenylphosphine)gold]ammonium(2+) Bis[tetrafluoroborate(1-)] Annette Schier, Andreas Grohmann, José M. López-de-Luzuriaga, and Hubert Schmidbaur pp 547 - 554; DOI: 10.1021/ic991102x |
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Reduced Zirconium Halide Clusters in Aqueous Solution Xiaobing Xie and Timothy Hughbanks pp 555 - 561; DOI: 10.1021/ic9908423 |
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Coordination Chemistry of Verdazyl Radicals: Group 12 Metal (Zn, Cd, Hg) Complexes of 1,4,5,6-Tetrahydro-2,4-dimethyl-6-(2'-pyridyl)-1,2,4,5-tetrazin-3(2H)-one (pvdH3) and 1,5-Dimethyl-3-(2'-pyridyl)-6-oxoverdazyl (pvd) David J. R. Brook, Spring Fornell, Jonathan E. Stevens, Bruce Noll, Tad H. Koch, and Wolfgang Eisfeld pp 562 - 567; DOI: 10.1021/ic9903883 |
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A New Type of Hexaosmium Boride Cluster, H3Os6(CO)16B, That Does Not Conform to Electron Counting Rules Jang-Hoon Chung, Glenn Jordan, Edward A. Meyers, and Sheldon G. Shore pp 568 - 572; DOI: 10.1021/ic991113q |
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Binding Properties of Octaaminocryptands Françoise Arnaud-Neu, Saowarux Fuangswasdi, Beatrice Maubert, Jane Nelson, and Vickie McKee pp 573 - 579; DOI: 10.1021/ic9905704 |
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Molecular Structure of an Fe(IV) Species: {[Fe(TTP)]2N}SbCl6 Ming Li, Maoyu Shang, Noelle Ehlinger, Charles E. Schulz, and W. Robert Scheidt pp 580 - 583; DOI: 10.1021/ic990900k |
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Bidentate Ligands That Contain Pyrrole in Place of Pyridine Feiyue Wu, Charles M. Chamchoumis, and Randolph P. Thummel pp 584 - 590; DOI: 10.1021/ic990445s |
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Assignment of Multiline Tungsten-183 NMR Spectra of Diamagnetic Polyoxotungstates from Intensity Patterns Nikolay N. Sveshnikov and Michael T. Pope pp 591 - 594; DOI: 10.1021/ic9908928 |
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Coordination Chemistry of Trivalent Lanthanide and Actinide Ions in Dilute and Concentrated Chloride Solutions P. G. Allen, J. J. Bucher, D. K. Shuh, N. M. Edelstein, and I. Craig pp 595 - 601; DOI: 10.1021/ic9905953 |
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Gold(I) Heteroatom-Substituted Imido Complexes. Amino Nitrene Loss from [(LAu)3(-NNR2)]+ Bruce W. Flint, Yi Yang, and Paul R. Sharp pp 602 - 608; DOI: 10.1021/ic990586u |
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Mixed Chloride/Amine Complexes of Dimolybdenum(II,II). 6. Stepwise Substitution of Amines by Tertiary Phosphines and Vice Versa: Stereochemical Hysteresis F. Albert Cotton, Evgeny V. Dikarev, and Santiago Herrero pp 609 - 616; DOI: 10.1021/ic9913684 |
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Redox-Tunable Valence Tautomerism in a Cobalt Schiff Base Complex Daniel Ruiz-Molina, Jaume Veciana, Klaus Wurst, David N. Hendrickson, and Concepció Rovira pp 617 - 619; DOI: 10.1021/ic990714e |
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Synthesis and Characterization of a Novel Tetranuclear Copper(II) Resorc[4]arene Complex Possessing Four Structurally Different Copper Centers O. Danny Fox, N. Kent Dalley, and Roger G. Harrison pp 620 - 622; DOI: 10.1021/ic990798r |
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Polyoxometalate-Diphosphate Complexes. 5.1 Cigar-Shaped 30-Molybdobispyrophosphate: Structure of (N(C4H9)4)2H9[{(P2O7)Mo15O45}2][PMo12O40] Ulrich Kortz pp 623 - 624; DOI: 10.1021/ic9907258 |
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Polyoxometalate-Diphosphate Complexes. 6.1 Possible Intermediates in the Molybdate-Catalyzed Hydrolysis of Pyrophosphate: Structure of Hexamolybdopyrophosphate [(O3POPO3)Mo6O18(H2O)4]4- Ulrich Kortz pp 625 - 626; DOI: 10.1021/ic990959r |
Issue 4
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After More than 60 Years, a New NaTl Type Zintl Phase: KTl at High Pressure Jürgen Evers and Gilbert Oehlinger pp 628 - 629; DOI: 10.1021/ic990894s |
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Synthesis and Structural Characterization of a 4-Coordinate Molybdenum(VI) Dioxo Diaryloxide, MoO2(O-2,6-t-Bu2C6H3)2·HO-2,6-t-Bu2C6H3 Tracy A. Hanna, Christopher D. Incarvito, and Arnold L. Rheingold pp 630 - 631; DOI: 10.1021/ic991271h |
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Reactivity of the Iron Porphyrin Fe(TPP)(NO) with Excess NO. Formation of Fe(TPP)(NO)(NO2) Occurs via Reaction with Trace NO2 Ivan M. Lorkovi  and Peter C. Fordpp 632 - 633; DOI: 10.1021/ic9910413 |
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Influence of Carrier Ligand NH Hydrogen Bonding to the O6 and Phosphate Group of Guanine Nucleotides in Platinum Complexes with a Single Guanine Ligand Maria Carlone, Francesco P. Fanizzi, Francesco P. Intini, Nicola Margiotta, Luigi G. Marzilli, and Giovanni Natile pp 634 - 641; DOI: 10.1021/ic990517f |
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Ammonolysis of Mono(pentamethylcyclopentadienyl) Titanium(IV) Derivatives Angel Abarca, Pilar Gómez-Sal, Avelino Martín, Miguel Mena, Josep María Poblet, and Carlos Yélamos pp 642 - 651; DOI: 10.1021/ic9907718 |
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Synthesis and Characterization of Pyridine Amide Cation Radical Complexes of Iron: Stabilization Due to Coordination with Low-Spin Iron(III) Center Apurba Kumar Patra, Manabendra Ray, and Rabindranath Mukherjee pp 652 - 657; DOI: 10.1021/ic9909734 |
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Electronic Structure of [(CpCr){(CO)3M}]-Cot (M = Cr, Fe): A Theoretical Study Uwe Richter, Joachim Reinhold, and Jürgen Heck pp 658 - 664; DOI: 10.1021/ic9910559 |
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Trimerization of NaC2N3 to Na3C6N9 in the Solid: Ab Initio Crystal Structure Determination of Two Polymorphs of NaC2N3 and of Na3C6N9 from X-ray Powder Diffractometry Barbara Jürgens, Elisabeth Irran, Julius Schneider, and Wolfgang Schnick pp 665 - 670; DOI: 10.1021/ic991044f |
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Crystal Structure and Replacement Reaction of Coordinated Water Molecules of the Heteropoly Compounds of Sandwich-Type Tungstoarsenates Li-Hua Bi, En-Bo Wang, Jun Peng, Ru-Dan Huang, Lin Xu, and Chang-Wen Hu pp 671 - 679; DOI: 10.1021/ic990596v |
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Gold and Silver Complexes with the Ferrocenyl Phosphine FcCH2PPh2 [Fc = (5-C5H5)Fe(5-C5H4)] Eva M. Barranco, Olga Crespo, M. Concepción Gimeno, Antonio Laguna, Peter G. Jones, and Birte Ahrens pp 680 - 687; DOI: 10.1021/ic9905446 |
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The Related Compounds MThTe3 (M = Mn, Mg) and ACuThSe3 (A = K, Cs): Syntheses and Characterization Amy A. Narducci and James A. Ibers pp 688 - 691; DOI: 10.1021/ic991039b |
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Novel MnIIMnIIIMnII Trinuclear Complexes with Carbohydrate Bridges Derived from Seven-Coordinate Manganese(II) Complexes with N-Glycoside Tomoaki Tanase, Saori Tamakoshi, Mayumi Doi, Masahiro Mikuriya, Hiromu Sakurai, and Shigenobu Yano pp 692 - 704; DOI: 10.1021/ic990349r |
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Rhodium Complexes with the Chelating and Binucleating Ligands P(CH2CH2Py)nPh3-n (Py = 2-Pyridyl; n = 1, 2): Structures and Fluxional Behavior M. Aránzazu Alonso, Juan A. Casares, Pablo Espinet, Katerina Soulantica, Jonathan P. H. Charmant, and A. Guy Orpen pp 705 - 711; DOI: 10.1021/ic990634a |
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Synthesis and Characterization of Nickel(II) Bis(alkylthio)salen Complexes D. Scott Bohle, Abdullah Zafar, Patricia A. Goodson, and David A. Jaeger pp 712 - 718; DOI: 10.1021/ic990950p |
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Monochlorogallane: Physical Properties and Structure of the Gaseous Molecule H2Ga(-Cl)2GaH2 As Determined by Vibrational, Electron Diffraction, and ab Initio Studies Emma Johnsen, Anthony J. Downs, Timothy M. Greene, Philip F. Souter, Kirsten Aarset, Elizabeth M. Page, David A. Rice, Alan N. Richardson, Paul T. Brain, David W. H. Rankin, and Colin R. Pulham pp 719 - 727; DOI: 10.1021/ic9908975 |
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Synthesis and Characterization of New Cationic Hexacoordinate Silanes Beon-Kyu Kim, Seok-Bong Choi, Steven D. Kloos, and Philip Boudjouk pp 728 - 731; DOI: 10.1021/ic990415p |
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Crystal Structures and Pressure-Induced Redox Reaction of Cs2PdI4·I2 to Cs2PdI6 B. Schüpp, P. Heines, A. Savin, and H.-L. Keller pp 732 - 735; DOI: 10.1021/ic990670+ |
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Hydrogen Atom and Hydride Transfer in the Reactions of Chromium(IV) and Chromium(V) Complexes with Rhodium Hydrides. Crystal Structure of a Superoxorhodium(III) Product Andreja Bakac and Ilia A. Guzei pp 736 - 740; DOI: 10.1021/ic991098p |
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Mechanistic and Kinetic Studies of Crystallization of Birnessite Jian Luo, Qiuhua Zhang, and Steven L. Suib pp 741 - 747; DOI: 10.1021/ic990456l |
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Linear Trichromium Complexes with Direct Cr to Cr Contacts. 1. Compounds with Cr3(dipyridylamide)42+ Cores Rodolphe Clérac, F. Albert Cotton, Lee M. Daniels, Kim R. Dunbar, Carlos A. Murillo, and Isabel Pascual pp 748 - 751; DOI: 10.1021/ic990793u |
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Linear Trichromium Complexes with Direct Cr to Cr Contacts. 2. Compounds with Cr3(dipyridylamide)43+ Cores Rodolphe Clérac, F. Albert Cotton, Lee M. Daniels, Kim R. Dunbar, Carlos A. Murillo, and Isabel Pascual pp 752 - 756; DOI: 10.1021/ic991022t |
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Synthesis and Properties of Iron(II) and Manganese(II) Complexes Derived from a Topologically Constrained Pentadentate Ligand Simon Collinson, Nathaniel W. Alcock, Ahasuya Raghunathan, Pawan K. Kahol, and Daryle H. Busch pp 757 - 764; DOI: 10.1021/ic981410f |
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Structural and EPR Study of the Dependence on Deuteration of the Jahn-Teller Distortion in Ammonium Hexaaquacopper(II) Sulfate, (NH4)2[Cu(H2O)6](SO4)2 Robert W. Henning, Arthur J. Schultz, Michael A. Hitchman, Genevieve Kelly, and Tim Astley pp 765 - 769; DOI: 10.1021/ic9910864 |
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Intraligand Charge Transfer in the Pd(II) Oxinate Complex Pd(qol)2. Site-Selective Emission, Excitation, and Optically Detected Magnetic Resonance Hartmut Yersin, Dirk Donges, Jeffrey K. Nagle, Rolf Sitters, and Max Glasbeek pp 770 - 777; DOI: 10.1021/ic991023l |
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Synthesis and Structure of K10Tl7: The First Binary Trielide Containing Naked Pentagonal Bipyramidal Tl7 Clusters Stefan Kaskel and John D. Corbett pp 778 - 782; DOI: 10.1021/ic991168s |
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Metal-Assembled Cobalt(II) Resorc[4]arene-Based Cage Molecules That Reversibly Capture Organic Molecules from Water and Act as NMR Shift Reagents O. Danny Fox, Jenny F.-Y. Leung, Jesse M. Hunter, N. Kent Dalley, and Roger G. Harrison pp 783 - 790; DOI: 10.1021/ic991235i |
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Syntheses, Structures, and Reactivities of Mono- and Dinuclear Iridium Thiolato Complexes Containing Nitrosyl Ligands Shoji Matsukawa, Shigeki Kuwata, and Masanobu Hidai pp 791 - 798; DOI: 10.1021/ic990805b |
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Rates and Mechanisms of Water Exchange of UO22+(aq) and UO2(oxalate)F(H2O)2-: A Variable-Temperature 17O and 19F NMR Study Ildikó Farkas, István Bányai, Zoltán Szabó, Ulf Wahlgren, and Ingmar Grenthe pp 799 - 805; DOI: 10.1021/ic990929o |
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High-Pressure Synthesis of the Polymorph of Layer Structured Compounds MNX (M = Zr, Hf; X = Cl, Br, I) Shoji Yamanaka, Kojiro Itoh, Hiroshi Fukuoka, and Masahiro Yasukawa pp 806 - 809; DOI: 10.1021/ic991058l |
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Synthesis and Spectroscopy of N3P3X5OCH=CH2 (X = Cl, F, OCH3, OCH2CF3, N(CH3)2) and N3P3X4(OCH=CH2)2 (X = Cl, N(CH3)2). Correlations of Ultraviolet Photoelectron Spectroscopy and Nuclear Magnetic Resonance Data to Electronic and Geometrical Structure Christopher W. Allen, Douglas E. Brown, and S. Davis Worley pp 810 - 814; DOI: 10.1021/ic990406g |
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Low-Valent Gallium, Indium, and Tin Compounds That Contain a Highly Fluorinated Tris(pyrazolyl)borate Ligand: Syntheses and Characterization of [HB(3,5-(CF3)2Pz)3]Ga, [HB(3,5-(CF3)2Pz)3]In, and [HB(3,5-(CF3)2Pz)3]Sn(CF3SO3) H. V. Rasika Dias and Wiechang Jin pp 815 - 819; DOI: 10.1021/ic9912171 |
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Ruthenium Complexes with a Terminal Hydrazido Ligand. Synthesis, Spectroscopy, and X-ray Crystal Structure Xian-Ru Sun, Jie-Sheng Huang, Kung-Kai Cheung, and Chi-Ming Che pp 820 - 826; DOI: 10.1021/ic990467e |
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Structural Characterization of anti- and syn-Allyltricarbonyliron Bromide: Rotational Spectra, Quadrupole Coupling, and Density Functional Calculations Brian J. Drouin, Jennifer J. Dannemiller, and Stephen G. Kukolich pp 827 - 835; DOI: 10.1021/ic990884r |
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Cisplatin-DNA Cross-link Models with an Unusual Type of Chirality-Neutral Chelate Amine Carrier Ligand, N,N'-Dimethylpiperazine (Me2ppz): Me2ppzPt(guanosine monophosphate)2 Adducts That Exhibit Novel Properties Sharon T. Sullivan, Antonella Ciccarese, Francesco P. Fanizzi, and Luigi G. Marzilli pp 836 - 842; DOI: 10.1021/ic9903580 |
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Pentafluorosulfanylnitramide Salts Michael E. Sitzmann, Richard Gilardi, Ray J. Butcher, William M. Koppes, Alfred G. Stern, Joseph S. Thrasher, Nirupam J. Trivedi, and Zhen-Yu Yang pp 843 - 850; DOI: 10.1021/ic991281i |
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Metal-Ligand Interactions in Bis(isodicyclopentadienyl)iron Complexes Rolfe H. Herber, Irene Gattinger, and Frank H. Köhler pp 851 - 853; DOI: 10.1021/ic991258x |
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Reactivity of the [Mo3(3-S)(2-S2)3Br6]2- Anion toward the Imidodiphosphinochalcogenido Ligands [N(QPPh2)2]- (Q = S, Se): Synthesis and Characterization of [Mo3(3-S)(2-S2)3{N(QPPh2)2}3]Br Virginie Béreau, Christopher G. Pernin, and James A. Ibers pp 854 - 856; DOI: 10.1021/ic9907056 |
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Reaction between the (3,1) Isomer of Ru2(F5ap)4Cl and CN-. Synthesis, Structural Determination, and Electrochemistry of Ru2(F5ap)3[-(o-NC)F4ap](-CN) and Two Geometric Isomers of Ru2(F5ap)4(-CN)2 John L. Bear, Yulan Li, Jing Cui, Baocheng Han, Eric Van Caemelbecke, Tuan Phan, and Karl M. Kadish pp 857 - 861; DOI: 10.1021/ic990100+ |
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EXAFS Study of Uranyl Nitrate Dimer at High and Low Temperature Craig E. Barnes, Yongsoon Shin, Suree Saengkerdsub, and Sheng Dai pp 862 - 864; DOI: 10.1021/ic9904992 |
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Synthesis, Structure, and Magnetic Properties of the Charge-Transfer Salt Ferromagnet Decamethylchromocenium Dimethyl Dicyanofumarate, TCurie = 5.7 K Bharat B. Kaul, Roger D. Sommer, Bruce C. Noll, and Gordon T. Yee pp 865 - 868; DOI: 10.1021/ic991196a |
Issue 5
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One-Dimensional Antiferromagnetic Chain in [Ni(dmit)2]- Salts of [K+ or Rb+(4,13-diaza-18-crown-6)] Supramolecular Cation Nobuhiro Takamatsu, Tomoyuki Akutagawa, Tatsuo Hasegawa, Takayoshi Nakamura, Tamotsu Inabe, Wataru Fujita, and Kunio Awaga pp 870 - 871; DOI: 10.1021/ic991198v |
Magnetic Interactions in the High-Spin Iron(III) Oxooctaethylchlorinato Derivative [Fe(oxoOEC)(Cl)] and Its -Cation Radical [Fe(oxoOEC )(Cl)]SbCl6Teresa J. Neal, Seong-Joo Kang, Ilona Turowska-Tyrk, Charles E. Schulz, and W. Robert Scheidt pp 872 - 880; DOI: 10.1021/ic991052w |
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Structural, Spectroscopic, and Electrochemical Studies of Binuclear Manganese(II) Complexes of Bis(pentadentate) Ligands Derived from Bis(1,4,7-triazacyclononane) Macrocycles Suzanne J. Brudenell, Leone Spiccia, Alan M. Bond, Gary D. Fallon, David C. R. Hockless, George Lazarev, Peter J. Mahon, and Edward R. T. Tiekink pp 881 - 892; DOI: 10.1021/ic9814470 |
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Step-Scan FTIR Time-Resolved Spectroscopy Study of Excited-State Dipole Orientation in Soluble Metallopolymers Gregory D. Smith, Kimberly A. Maxwell, Joseph M. DeSimone, Thomas J. Meyer, and Richard A. Palmer pp 893 - 898; DOI: 10.1021/ic990819h |
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Catalysis of the Silica Sol-Gel Process by Divalent Transition Metal Bis(acetylacetonate) Complexes Elizabeth I. Mayo, Duke D. Pooré, and A. E. Stiegman pp 899 - 905; DOI: 10.1021/ic990577l |
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Structural Correlations and Conformational Preference in Edge-Sharing Binuclear d8 Complexes with XR2 Bridges. A Theoretical Study Gabriel Aullón, Agustí Lledós, and Santiago Alvarez pp 906 - 916; DOI: 10.1021/ic991268y |
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Evolution of the Jahn-Teller Distortion of MnO6 Octahedra in RMnO3 Perovskites (R = Pr, Nd, Dy, Tb, Ho, Er, Y): A Neutron Diffraction Study J. A. Alonso, M. J. Martínez-Lope, M. T. Casais, and M. T. Fernández-Díaz pp 917 - 923; DOI: 10.1021/ic990921e |
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Synthesis of MII[N(SiMe3)2][Me3SiNC(tBu)NSiMe3] (M = Sn, Ge) from Amidinate Precursors: Active Catalysts for Phenyl Isocyanate Cyclization Stephen R. Foley, Yuanlin Zhou, Glenn P. A. Yap, and Darrin S. Richeson pp 924 - 929; DOI: 10.1021/ic991004b |
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Molecular and Electronic Structure of Nitridocyanometalates of Chromium(V) and Manganese(V): A Combined Experimental and DFT Study Jesper Bendix, Robert J. Deeth, Thomas Weyhermüller, Eckhard Bill, and Karl Wieghardt pp 930 - 938; DOI: 10.1021/ic990971j |
Organotin Derivatives of  -[XIIIW9O33]9- (X = As, Sb) Heteropolytungstates. Solution- and Solid-State Characterization of [{(C6H5Sn)2O}2H(-AsW9O33)2]9- and [(C6H5Sn)3Na3(-SbW9O33)2]6-Gerta Sazani, Michael H. Dickman, and Michael T. Pope pp 939 - 943; DOI: 10.1021/ic991095c |
Mechanism of the S  N Isomerization and Aquation of the Thiocyanato Pentaammine Cobalt(III) IonFrançois P. Rotzinger and David M. Benoit pp 944 - 952; DOI: 10.1021/ic990948y |
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Metal-Metal Interactions in Weakly Coupled Mixed-Valence E- and Z-Diferrocenylethylene Complexes Yuan Jang Chen, Dung-Shien Pan, Chi-Fa Chiu, Jia-Xin Su, She Jing Lin, and Keh Shin Kwan pp 953 - 958; DOI: 10.1021/ic991084j |
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Xanthene-Bridged Cofacial Bisporphyrins Christopher J. Chang, Yongqi Deng, Alan F. Heyduk, C. K. Chang, and Daniel G. Nocera pp 959 - 966; DOI: 10.1021/ic990987+ |
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Structural Studies of the [Tris(imidazolyl)phosphine]metal Nitrate Complexes {[PimPri,But]M(NO3)}+ (M = Co, Cu, Zn, Cd, Hg): Comparison of Nitrate-Binding Modes in Synthetic Analogues of Carbonic Anhydrase Clare Kimblin, Vincent J. Murphy, Tony Hascall, Brian M. Bridgewater, Jeffrey B. Bonanno, and Gerard Parkin pp 967 - 974; DOI: 10.1021/ic990682v |
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Dinuclear Azolato-Bridged Complexes of the Nickel Group Metals with Haloaryl Ligands: A Reinvestigation of Their Behavior in Solution Pablo Espinet, Ana M. Gallego, Jesús M. Martínez-Ilarduya, and Eva Pastor pp 975 - 979; DOI: 10.1021/ic9911062 |
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Reduced Mono-, Di-, and Tetracubane-Type Clusters Containing the [MoFe3S4]2+ Core Stabilized by Tertiary Phosphine Ligation Frank Osterloh, Brent M. Segal, Catalina Achim, and R. H. Holm pp 980 - 989; DOI: 10.1021/ic991016x |
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Characterization and X-ray Absorption Spectroscopic Studies of Bis[quinato(2-)]oxochromate(V) Rachel Codd, Aviva Levina, Lianbo Zhang, Trevor W. Hambley, and Peter A. Lay pp 990 - 997; DOI: 10.1021/ic990730b |
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Synthesis and Structure of the Cluster Ion Pair {Ru3(CO)9[-P(NPri2)2]3}{Ru6(CO)15(6-C)[-P(NPri2)2]}. A Theoretical Overview of M3(-PR2)3 Frameworks Weibin Wang, Paul J. Low, Arthur J. Carty, Enrico Sappa, Giuliana Gervasio, Carlo Mealli, Andrea Ienco, and Enrique Perez-Carreño pp 998 - 1005; DOI: 10.1021/ic990195f |
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The Solid-State Electrochemistry of Metal Octacyanomolybdates, Octacyanotungstates, and Hexacyanoferrates Explained on the Basis of Dissolution and Reprecipitation Reactions, Lattice Structures, and Crystallinities Uwe Schröder and Fritz Scholz pp 1006 - 1015; DOI: 10.1021/ic9909330 |
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Phosphate Diester Hydrolysis by Mono- and Dinuclear Lanthanum Complexes with an Unusual Third-Order Dependence Paul E. Jurek, Anne M. Jurek, and Arthur E. Martell pp 1016 - 1020; DOI: 10.1021/ic9906961 |
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Conversion of Core Oxos to Water Molecules by 4e-/4H+ Reductive Dehydration of the Mn4O26+ Core in the Manganese-Oxo Cubane Complex Mn4O4(Ph2PO2)6: A Partial Model for Photosynthetic Water Binding and Activation Wolfgang F. Ruettinger and G. Charles Dismukes pp 1021 - 1027; DOI: 10.1021/ic9911421 |
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Chemistry of Thiocarboxylates: Synthesis and Structures of Neutral Copper(I) Thiocarboxylates with Triphenylphosphine Theivanayagam C. Deivaraj, Ghee Xiong Lai, and Jagadese J. Vittal pp 1028 - 1034; DOI: 10.1021/ic9907314 |
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Silver(I) Coordination Polymers Using Thioether Macrocycle Building Blocks Alexander J. Blake, Neil R. Champness, Steven M. Howdle, and Paul B. Webb pp 1035 - 1038; DOI: 10.1021/ic991145d |
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A Dinuclear Cation with Both Four- and Five-Coordinate Cobalt(II) F. Albert Cotton, Carlos A. Murillo, and Hong-Cai Zhou pp 1039 - 1041; DOI: 10.1021/ic991186+ |
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Structural and Solution Calorimetric Studies of Sulfur Binding to Nucleophilic Carbenes Jinkun Huang, Hans-Jörg Schanz, E. D. Stevens, Steven P. Nolan, Kenneth B. Capps, Andreas Bauer, and Carl D. Hoff pp 1042 - 1045; DOI: 10.1021/ic990906+ |
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Facile Syntheses and Structures of New Metal-Maleonitrilediselenolates [K([2.2.2]-cryptand)]3[Ag(Se2C2(CN)2)(Se6)], [K([2.2.2]-cryptand)]2[Ni(Se2C2(CN)2)2], and Ni(dppp)(Se2C2(CN)2) Craig C. McLauchlan and James A. Ibers pp 1046 - 1048; DOI: 10.1021/ic9901719 |
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Electrochemical Properties of Vanadium(III,IV,V)-Salen Complexes in Acetonitrile. Four-Electron Reduction of O2 by V(III)-Salen. Zenghe Liu and Fred C. Anson: pp 1048 - 1048; DOI: 10.1021/ic992000+ |
Issue 6
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Single Crystal and Solution Complex Structure of Nd(CO3)45-. The First Characterization of a Mononuclear Lanthanide(III) Carbonato Complex Wolfgang Runde, Mary P. Neu, Craig Van Pelt, and Brian L. Scott pp 1050 - 1051; DOI: 10.1021/ic991087w |
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Electrocatalysis in Photochemically Activated Electropolymerized Thin Films John A. Moss, Robert M. Leasure, and Thomas J. Meyer pp 1052 - 1058; DOI: 10.1021/ic990235f |
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From Simple trans-[a2Pt(2-hydroxypyrimidine)2]2+ (a = NH3, CH3NH2) Complexes to Structures of Higher Complexity. Molecular Recognition of 2-Aminopyrimidine by Hydrogen Bond Formation and Reactivity toward Additional Metal Ions Jorge A. R. Navarro, Eva Freisinger, and Bernhard Lippert pp 1059 - 1065; DOI: 10.1021/ic9903634 |
The Structure of arachno-[B6H11]-, at -25  C in (CD3)2O, Is Resolved via the ab Initio/IGLO-GIAO/NMR ProcedureMatthias Hofmann, Paul v. R. Schleyer, and Robert E. Williams pp 1066 - 1070; DOI: 10.1021/ic991073q |
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Microcalorimetric Determination of Thermodynamic Parameters for Ionophore-Siderophore Host-Guest Complex Formation Stephen M. Trzaska, Eric J. Toone, and Alvin L. Crumbliss pp 1071 - 1075; DOI: 10.1021/ic9908571 |
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Structural Trends in First-Row Transition-Metal Bis(benzimidazole) Complexes Pramatha Payra, Huichang Zhang, Wai Him Kwok, Maosheng Duan, Judith Gallucci, and Michael K. Chan pp 1076 - 1080; DOI: 10.1021/ic991075a |
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Deprotonation of Cationic Tungsten(IV) Aqua-Oxo-Alkyne Complexes To Form Dioxo-Vinyl Tungsten(VI) Complexes Todd W. Crane, Peter S. White, and Joseph L. Templeton pp 1081 - 1091; DOI: 10.1021/ic990994y |
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Coordination Chemistry of a Novel Tetramacrocyclic Ligand Derived from 1,4,7-Triazacyclononane: Synthesis, Structure, and Properties of Nickel(II) and Copper(II) Complexes Bim Graham, Martin J. Grannas, Milton T. W. Hearn, Christopher M. Kepert, Leone Spiccia, Brian W. Skelton, and Allan H. White pp 1092 - 1099; DOI: 10.1021/ic991082z |
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Structural Studies on Single Crystals of Chevrel Phase Selenides REMo6Se8 (RE = La, Ce, Pr, Nd, or Sm) at 298 K F. Le Berre, C. Hamard, O. Peña, and A. Wojakowski pp 1100 - 1105; DOI: 10.1021/ic990762z |
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Metal Complexes of N-Tosylamidoporphyrin: cis-Acetato-N-tosylimido-meso-tetraphenylporphyrinatothallium(III) and trans-Acetato-N-tosylimido-meso-tetraphenylporphyrinatogallium(III) Jo-Yu Tung, Jyh-Iuan Jang, Chu-Chieh Lin, Jyh-Horung Chen, and Lian-Pin Hwang pp 1106 - 1112; DOI: 10.1021/ic9911318 |
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Theoretical Study of the Mechanisms of Palladation of Methylenecyclopropane and [3 + 2] Cycloadditions Tomohiro Suzuki and Hiroshi Fujimoto pp 1113 - 1119; DOI: 10.1021/ic991093s |
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Unusual Coordination Mode of Thiosemicarbazone Ligands. A Search for the Origin Falguni Basuli, Shie-Ming Peng, and Samaresh Bhattacharya pp 1120 - 1127; DOI: 10.1021/ic991083r |
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Redox Characteristics of Nickel and Palladium Complexes of the Open-Chain Tetrapyrrole Octaethylbilindione: A Biliverdin Model Pamela A. Lord, Marilyn M. Olmstead, and Alan L. Balch pp 1128 - 1134; DOI: 10.1021/ic9910209 |
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Spin Frustration in MII[C(CN)3]2 (M = V, Cr). A Magnetism and Neutron Diffraction Study Jamie L. Manson, Eric Ressouche, and Joel S. Miller pp 1135 - 1141; DOI: 10.1021/ic991231d |
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A New Bimetallic Assembly Magnet [{Ni(tn)2}5{FeIII(CN)6}3]n(ClO4)n·2.5nH2O (tn = Trimethylenediamine) with a Novel 3-D Tunnel Structure Si-Wei Zhang, De-Gang Fu, Wei-Yin Sun, Zheng Hu, Kai-Bei Yu, and Wen-Xia Tang pp 1142 - 1146; DOI: 10.1021/ic990591y |
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Oligomerization of Early Transition Metal {M(OH)3}2(-C2) Acetylides toward the Formation of [(OH)3MC]n (n = 4, 6) Metalla Carbides: A Theoretical Study by Density Functional Theory Paola Belanzoni, Antonio Sgamellotti, Nazzareno Re, and Carlo Floriani pp 1147 - 1151; DOI: 10.1021/ic990845f |
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Pd(II) Complexes with Polydentate Nitrogen Ligands. Molecular Recognition and Dynamic Behavior Involving Pd-N Bond Rupture. X-ray Molecular Structures of [{Pd(C6HF4)2}(bpzpm)] and [{Pd(3-C4H7)}2(bpzpm)] (CF3SO3)2 [bpzpm = 4,6-Bis(pyrazol-1-yl)pyrimidine] Felipe Gómez-de la Torre, Antonio de la Hoz, Félix A. Jalón, Blanca R. Manzano, Ana M. Rodríguez, José Elguero, and Martín Martínez-Ripoll pp 1152 - 1162; DOI: 10.1021/ic990495x |
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A Study of the Sequential Acid-Catalyzed Hydroxylation of Dodecahydro-closo-dodecaborate(2-) Toralf Peymann, Carolyn B. Knobler, and M. Frederick Hawthorne pp 1163 - 1170; DOI: 10.1021/ic991105+ |
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Kinetics and Mechanism of Copper(II) Complex Formation with Tripodal Aminopolythiaether and Aminopolypyridyl Ligands in Aqueous Solution Edna A. Ambundo, Marie-Veronique Deydier, L. A. Ochrymowycz, and D. B. Rorabacher pp 1171 - 1179; DOI: 10.1021/ic990904p |
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Coordination of Two High-Affinity Hexamer Peptides to Copper(II) and Palladium(II) Models of the Peptide-Metal Chelation Site on IMAC Resins Ya Chen, Richard Pasquinelli, Mohammed Ataai, Richard R. Koepsel, Richard A. Kortes, and Rex E. Shepherd pp 1180 - 1186; DOI: 10.1021/ic990520z |
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Structural Studies on Layered Alkylpyridinium Iodopalladate Networks Francesco Neve, Alessandra Crispini, and Oriano Francescangeli pp 1187 - 1194; DOI: 10.1021/ic9906959 |
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Reaction of CF3 Radicals with CO and O2. Isolation of Bis(trifluoromethyl)peroxydicarbonate, CF3OC(O)OOC(O)OCF3, and Identification of Bis(trifluoromethyl)trioxydicarbonate, CF3OC(O)OOOC(O)OCF3 G. A. Argüello, H. Willner, and F. E. Malanca pp 1195 - 1199; DOI: 10.1021/ic991265l |
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Electron Transfer. 141. Reactions of Indium(I) with Transition Metal Center Oxidants Shawn Swavey and E. S. Gould pp 1200 - 1203; DOI: 10.1021/ic991181c |
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Matrix Infrared Spectroscopic Study of Magnesium Carbene and Carbenoid Radicals and Analysis of Their Bonding with Density Functional Calculations William D. Bare, Angelo Citra, Carl Trindle, and Lester Andrews pp 1204 - 1215; DOI: 10.1021/ic991229m |
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Syntheses, Structures, and Properties of the Bis(cyclopentadienyl) Rare-Earth Imidodiphosphinochalcogenido Compounds Cp2Ln[N(QPPh2)2] (Ln = La, Gd, Er, or Yb for Q = Se; Ln = Yb for Q = S) Christopher G. Pernin and James A. Ibers pp 1216 - 1221; DOI: 10.1021/ic990889o |
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Soluble Yttrium Chalcogenides: Syntheses, Structures, and NMR Properties of Y[3-N(SPPh2)2]3 and Y[2-N(SePPh2)2]2[3-N(SePPh2)2] Christopher G. Pernin and James A. Ibers pp 1222 - 1226; DOI: 10.1021/ic990984x |
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Organoantimony(V) Cyanoximates: Synthesis, Spectra and Crystal Structures Konstantin V. Domasevitch, Nikolay N. Gerasimchuk, and Andrew Mokhir pp 1227 - 1237; DOI: 10.1021/ic9906048 |
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Alkali Salts of C3-Symmetric, Linked Aryloxides: Selective Binding of Substrates with Metal Aggregates Maarten B. Dinger and Michael J. Scott pp 1238 - 1254; DOI: 10.1021/ic991309q |
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Variable-Energy Photoelectron Spectroscopy of Substituted Rhenium and Manganese Pentacarbonyls: Molecular Orbital Assignments and the Interatomic Resonant Effect Y. F. Hu, G. Michael Bancroft, and K. H. Tan pp 1255 - 1264; DOI: 10.1021/ic9912272 |
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Mixed Uranium Chloride Fluorides UF6-nCln and Methoxyuranium Fluorides UF6-n(OCH3)n: A Theoretical Study of Equilibrium Geometries, Vibrational Frequencies, and the Role of the f Orbitals Georg Schreckenbach pp 1265 - 1274; DOI: 10.1021/ic9910615 |
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Synthesis and Structures of Bis(dithiolene)-Tungsten(IV) Complexes Related to the Active Sites of Tungstoenzymes Kie-Moon Sung and R. H. Holm pp 1275 - 1281; DOI: 10.1021/ic991153u |
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Synthesis of Halogenated Polyhedral Phosphaboranes. Crystal Structure of closo-1,7-P2B10Cl10 Willi Keller, Gisela Sawitzki, and Wolfgang Haubold pp 1282 - 1287; DOI: 10.1021/ic990112v |
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Metal-Metal Interactions as a Function of Bridging Ligand Topology: An Electrochemical, Spectroelectrochemical, and Magnetic Study on Dinuclear Oxo-Mo(V) Complexes with Various Isomers of Dihydroxynaphthalene as Bridging Ligand Simon Bayly, Jon A. McCleverty, Michael D. Ward, Dante Gatteschi, and Federico Totti pp 1288 - 1293; DOI: 10.1021/ic9912373 |
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Thermal and Photochemical Reduction of Aqueous Chlorine by Ruthenium(II) Polypyridyl Complexes Basudeb Saha and David M. Stanbury pp 1294 - 1300; DOI: 10.1021/ic9910920 |
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Synthesis and Reactivity of Hydrazido(2-) and Imido Derivatives of Titanium(IV) Tetratolylporphyrin Joseph L. Thorman and L. Keith Woo pp 1301 - 1304; DOI: 10.1021/ic990991l |
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Isomeric Equilibria in Aqueous Solution Involving Aromatic Ring Stacking in the Sexternary Complexes Formed by the Quaternary cis-(NH3)2Pt(2'-deoxyguanosine-N7)(dGMP-N7) Complex and the Binary Cu(2,2'-bipyridine)2+ or Cu(1,10-phenanthroline)2+ Complexes (dGMP2- = 2'-Deoxyguanosine 5'-monophosphate) Marc Sven Lüth, Bin Song, Bernhard Lippert, and Helmut Sigel pp 1305 - 1310; DOI: 10.1021/ic9905087 |
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Kinetics and Mechanism of the Monomerization of a Re(V) Dithiolato Dimer with Monodentate Ligands. Electronic and Steric Effects Gábor Lente, Ilia A. Guzei, and James H. Espenson pp 1311 - 1319; DOI: 10.1021/ic991431p |
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Site-Specific Methylation of Coordinated 1,2,4-Triazoles: A Novel Route to Sterically Hindered Ru(bpy)2 Complexes Stefano Fanni, Suzanne Murphy, J. Scott Killeen, and Johannes G. Vos pp 1320 - 1321; DOI: 10.1021/ic991103p |
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A Convenient Route To Synthesize the Fully Conjugated Bimetallic Complex (Bu4N)2{tto[Ni(dmit)2]} (tto = Tetrathiooxalate, C2S42-, and dmit = 1,3-dithiole-2-thione-4,5-dithiolate, C3S52-) and the Crystal Structure of a New Crystal Form Jun-Feng Bai, Jing-Lin Zuo, Zhen Shen, Xiao-Zeng You, Hoong-Kun Fun, and Kandasamy Chinnakali pp 1322 - 1324; DOI: 10.1021/ic9902875 |
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Cuboidal W3S4 Cluster Complexes as New Generation X-ray Contrast Agents Shi-Bao Yu, Michael Droege, Brent Segal, Sook-Hui Kim, Tony Sanderson, and Alan D. Watson pp 1325 - 1328; DOI: 10.1021/ic990976g |
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Solid State Structures of [Ag5(dppm)4(S2CC(CN)P(O)(OEt)2)2][PF6] and Ag4(dppm)4(S2CC(CN)P(O)(OEt)2)2: Variable Coordination Modes of 1,1-Dithiolate to Silver(I) C. W. Liu, Ben-Jie Liaw, Ju-Chung Wang, and Tai-Chiun Keng pp 1329 - 1332; DOI: 10.1021/ic991012s |
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Analogues of the Tp* Ligand Containing a 3-Me but Non-Methyl 5-R Groups Arnold L. Rheingold, Louise M. Liable-Sands, and Swiatoslaw Trofimenko pp 1333 - 1335; DOI: 10.1021/ic991239n |
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Reaction of Model Nucleobases with the Diaqua(bis(N-methylimidazol-2-yl) ketone)platinum(II) Dication. Synthesis and Structure of the Head-to-Tail Isomers of Bis(9-methylguanine-N7) (bis(N-methylimidazol-2-yl) ketone)platinum(II) Perchlorate, Bis(1-methylcytosine-N3) (bis(N-methylimidazol-2-yl) ketone)platinum(II) Perchlorate, Bis(-1-methylthyminato-N3,O4)-bis[(bis(N-methylimidazol-2-yl) ketone)platinum(II)] Perchlorate, and Bis(-1-methyluracilato-N3,O4)bis[(bis(N-methylimidazol-2-yl) ketone)platinum(II)] Nitrate Matthias Grehl and Bernt Krebs: pp 1336 - 1336; DOI: 10.1021/ic0000449 |
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Multiple Bonding Involving Late Transition Metals. The Case of a Silver-Oxo Complex. Thomas R. Cundari, Jeremy N. Harvey, Thomas R.Klinckman, and Wentao Fu: pp 1336 - 1336; DOI: 10.1021/ic000101y |
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Neocuproine-Extended Porphyrin Coordination Complexes. 2. Spectroscopic Properties of the Metalloporphyrin Derivatives and Investigations into the HOMO Ordering. Tommaso A. Vannelli and Timothy B. Karpishin: pp 1336 - 1336; DOI: 10.1021/ic000132t |
Issue 7
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Crystal Structures of Tris(8-dimethylaminonaphthyl)phosphane and Its Hydrochloride Salt. The First Seven-Coordinate Phosphorus Compound A. Chandrasekaran, Natalya V. Timosheva, Roberta O. Day, and Robert R. Holmes pp 1338 - 1339; DOI: 10.1021/ic991295o |
Synthesis and First X-ray Structural Analysis of Monomeric Imino- 5-stibanesYoshihiro Matano, Hazumi Nomura, and Hitomi Suzuki pp 1340 - 1341; DOI: 10.1021/ic991120e |
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Molecular Rectification by a Bimetallic Ru-Os Compound Anchored to Nanocrystalline TiO2 Cornelius Kleverlaan, Monica Alebbi, Roberto Argazzi, Carlo A. Bignozzi, Georg M. Hasselmann, and Gerald J. Meyer pp 1342 - 1343; DOI: 10.1021/ic991311h |
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Self-Assembly Molecular Squares with Metal Complexes as Bridging Ligands Shih-Sheng Sun, Alexsandra S. Silva, Ira M. Brinn, and Alistair J. Lees pp 1344 - 1345; DOI: 10.1021/ic991226+ |
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Preparation and Crystal Structures of Formato Complexes of the [MIV3O4]4+ and [MIV3S4]4+ (M = Mo, W) Clusters. Convenient Precursors to the Corresponding Aqua Complexes Michael Brorson, Alan Hazell, Claus J. H. Jacobsen, Iver Schmidt, and J  rgen Villadsenpp 1346 - 1350; DOI: 10.1021/ic9906656 |
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Superexchange in Magnetic Insulators: An Interpretation of the Metal-Metal Charge Transfer Energy in the Anderson Theory H gni Weihe, Hans U. Güdel, and Hans Toftlundpp 1351 - 1362; DOI: 10.1021/ic990779h |
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Ferromagnetism in Malonato-Bridged Copper(II) Complexes. Synthesis, Crystal Structures, and Magnetic Properties of {[Cu(H2O)3][Cu(mal)2(H2O)]}n and {[Cu(H2O)4]2[Cu(mal)2(H2O)]}[Cu(mal)2(H2O)2]{[Cu(H2O)4][Cu(mal)2(H2O)2]} (H2mal = malonic Acid) Catalina Ruiz-Pérez, Joaquín Sanchiz, María Hernández Molina, Francesc Lloret, and Miguel Julve pp 1363 - 1370; DOI: 10.1021/ic9908165 |
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Binding of Phosphate with a Simple Hexaaza Polyammonium Macrocycle Olga A. Gerasimchuk, Susan Mason, José M. Llinares, Maoping Song, Nathaniel W. Alcock, and Kristin Bowman-James pp 1371 - 1375; DOI: 10.1021/ic9911116 |
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Polynuclear Chromium(III) Carboxylates. 1. Synthesis, Structure, and Magnetic Properties of an Octanuclear Complex with a Ring Structure Michal Eshel, Avi Bino, Israel Felner, David C. Johnston, Marshall Luban, and Lance L. Miller pp 1376 - 1380; DOI: 10.1021/ic9907009 |
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Synthesis, Spectral Characterization, and Structural Studies of 2-Aminobenzoate Complexes of Divalent Alkaline Earth Metal Ions: X-ray Crystal Structures of [Ca(2-aba)2(OH2)3], [{Sr(2-aba)2(OH2)2}·H2O], and [Ba(2-aba)2(OH2)] (2-abaH = 2-NH2C6H4COOH) Ramaswamy Murugavel, Vivek V. Karambelkar, Ganapathi Anantharaman, and Mrinalini G. Walawalkar pp 1381 - 1390; DOI: 10.1021/ic990895k |
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207Pb-1H Two-Dimensional NMR Spectroscopy: A Useful New Tool for Probing Lead(II) Coordination Chemistry Elizabeth S. Claudio, Marc A. ter Horst, Cameron E. Forde, Charlotte L. Stern, Matthew K. Zart, and Hilary Arnold Godwin pp 1391 - 1397; DOI: 10.1021/ic9909431 |
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A Unique Distortion in K1/3Ba2/3AgTe2: X-ray Diffraction Determination and Electronic Band Structure Analysis of Its Incommensurately Modulated Structure O. Gourdon, Jason Hanko, F. Boucher, V. Petricek, M.-H. Whangbo, M. G. Kanatzidis, and M. Evain pp 1398 - 1409; DOI: 10.1021/ic991457g |
- and  -Cyclodextrin Rotaxanes of -Bis(4-pyridyl)bis[pentacyanoferrate(II)] ComplexesAndrew J. Baer and Donal H. Macartney pp 1410 - 1417; DOI: 10.1021/ic990502h |
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Density Functional Description of the Early Stages of the Dioxygenation of [(MeC(CH2PPh2)3)M(catecholate)]+ Complexes [M = Co(III), Ir(III)]: Toward a Rationalization of the Catalytic Mechanism of Ring-Opening Dioxygenases Alessandro Bencini, Eckhard Bill, Fabio Mariotti, Federico Totti, Andrea Scozzafava, and Angelo Vargas pp 1418 - 1425; DOI: 10.1021/ic990633i |
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Three-Dimensional Open-Framework Cobalt(II) Phosphates by Novel Routes Srinivasan Natarajan, S. Neeraj, Amitava Choudhury, and C. N. R. Rao pp 1426 - 1433; DOI: 10.1021/ic991223x |
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Stepwise Assembly of Unsymmetrical Supramolecular Arrays Containing Porphyrins and Coordination Compounds Enzo Alessio, Enrica Ciani, Elisabetta Iengo, Vadim Yu. Kukushkin, and Luigi G. Marzilli pp 1434 - 1443; DOI: 10.1021/ic990709a |
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Formation and Dissociation Kinetics and Crystal Structures of Nickel(II)-Macrocyclic Tetrathiaether Complexes in Acetonitrile. Comparison to Nickel(II)-Macrocyclic Tetramines Chandrika P. Kulatilleke, Scott N. Goldie, Mary Jane Heeg, L. A. Ochrymowycz, and D. B. Rorabacher pp 1444 - 1453; DOI: 10.1021/ic991019+ |
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Molybdenum(V) on an Oxide String. Formation and Solution Stability of the Linear Complex (-trans-Dioxo(tetraphenylporphyrinato)molybdenato(V))bis(oxo(tetraphenylporphyrinato)molybdenum(V)) Perchlorate Brent J. Hamstra, Beisong Cheng, Mary K. Ellison, and W. Robert Scheidt pp 1454 - 1457; DOI: 10.1021/ic9906003 |
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Catalysis and Kinetics of Hydrogen Peroxide Disproportionation by Dinuclear Manganese(III) Complexes of 1,5-Bis(salicylidenamino)pentan-3-ol and the 5-Bromophenyl-Substituted Derivative Claudia Palopoli, Benoit Chansou, Jean-Pierre Tuchagues, and Sandra Signorella pp 1458 - 1462; DOI: 10.1021/ic991030+ |
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Conformation of Heterocycles Controlled by the Existence of Unusual C-H···X Hydrogen Bonds: Syntheses and Structure Determination of Aluminum Aryloxides Bao-Tsan Ko, Ying-Chieh Chao, and Chu-Chieh Lin pp 1463 - 1469; DOI: 10.1021/ic9909835 |
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Hydrothermal Synthesis and Magnetic Behavior of a Novel Layered Coordination Polymer Generated from Manganese(II) Adipate YooJin Kim and Duk-Young Jung pp 1470 - 1475; DOI: 10.1021/ic991119f |
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The First Organo-Templated Cobalt Phosphate with a Zeolite Topology Hong-Ming Yuan, Jie-Sheng Chen, Guang-Shan Zhu, Ji-Yang Li, Ji-Hong Yu, Guang-Di Yang, and Ru-Ren Xu pp 1476 - 1479; DOI: 10.1021/ic990719b |
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Synthesis and Characterization of Racemic Mixture and Meso Isomers of Bis(trans-2-aminocyclohexyl)aminepentaacetic Acid and the Stabilities of Their Gd(III) Complexes Yizhen Sun, Arthur E. Martell, Joseph H. Reibenspies, David E. Reichert, and Michael J. Welch pp 1480 - 1486; DOI: 10.1021/ic991189m |
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Crystallographic, X-ray Absorption, and IR Studies of Solid- and Solution-State Structures of Tris(nitrato) N,N,N',N'-Tetraethylmalonamide Complexes of Lanthanides. Comparison with the Americium Complex C. Den Auwer, M. C. Charbonnel, M. G. B. Drew, M. Grigoriev, M. J. Hudson, P. B. Iveson, C. Madic, M. Nierlich, M. T. Presson, R. Revel, M. L. Russell, and P. Thuéry pp 1487 - 1495; DOI: 10.1021/ic990817x |
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Trigonal Prismatic vs Octahedral Coordination Geometry: Syntheses and Structural Characterization of Hexakis(arylthiolato) Zirconate Complexes Jan C. Friese, Arndt Krol, Carsten Puke, Kristin Kirschbaum, and Dean M. Giolando pp 1496 - 1500; DOI: 10.1021/ic991402e |
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Tetranuclear Manganese Carboxylate Complexes with a Trigonal Pyramidal Metal Topology via Controlled Potential Electrolysis Sheyi Wang, Michael S. Wemple, Jae Yoo, Kirsten Folting, John C. Huffman, Karl S. Hagen, David N. Hendrickson, and George Christou pp 1501 - 1513; DOI: 10.1021/ic991068m |
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Evidence of Bilayer Structure in V2O5 Xerogel Marco Giorgetti, Stefano Passerini, William H. Smyrl, and Mario Berrettoni pp 1514 - 1517; DOI: 10.1021/ic9913233 |
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Cis-Influence of Hydroporphyrin Macrocycles on Axial Ligation Equilibria and Alkyl Exchange Reactions of Alkylcobalt(III) Porphyrin Complexes Alan M. Stolzenberg and Jack S. Summers pp 1518 - 1524; DOI: 10.1021/ic991304t |
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LiEuPSe4 and KEuPSe4: Novel Selenophosphates with the Tetrahedral [PSe4]3- Building Block Jennifer A. Aitken, Konstantinos Chondroudis, Victor G. Young, Jr., and Mercouri G. Kanatzidis pp 1525 - 1533; DOI: 10.1021/ic991090f |
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Molecular Lattice Fragment of LiI. Crystal Structure and ab Initio Calculations of [LiI(NEt3)]4 C. Doriat, R. Köppe, E. Baum, G. Stösser, H. Köhnlein, and H. Schnöckel pp 1534 - 1537; DOI: 10.1021/ic9903432 |
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Electronic Structures and Properties of Eight-Coordinate Metal-Polyarsenic Complexes MAs8n- (M = V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re) Jun Li and Kechen Wu pp 1538 - 1544; DOI: 10.1021/ic9902166 |
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Structural Features of Ag[AuF4] and Ag[AuF6] and the Stuctural Relationship of Ag[AgF4]2 and Au[AuF4]2 to Ag[AuF4]2 Oliver Graudejus, Angus P. Wilkinson, and Neil Bartlett pp 1545 - 1548; DOI: 10.1021/ic991178t |
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Kinetics of Manganese(III) Acetate in Acetic Acid: Generation of Mn(III) with Co(III), Ce(IV), and Dibromide Radicals; Reactions of Mn(III) with Mn(II), Co(II), Hydrogen Bromide, and Alkali Bromides Xiang-Dong Jiao and James H. Espenson pp 1549 - 1554; DOI: 10.1021/ic991213w |
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Controlled Molecular Motions in Copper-Complexed Rotaxanes: An XAS Study Jean-Marc Kern, Laurence Raehm, Jean-Pierre Sauvage, Bernadette Divisia-Blohorn, and Pierre-Louis Vidal pp 1555 - 1560; DOI: 10.1021/ic991163v |
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Syntheses and Structures of Methyltris(pyrazolyl)silane Complexes of the Group 6 Metals Eric E. Pullen, Daniel Rabinovich, Christopher D. Incarvito, Thomas E. Concolino, and Arnold L. Rheingold pp 1561 - 1567; DOI: 10.1021/ic990945l |
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Unusual Ligand Coordination for Cesium Jeffrey C. Bryan, Konstantinos Kavallieratos, and Richard A. Sachleben pp 1568 - 1572; DOI: 10.1021/ic991203v |
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Electronic Effects on the Rates of Coupled Two-Electron/Halide Self-Exchange Reactions of Substituted Ruthenocenes Timothy M. Shea and T. David Westmoreland pp 1573 - 1577; DOI: 10.1021/ic990690b |
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Solution and Solid-State Structures of Phosphine Adducts of Monomeric Zinc Bisphenoxide Complexes. Importance of These Derivatives in CO2/Epoxide Copolymerization Processes Donald J. Darensbourg, Marc S. Zimmer, Patrick Rainey, and David L. Larkins pp 1578 - 1585; DOI: 10.1021/ic990594a |
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Interactions between Divalent Metal Ions and an Octacoordinate Macrocyclic Ligand Haiyang He, Arthur E. Martell, Ramunas J. Motekaitis, and Joseph H. Reibenspies pp 1586 - 1592; DOI: 10.1021/ic9911264 |
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New Approach to Ru(II) Pincer Ligand Chemistry. Bis(tert-butylaminomethyl)pyridine Coordinated to Ruthenium(II) Christian Gemel, Kirsten Folting, and Kenneth G. Caulton pp 1593 - 1597; DOI: 10.1021/ic990737t |
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Sugar Binding to VO3+. Synthesis and Structure of a New Mannopyranoside Vanadate Kajal Krishna Rajak, Bharat Baruah, Sankar Prasad Rath, and Animesh Chakravorty pp 1598 - 1601; DOI: 10.1021/ic9910460 |
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A Linear, Four-Spin Mn(II)-Nitronyl-Nitroxide-Substituted Phosphine Oxide System Exhibiting Both Antiferro- and Ferromagnetic Interactions Corinne Rancurel, Daniel B. Leznoff, Jean-Pascal Sutter, Philippe Guionneau, Daniel Chasseau, Janis Kliava, and Olivier Kahn pp 1602 - 1605; DOI: 10.1021/ic9909678 |
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Synthesis of Nanocrystalline CuMS2 (M = In or Ga) through a Solvothermal Process Qingyi Lu, Junqing Hu, Kaibin Tang, Yitai Qian, Guien Zhou, and Xianming Liu pp 1606 - 1607; DOI: 10.1021/ic9911365 |
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An Unusual Metal-Mediated Formation of an Asymmetrical Carboxylate-Bridged Dinuclear Copper(II) Complex Heike Keutel, Daniel Seidel, Martin Klussmann, and Helmar Görls pp 1608 - 1610; DOI: 10.1021/ic990374x |
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Synthesis Crystal Structure and Magnetic Properties of the Trinuclear Nickel(II) Complex Bis[(-thiocyanato-N)bis(-pyridazine-N1,N2)bis(thiocyanato-N)(pyridazine-N1)nickel(II)- N,N1,N1']nickel(II) Juan Cano, Giovanni De Munno, Francesc Lloret, and Miguel Julve pp 1611 - 1614; DOI: 10.1021/ic991219l |
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Synthesis of Cl2InN3, Br2InN3, and Related Adducts Cory Steffek, Jeff McMurran, Brett Pleune, J. Kouvetakis, Thomas E. Concolino, and Arnold L. Rheingold pp 1615 - 1617; DOI: 10.1021/ic990387a |
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The Mn(OESPz) (OESPz2- = 2,3,7,8,12,13,17,18-Octakis(ethylsulfanyl)- 5,10,15,20-tetraazaporphyrinato Dianion) Complex as an in Situ Regenerative Defluorinating Agent Giampaolo Ricciardi, Sandra Belviso, and Francesco Lelj pp 1618 - 1620; DOI: 10.1021/ic981120z |
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A Bibenzimidazole-Containing Ruthenium(II) Complex Acting as a Cation-Driven Molecular Switch Sven Rau, Torsten Büttner, Christian Temme, Mario Ruben, Helmar Görls, Dirk Walther, Marco Duati, Stefano Fanni, and Johannes G. Vos pp 1621 - 1624; DOI: 10.1021/ic991225h |
Issue 8
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Structure and Magnetic Characteristics of an Oxalate-Bridged U(IV)-Mn(II) Three-Dimensional Network Klaus P. Mörtl, Jean-Pascal Sutter, Stéphane Golhen, Lahcène Ouahab, and Olivier Kahn pp 1626 - 1627; DOI: 10.1021/ic9911825 |
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Synthesis, Characterization, and Polymerization Activity of [Bis(4,4'-bis(neophyldimethylsilylmethyl)-2,2'-bipyridyl)copper(I)]+CuBr2- and Implications for Copper(I) Catalyst Structures in Atom Transfer Radical Polymerization Amy T. Levy, Marilyn M. Olmstead, and Timothy E. Patten pp 1628 - 1634; DOI: 10.1021/ic990567k |
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Titanium Alkoxide Complexes: Condensed Phase and Gas Phase Comparisons Steven M. Damo, Kin-Chung Lam, Arnold Rheingold, and Marc A. Walters pp 1635 - 1638; DOI: 10.1021/ic990844n |
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Adduct Formation between Alkali Metal Ions and Divalent Metal Salicylaldimine Complexes Having Methoxy Substituents. A Structural Investigation D. Cunningham, P. McArdle, M. Mitchell, N. Ní Chonchubhair, M. O'Gara, Federico Franceschi, and Carlo Floriani pp 1639 - 1649; DOI: 10.1021/ic990496p |
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Synthesis, Spectroscopic Characterization, and Crystal Structure of the Bimetallic Complex [Ni2(-CO)(CO)2(-NH(PPh2)2)2] Eugenio Simón-Manso, Mauricio Valderrama, Verónica Arancibia, Yamil Simón-Manso, and Daphne Boys pp 1650 - 1654; DOI: 10.1021/ic990773s |
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1H- and 2H-T1 Relaxation Behavior of the Rhodium Dihydrogen Complex [(Triphos)Rh(2-H2)H2]+ Vladimir I. Bakhmutov, Claudio Bianchini, Maurizio Peruzzini, Francesco Vizza, and Evgeny V. Vorontsov pp 1655 - 1660; DOI: 10.1021/ic990667q |
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Formation of Charge-Transfer Complexes from Neutral Bis(porphyrin) Sandwiches James P. Collman, Jonathan L. Kendall, Judy L. Chen, K. A. Collins, and Jean-Claude Marchon pp 1661 - 1667; DOI: 10.1021/ic9907516 |
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Two New One-Dimensional Compounds with End-to-End Dicyanamide as a Bridging Ligand: Syntheses and Structural Characterization of trans-[Mn(4-bzpy)2(N(CN)2)2]n and cis-[Mn(Bpy)(N(CN)2)2]n, (4-bzpy = 4-benzoylpyridine; bpy = 2,2'-bipyridyl) Albert Escuer, Franz A. Mautner, Núria Sanz, and Ramon Vicente pp 1668 - 1673; DOI: 10.1021/ic990905h |
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Synthesis and Characterization of Square Planar Nickel(II)-Arylthiolate Complexes with the Biphenyl-2,2'-dithiolate Ligand Edurne Erkizia and Rebecca R. Conry pp 1674 - 1679; DOI: 10.1021/ic990931f |
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Synthesis and Structure of Organic-Soluble Binuclear Molecular Phosphonates of Tantalum, Molybdenum, and Tungsten Olexandr I. Guzyr, Rolf Siefken, Debashis Chakraborty, Herbert W. Roesky, and Markus Teichert pp 1680 - 1683; DOI: 10.1021/ic990966f |
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Icosahedron Oligomerization and Condensation in Intermetallic Compounds. Bonding and Electronic Requirements Monique Tillard-Charbonnel, Alain Manteghetti, and Claude Belin pp 1684 - 1696; DOI: 10.1021/ic9910817 |
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Eight- and 16-Membered Cyanuric-Sulfanuric Ring Systems: C2N4S2 C2N3S Ring Contraction Tristram Chivers, Monica P. Gibson, Masood Parvez, and Ignacio Vargas-Baca pp 1697 - 1704; DOI: 10.1021/ic991314u |
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Syntheses and Structures of Quinuclidine-Stabilized Amido- and Azidogallanes Bing Luo, Victor G. Young, Jr., and Wayne L. Gladfelter pp 1705 - 1709; DOI: 10.1021/ic9910110 |
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Equilibrium and Kinetic Studies of the Aquation of the Dinuclear Platinum Complex [{trans-PtCl(NH3)2}2(-NH2(CH2)6NH2)]2+: pKa Determinations of Aqua Ligands via [1H,15N] NMR Spectroscopy Murray S. Davies, John W. Cox, Susan J. Berners-Price, Walter Barklage, Yun Qu, and Nicholas Farrell pp 1710 - 1715; DOI: 10.1021/ic991104h |
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Synthesis and Crystal Structure of a Novel Germanate: (NH4)4[(GeO2)3(GeO1.5F3)2]·0.67H2O Tony Conradsson, Xiaodong Zou, and Mike S. Dadachov pp 1716 - 1720; DOI: 10.1021/ic9911217 |
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Kinetics and Mechanism of Complex Formation of Nickel(II) with Tetra-N-alkylated Cyclam in N,N-Dimethylformamide (DMF): Comparative Study on the Reactivity and Solvent Exchange of the Species Ni(DMF)62+ and Ni(DMF)5Cl+ Horst Elias, Rüdiger Schumacher, Jörg Schwamberger, Thorsten Wittekopf, Lothar Helm, André E. Merbach, and Stefan Ulrich pp 1721 - 1727; DOI: 10.1021/ic991139h |
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Kinetics and Mechanism for Reduction of the Anticancer Prodrug trans,trans,trans-[PtCl2(OH)2(c-C6H11NH2)(NH3)] (JM335) by Thiols Kelemu Lemma, Tiesheng Shi, and Lars I. Elding pp 1728 - 1734; DOI: 10.1021/ic991351l |
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Weakly Coordinating Anions HA2- Generated from Oxoanions A- and Their Conjugate Acids. Coordination Equilibria, Ionic Conductivities, and the Structures of {Cu2(H(CH3SO3)2)4}n and [Cu(CO)(H(CF3CO2)2)]2 Oleg G. Polyakov, Benjamin G. Nolan, Benjamin P. Fauber, Susie M. Miller, Oren P. Anderson, and Steven H. Strauss pp 1735 - 1742; DOI: 10.1021/ic991165f |
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Heteronuclear Chains of Four Metal Atoms Including One Quadruply Bonded Dimetal Unit. Dichromium and Dimolybdenum Compounds with Appended Copper(I) Atoms F. Albert Cotton, Carlos A. Murillo, Lindsay E. Roy, and Hong-Cai Zhou pp 1743 - 1747; DOI: 10.1021/ic991274u |
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Studies of Dirhodium(II) Tetra(trifluoroacetate). 5. Remarkable Examples of the Ambidentate Character of Dimethyl Sulfoxide F. Albert Cotton, Evgeny V. Dikarev, Marina A. Petrukhina, and Salah-Eddine Stiriba pp 1748 - 1754; DOI: 10.1021/ic9913076 |
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The CrIIL Reduction of [2Fe-2S] Ferredoxins and Site of Attachment of CrIII Using 1H NMR and Site-Directed Mutagenesis S.-C. Im, J. A. R. Worrall, G. Liu, A. Aliverti, G. Zanetti, C. Luchinat, I. Bertini, and A. G. Sykes pp 1755 - 1764; DOI: 10.1021/ic991127w |
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Emission and Metal- and Ligand-Centered-Redox Characteristics of the Hexarhenium(III) Clusters trans- and cis-[Re6(3-S)8Cl4(L)2]2-, Where L Is a Pyridine Derivative or Pyrazine Takashi Yoshimura, Keisuke Umakoshi, Yoichi Sasaki, Shoji Ishizaka, Haeng-Boo Kim, and Noboru Kitamura pp 1765 - 1772; DOI: 10.1021/ic991282a |
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Novel Gallium Phosphate Framework Encapsulating Trinuclear Mn3(H2O)6O8 Cluster: Hydrothermal Synthesis and Characterization of Mn3(H2O)6Ga4(PO4)6 Kuei-Fang Hsu and Sue-Lein Wang pp 1773 - 1778; DOI: 10.1021/ic991340s |
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Orientation of Iron Bleomycin and Porphyrin Complexes on DNA Fibers Makoto Chikira, Takamasa Iiyama, Katsuyuki Sakamoto, William E. Antholine, and David H. Petering pp 1779 - 1786; DOI: 10.1021/ic991365r |
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C6, C7, and C8 Perfluoroalkyl-Substituted Phosphinic Acids Rajendra P. Singh and Jean'ne M. Shreeve pp 1787 - 1789; DOI: 10.1021/ic991392h |
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Ternary Rare-Earth Selenides with the U3ScS6 Structure Type: Synthesis, Characterization, and Some Magnetic Properties of Ln3TSe6 (Ln = Sm, Gd; T = In, Cr) and Tb3CrSe6 Olivier Tougait and James A. Ibers pp 1790 - 1794; DOI: 10.1021/ic9914802 |
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Improved Procedures for the Generation of Diborane from Sodium Borohydride and Boron Trifluoride Josyula V. B. Kanth and Herbert C. Brown pp 1795 - 1802; DOI: 10.1021/ic0000911 |
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Synthesis, X-ray Powder Structure, and Magnetic Properties of the New, Weak Ferromagnet Iron(II) Phenylphosphonate Carlo Bellitto, Fulvio Federici, Angela Altomare, Rosanna Rizzi, and Said A. Ibrahim pp 1803 - 1808; DOI: 10.1021/ic9914995 |
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Layered K4[Re6S10(CN)2] and Chainlike K4[Re6Se10(CN)4]: New Types of Chalcocyanide Cluster Compounds with Bridging Chalcogenide Ligands Yuri V. Mironov, Vladimir E. Fedorov, Craig C. McLauchlan, and James A. Ibers pp 1809 - 1811; DOI: 10.1021/ic990936c |
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Hydrogen-Deuterium Exchange in Decaborane(14): Mechanistic Studies Donald F. Gaines and Herbert Beall pp 1812 - 1813; DOI: 10.1021/ic991032u |
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An Inorganic Application of Transient Direct Current Photoconductivity: Corroboration of a Charge-Transfer Assignment for the Luminescing States of Pt(dpphen)(ecda) Frederik W. M. Vanhelmont, Robert C. Johnson, and Joseph T. Hupp pp 1814 - 1816; DOI: 10.1021/ic9911670 |
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Transient DC Photocurrent Investigation of Charge Redistribution within Re(CO)3Cl(2,2'-bipyridine): An Unexpected Decrease in Molecular Dipole Moment upon Emissive Excited-State Formation Frederik W. M. Vanhelmont and Joseph T. Hupp pp 1817 - 1819; DOI: 10.1021/ic991285n |
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Synthesis and Structural Characterization of a New Open-Framework Tin(II) Phosphate: [Sn4(PO4)3]-·0.5[C4N2H12]2+ Yun-Ling Liu, Guang-Shan Zhu, Jie-Sheng Chen, Li-Yan Na, Jia Hua, Wen-Qin Pang, and Ru-Ren Xu pp 1820 - 1822; DOI: 10.1021/ic991241e |
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Complexation of Co(DBF2)2 by N-Methylimidazole in Acetonitrile: Formation Constants and 1H NMR Shifts and Relaxation Times Kefei Wang and R. B. Jordan pp 1823 - 1827; DOI: 10.1021/ic9910561 |
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Nanophase Cobalt Oxyhydroxide Mineral Synthesized within the Protein Cage of Ferritin Trevor Douglas and Victoria T. Stark pp 1828 - 1830; DOI: 10.1021/ic991269q |
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Polynuclear Carboxylato-Bridged Iron(II) Clusters: Synthesis, Structure, and Host-Guest Chemistry Sanjay K. Mandal, Victor G. Young, Jr., and Lawrence Que, Jr. pp 1831 - 1833; DOI: 10.1021/ic9912676 |
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Stereochemical Activity of the Metal-Centered Lone Electron Pair in Group 14 Metallocenes. Crystal Structure of the Linear Sandwich Complex [C5(iPr)3H2]2Pb. David J. Burkey, Timothy P. Hanusa, and John C. Huffman pp 1834 - 1834; DOI: 10.1021/ic000222y |
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EPR Spectra from "EPR-Silent" Species: High-Field EPR Spectroscopy of Aqueous Chromium(II) Joshua Telser, Luca A. Pardi, J. Krzystek, and Louis-Claude Brunel pp 1834 - 1834; DOI: 10.1021/ic9902828 |
Issue 9
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Direct Hydrolytic Route to Molecular Oxo-Hydroxo Lanthanide Clusters Ruiyao Wang, Michael D. Carducci, and Zhiping Zheng pp 1836 - 1837; DOI: 10.1021/ic991391p |
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A Redox Reaction To Synthesize Nanocrystalline Cu2-xSe in Aqueous Solution Weixin Zhang, Xiaoming Zhang, Lei Zhang, Jianxin Wu, Zehua Hui, Youwei Cheng, Juewen Liu, Yi Xie, and Yitai Qian pp 1838 - 1839; DOI: 10.1021/ic990871d |
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Preparation, Characterization, X-ray Crystal Structure, and Energetics of Cesium 5-Cyano-1,2,3,4-Tetrazolate: Cs[NCCNNNN] Hans P. H. Arp, Andreas Decken, Jack Passmore, and Dale J. Wood pp 1840 - 1848; DOI: 10.1021/ic990828q |
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Structure of Triamidoaluminum Complexes: A Theoretical ab Initio/IMOMM Study Paul Fleurat-Lessard and François Volatron pp 1849 - 1854; DOI: 10.1021/ic991386l |
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Alkaline Earth Complexes of 1,4,7,10-Tetrakis(2-hydroxyethyl)- and 1,4,7,10-Tetrakis(2-methoxyethyl)-1,4,7,10-tetraazacyclododecane: An Equilibrium and Kinetic Study Ramesh Dhillon, Stephen F. Lincoln, Samer Madbak, Ashley K. W. Stephens, Kevin P. Wainwright, and Sonya L. Whitbread pp 1855 - 1858; DOI: 10.1021/ic990636v |
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Trinuclear N,N-Bridged Copper(II) Complexes Involving a Cu3OH Core: [Cu3(3-OH)L3A(H2O)2]A·(H2O)x {L = 3-Acetylamino-1,2,4-triazolate; A = CF3SO3, NO3, ClO4; x = 0, 2} Synthesis, X-ray Structures, Spectroscopy, and Magnetic Properties Sacramento Ferrer, Jaap G. Haasnoot, Jan Reedijk, Edgar Müller, Marina Biagini Cingi, Maurizio Lanfranchi, Anna Maria Manotti Lanfredi, and Joan Ribas pp 1859 - 1867; DOI: 10.1021/ic981393u |
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Wide Spectral Range Nonlinear Optical Crystals of One-Dimensional Coordination Solids [Et4N][Cd(SCN)3] and [Et4N][Cd(SeCN)3] and the General Design Criteria for [R4N][Cd(XCN)3] (Where R = Alkyl and X = S, Se, Te) as NLO Crystals Hong Zhang, David E. Zelmon, Gary E. Price, and Boon K. Teo pp 1868 - 1873; DOI: 10.1021/ic9912833 |
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Synthesis, Structure, and Magnetic Characterization of a Hysteretic Charge-Transfer Salt Metamagnet, Decamethylferrocenium 2,3-Dicyano-1,4-Naphthoquinonide, [Fe(Cp*)2][DCNQ] Gordon T. Yee, Michael J. Whitton, Roger D. Sommer, Christoph M. Frommen, and William M. Reiff pp 1874 - 1877; DOI: 10.1021/ic991188u |
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Solution Equilibria of Tetrakis(ethyisocyanide)platinum(II) with Tetracyanoplatinate(II): Equilibria and Thermodynamics of the Formation of Di-, Tri-, and Tetraplatinum Species P. J. Martellaro and E. H. Abbott pp 1878 - 1881; DOI: 10.1021/ic990659+ |
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Inversion of the Cis Geometry Requirement for Cytotoxicity in Structurally Novel Platinum(II) Complexes Containing the Bidentate N,O-Donor Pyridin-2-yl-acetate Ulrich Bierbach, Michal Sabat, and Nicholas Farrell pp 1882 - 1890; DOI: 10.1021/ic991259p |
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Synthesis, Crystal Structure, EXAFS, and Magnetic Properties of Catena [-Tris(1,2-bis(tetrazol-1-yl)propane-N1,N1')iron(II)] Bis(perchlorate). First Crystal Structure of an Iron(II) Spin-Crossover Chain Compound Petra J. van Koningsbruggen, Yann Garcia, Olivier Kahn, Léopold Fournès, Huub Kooijman, Anthony L. Spek, Jaap G. Haasnoot, Jacques Moscovici, Karine Provost, Alain Michalowicz, Franz Renz, and Philipp Gütlich pp 1891 - 1900; DOI: 10.1021/ic991118n |
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The Synthesis and Characterization of Bis-Substituted Derivatives of the [a2-B20H18]4- Anion and the Interconversion of Isomers Rachel A. Watson-Clark, Kenneth Shelly, and M. Frederick Hawthorne pp 1901 - 1906; DOI: 10.1021/ic991321i |
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Triribbed-Functionalized Clathrochelate Iron(II) Dioximates as a New and Promising Tool To Obtain Polynucleating and Polynuclear Compounds with Improved Properties Yan Z. Voloshin, Oleg A. Varzatskii, Tatyana E. Kron, Vitaly K. Belsky, Valery E. Zavodnik, Nataly G. Strizhakova, and Alexey V. Palchik pp 1907 - 1918; DOI: 10.1021/ic990476n |
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Structural Distortions in mer-M(H)3(NO)L2 (M = Ru, Os) and Their Influence on Intramolecular Fluxionality and Quantum Exchange Coupling Dmitry V. Yandulov, Dejian Huang, John C. Huffman, and Kenneth G. Caulton pp 1919 - 1932; DOI: 10.1021/ic991452j |
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Syntheses, Molecular Structures, and Vibrational Spectra of Chloropentacarbonylrhodium(III) and -iridium(III) Undecafluorodiantimonate(V), [Rh(CO)5Cl][Sb2F11]2 and [Ir(CO)5Cl][Sb2F11]2: An Experimental and Density Functional Study Helge Willner, Christian Bach, Rudolf Wartchow, Changqing Wang, Steven J. Rettig, James Trotter, Volker Jonas, Walter Thiel, and Friedhelm Aubke pp 1933 - 1942; DOI: 10.1021/ic9911926 |
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Metal-Containing Ligands for Mixed-Metal Polymers: Novel Cu(II)-Ag(I) Mixed-Metal Coordination Polymers Generated from [Cu(2-methylpyrazine-5-carboxylate)2(H2O)]·3H2O and Silver(I) Salts Yu-Bin Dong, Mark D. Smith, and Hans-Conrad zur Loye pp 1943 - 1949; DOI: 10.1021/ic991475y |
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Kinetics and Mechanism of Complex Formation Reactions in the Iron(III)-Phosphate Ion System at Large Iron(III) Excess. Formation of a Tetranuclear Complex Gábor Lente, M. Elizabeth A. Magalhães, and István Fábián pp 1950 - 1954; DOI: 10.1021/ic991017p |
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Structure, Physical, and Photophysical Properties of Platinum(II) Complexes Containing Bidentate Aromatic and Bis(diphenylphosphino)methane as Ligands J. DePriest, G. Y. Zheng, N. Goswami, D. M. Eichhorn, C. Woods, and D. P. Rillema pp 1955 - 1963; DOI: 10.1021/ic991306d |
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Chloroaluminate Ionic Liquids as Reagents for Isolating Soluble Hexanuclear Zirconium Halide Cluster Compounds Dong Sun and Timothy Hughbanks pp 1964 - 1968; DOI: 10.1021/ic9913785 |
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Synthesis, Structure, and Magnetic Properties of Co2{[N(CN)2]4bpym}·H2O and M{[N(CN)2]2bpym}·H2O (M = Mn, Fe, Co; bpym = 2,2'-Bipyrimidine) Shireen R. Marshall, Christopher D. Incarvito, Jamie L. Manson, Arnold L. Rheingold, and Joel S. Miller pp 1969 - 1973; DOI: 10.1021/ic991244r |
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Kinetics and Mechanisms of the Oxidation of Hydrazinium Ion (N2H5+) by Aqueous Br2, Cl2, and BrCl. Electrophilicity Scale for Halogens and Interhalogens Zhongjiang Jia, Murad G. Salaita, and Dale W. Margerum pp 1974 - 1978; DOI: 10.1021/ic991220k |
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Spin-State Variation in Solid State and Solution of Mononuclear Iron(II) 1,4,7-Trimethyl-1,4,7-triazacyclonane Complexes David W. Blakesley, Sonha C. Payne, and Karl S. Hagen pp 1979 - 1989; DOI: 10.1021/ic990584+ |
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Coordination Polymers: Structural Transformation from Two to Three Dimensions through Ligand Conformation Change Zhan Shi, Lirong Zhang, Shan Gao, Guoyu Yang, Jia Hua, Lu Gao, and Shouhua Feng pp 1990 - 1993; DOI: 10.1021/ic991355q |
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EPR Characterization of the Products Formed after Photolysis of [CoIII(Salen)(CH3)(H2O)] and [CoIII(SaltMe)(CH3)(H2O)] in the Presence of N- and P-donor Bases João Gomes and Baltazar de Castro pp 1994 - 1997; DOI: 10.1021/ic990919n |
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SiONB Unit as Reference for Blocked Si···N Interactions in SiON Compounds Norbert W. Mitzel, Udo Losehand, and Bernhard Bauer pp 1998 - 2000; DOI: 10.1021/ic991400u |
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Titanium and Niobium Imido Complexes Derived from Diamidoamine Ligands Philip E. Collier, Stephen M. Pugh, Howard S. C. Clark, Jason B. Love, Alexander J. Blake, F. Geoffrey N. Cloke, and Philip Mountford pp 2001 - 2005; DOI: 10.1021/ic991014c |
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A Decairon Cluster Devoid of Polydentate Ligands S. Asirvatham, M. A. Khan, and K. M. Nicholas pp 2006 - 2007; DOI: 10.1021/ic9911668 |
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Synthesis and Characterization of (hfac)In(CH3)2: A Volatile Compound Useful for CVD of Indium and Indium-Containing Materials Chongying Xu, Thomas H. Baum, Ilia Guzei, and Arnold L. Rheingold pp 2008 - 2010; DOI: 10.1021/ic990266a |
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Low-Melting, Mononuclear Tetrahydrofuran Complexes of M(2,2,6,6-tetramethylheptane-3,5-dionate)2 (M = Ba, Sr) and Related Analogues Witold Paw, Thomas H. Baum, Kin-Chung Lam, and Arnold L. Rheingold pp 2011 - 2014; DOI: 10.1021/ic990641z |
Issue 10
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First Light-Emitting Neutral Molecular Rectangles T. Rajendran, Bala Manimaran, Fang-Yuan Lee, Gene-Hsiang Lee, Shie-Ming Peng, Chong Mou Wang, and Kuang-Lieh Lu pp 2016 - 2017; DOI: 10.1021/ic9912474 |
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Aquacobalamin (Vitamin B12a) Does Not Bind NO in Aqueous Solution. Nitrite Impurities Account for Observed Reaction Maria Wolak, Grazyna Stochel, Mohamed Hamza, and Rudi van Eldik pp 2018 - 2019; DOI: 10.1021/ic991266d |
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Structurally Reinforced Tetraazamacrocyclic Complexes Paul V. Bernhardt and Philip C. Sharpe pp 2020 - 2025; DOI: 10.1021/ic9906353 |
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New Rubidium Zinc Hydrogen Phosphate, Rb2Zn2(HPO4)3: Synthesis, Crystal Structure, and 31P Single-Crystal NMR Torben R. Jensen, Rita G. Hazell, Thomas Vosegaard, and Hans J. Jakobsen pp 2026 - 2032; DOI: 10.1021/ic9906757 |
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Calix[4]arenes as Selective Extracting Agents. An NMR Dynamic and Conformational Investigation of the Lanthanide(III) and Thorium(IV) Complexes Bernard Lambert, Vincent Jacques, Alexander Shivanyuk, Susan E. Matthews, Abdi Tunayar, Marc Baaden, Georges Wipff, Volker Böhmer, and Jean F. Desreux pp 2033 - 2041; DOI: 10.1021/ic990683n |
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Preparation, X-ray Crystal Structure Determination, Lattice Potential Energy, and Energetics of Formation of the Salt S4(AsF6)2·AsF3 Containing the Lattice-Stabilized Tetrasulfur [2+] Cation. Implications for the Understanding of the Stability of M42+ and M2+ (M = S, Se, and Te) Crystalline Salts T. Stanley Cameron, Isabelle Dionne, H. Donald Brooke Jenkins, Simon Parsons, Jack Passmore, and Helen K. Roobottom pp 2042 - 2052; DOI: 10.1021/ic990850j |
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Synthesis, X-ray Structure, Single-Crystal EPR and 1H NMR Studies of a Distorted Square Planar Cu(salEen)2(ClO4)2 Complex in a Novel Bilayered Architecture: salEen = N,N-Diethylethylenesalicylidenamine P. S. Subramanian, E. Suresh, and D. Srinivas pp 2053 - 2060; DOI: 10.1021/ic990874q |
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Solvothermal Route to Tin Monoselenide Bulk Single Crystal with Different Morphologies Bin Li, Yi Xie, Jiaxing Huang, and Yitai Qian pp 2061 - 2064; DOI: 10.1021/ic990964v |
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Bond Valence Sums in Coordination Chemistry. Calculation of the Oxidation State of Chromium in Complexes Containing Only Cr-O Bonds and a Redetermination of the Crystal Structure of Potassium Tetra(peroxo)chromate(V) Richard M. Wood, Khalil A. Abboud, Ruth C. Palenik, and Gus J. Palenik pp 2065 - 2068; DOI: 10.1021/ic990982c |
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Coordination Solids Derived from Cp*M(CN)3- (M = Rh, Ir) Stephen M. Contakes, Kevin K. Klausmeyer, and Thomas B. Rauchfuss pp 2069 - 2075; DOI: 10.1021/ic991037r |
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Observation of a Very Large Internal Hyperfine Field (62.4 T) in the Ferromagnetically Ordered State of the S = 1 -Iron(II) Octaethyltetraazaporphyrin W. M. Reiff, C. M. Frommen, G. T. Yee, and S. P. Sellers pp 2076 - 2079; DOI: 10.1021/ic990910l |
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Synthesis and Structure of Isomeric Palladium(II)-Pyrazole Chelate Complexes with and without an N-H Group as Hydrogen Bond Donor Douglas B. Grotjahn, David Combs, Sang Van, Gerardo Aguirre, and Fernando Ortega pp 2080 - 2086; DOI: 10.1021/ic990995q |
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Crystal Structures and Magnetic Properties of Metal Complexes Bearing Four Nitronyl Nitroxide Moieties in the Same Coordination Sphere Giancarlo Francese, Francisco M. Romero, Antonia Neels, Helen Stoeckli-Evans, and Silvio Decurtins pp 2087 - 2095; DOI: 10.1021/ic991236a |
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Synthesis and Dehydrative Condensation of Square-Planar Mono- and Dinuclear Hydroxopalladium Complexes with the Hydrotris(3,5-diisopropylpyrazolyl)borato Ligand (TpiPr2), TpiPr2(Py)Pd-OH, and (-OH)2{PdTpiPr2(H2O)}2 Munetaka Akita, Taichi Miyaji, Nobuyuki Muroga, Cordula Mock-Knoblauch, Waldemar Adam, Shiro Hikichi, and Yoshihiko Moro-oka pp 2096 - 2102; DOI: 10.1021/ic991034e |
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Paraoxon and Parathion Hydrolysis by Aqueous Molybdenocene Dichloride (Cp2MoCl2): First Reported Pesticide Hydrolysis by an Organometallic Complex Louis Y. Kuo and Nicholas M. Perera pp 2103 - 2106; DOI: 10.1021/ic991134k |
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Three New Polynuclear Copper(II) Complexes with the Symmetric [Cu(1,1-N3)2Cu]2+ Core and Pyridine Derivatives: Syntheses, Structure, and Magnetic Behavior Albert Escuer, Mohamed A. S. Goher, Franz A. Mautner, and Ramon Vicente pp 2107 - 2112; DOI: 10.1021/ic991135c |
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A Trigonal Planar 3-Fluorido Coinage Metal Complex from a Dicationic (Diphosphinomethane)copper(I) Dimer: Syntheses, Structures, and Bonding Bernd F. Straub, Frank Rominger, and Peter Hofmann pp 2113 - 2119; DOI: 10.1021/ic991173w |
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Crystal and Molecular Structure of an Eight-Coodinate N-Methyltetraphenylporphyrin Complex: Diacetato(N-methyl-meso-tetraphenylporphyrinato)thallium(III) Jo-Yu Tung, Jyh-Horung Chen, Feng-Ling Liao, Sue-Lein Wang, and Lian-Pin Hwang pp 2120 - 2124; DOI: 10.1021/ic991260o |
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Synthesis of Arene-Soluble Mixed-Metal Zr/Ce, Zr/Y, and Related {[Zr2(OiPr)9]LnX2}n Complexes Using the Dizirconium Nonaisopropoxide Ligand William J. Evans, Matthew A. Johnston, Michael A. Greci, Mohammad A. Ansari, Jason C. Brady, and Joseph W. Ziller pp 2125 - 2129; DOI: 10.1021/ic991272+ |
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Eu(III) Macrocyclic Complexes Promote Cleavage of and Bind to Models for the 5'-Cap of mRNA. Effect of Pendent Group and a Second Metal Ion Daniel M. Epstein, Lara L. Chappell, Homayoon Khalili, Ronald M. Supkowski, William DeW. Horrocks, Jr., and Janet R. Morrow pp 2130 - 2134; DOI: 10.1021/ic9912068 |
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Characterization of Divalent Metal Metavanadates by 51V Magic-Angle Spinning NMR Spectroscopy of the Central and Satellite Transitions Ulla Gro Nielsen, Hans J. Jakobsen, and J rgen Skibstedpp 2135 - 2145; DOI: 10.1021/ic991243z |
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Structural Studies of Silver(I) Coordination Polymers with Aryl Iodide Derived Ligands Ichiro Ino, Liang Ping Wu, Megumu Munakata, Masahiko Maekawa, Yusaku Suenaga, Takayoshi Kuroda-Sowa, and Yoshinobu Kitamori pp 2146 - 2151; DOI: 10.1021/ic991261g |
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The Lowest-Energy Ligand to Metal Charge-Transfer Absorption Band of trans-[OsO2(Malonate)2]2- Sandrine Stanislas, André L. Beauchamp, and Christian Reber pp 2152 - 2155; DOI: 10.1021/ic9912777 |
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Polyamine Macrocycles Incorporating a Phenolic Function: Their Synthesis, Basicity, and Coordination Behavior toward Metal Cations. Crystal Structure of a Binuclear Nickel Complex Paolo Dapporto, Mauro Formica, Vieri Fusi, Mauro Micheloni, Paola Paoli, Roberto Pontellini, Paolo Romani, and Patrizia Rossi pp 2156 - 2163; DOI: 10.1021/ic991291j |
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Oxidation of Sulfoxides by Hydrogen Peroxide, Catalyzed by Methyltrioxorhenium(VII) David W. Lahti and James H. Espenson pp 2164 - 2167; DOI: 10.1021/ic991292b |
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Divalent Samarium Compounds with Heavier Chalcogenolate (EPh; E = Se, Te) Ligands Deborah Freedman, Anna Kornienko, Thomas J. Emge, and John G. Brennan pp 2168 - 2171; DOI: 10.1021/ic9913278 |
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The Synthesis and the Molecular Structure of Hexakis(carbonyl)hexafluoroantimonato(V)tungsten(II) Undecafluorodiantimonate(V), [W(CO)6(FSbF5)][Sb2F11] Raimund Bröchler, Iona H. T. Sham, Matthias Bodenbinder, Volker Schmitz, Steven J. Rettig, James Trotter, Helge Willner, and Friedhelm Aubke pp 2172 - 2177; DOI: 10.1021/ic991331j |
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Synthesis and Characterization of Six-Coordinate "3 + 2" Mixed-Ligand Oxorhenium Complexes with the o-Diphenylphosphinophenolato Ligand and Tridentate Coligands of Different N and S Donor Atom Combinations Berthold Nock, Theodosia Maina, Francesco Tisato, Minas Papadopoulos, Catherine P. Raptopoulou, Aris Terzis, and Efstratios Chiotellis pp 2178 - 2184; DOI: 10.1021/ic991341k |
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Structural Studies of Indium and Thallium Insertion into the Framework of the Cluster Compound Ti2Nb6Cl14O4 Ekaterina Anokhina, Michael Essig, Cynthia Day, and Abdessadek Lachgar pp 2185 - 2188; DOI: 10.1021/ic9913536 |
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Pillared, 3D Metal-Organic Frameworks with Rectangular Channels. Synthesis and Characterization of Coordination Polymers Based on Tricadmium Carboxylates Owen R. Evans and Wenbin Lin pp 2189 - 2198; DOI: 10.1021/ic991360u |
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Cyclotriphosphorus Complexes: Solid-State Structures and Dynamic Behavior of Monoadducts with Carbonyl Fragments Massimo Di Vaira, Markus P. Ehses, Piero Stoppioni, and Maurizio Peruzzini pp 2199 - 2205; DOI: 10.1021/ic991380w |
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On the Nature of the Trigonal Fields in Hexaaquachromium(III) in Guanidinium Aluminum Sulfate Hexahydrate H. Riesen and L. Dubicki pp 2206 - 2211; DOI: 10.1021/ic991465x |
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Oxidation of Ammonia in Osmium Polypyridyl Complexes George M. Coia, Konstantinos D. Demadis, and Thomas J. Meyer pp 2212 - 2223; DOI: 10.1021/ic0000505 |
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Synthesis, Structural Characterization, and Theoretical Calculations of a New Copper(I)-Octahydrotriborate Complex C. Serrar, A. Es-sofi, A. Boutalib, A. Ouassas, and A. Jarid pp 2224 - 2226; DOI: 10.1021/ic990909m |
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Supramolecular Assemblies Based on Cucurbituril Adducts of Hydrogen-Bonded Molybdenum and Tungsten Incomplete Cuboidal Aqua Complexes Vladimir P. Fedin, Alexander V. Virovets, Maxim N. Sokolov, Danil N. Dybtsev, Olga A. Gerasko, and William Clegg pp 2227 - 2230; DOI: 10.1021/ic000026r |
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Ligand Control on Molecular Oxygen Activation by Rhodium Quinone Complexes Swati Dutta, Shie-Ming Peng, and Samaresh Bhattacharya pp 2231 - 2234; DOI: 10.1021/ic990999v |
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Molecular Ladders with Multiple Interpenetration of the Lateral Arms into the Squares of Adjacent Ladders Observed for [M2(4,4'-bpy)3(H2O)2(phba)2](NO3)2·4H2O (M = Cu2+ or Co2+; 4,4'-bpy = 4,4'-Bipyridine; phba = 4-Hydroxybenzoate) Ming-Liang Tong, Hong-Ji Chen, and Xiao-Ming Chen pp 2235 - 2238; DOI: 10.1021/ic991312+ |
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Three-Dimensional Oxalate-Bridged Heterometal Supramolecular Complex with a Large Helical Tunnel of 21.191 × 9.294 Å2 Hao-Yu Shen, Wei-Ming Bu, Dai-Zheng Liao, Zong-Hui Jiang, Shi-Ping Yan, and Geng-Lin Wang pp 2239 - 2242; DOI: 10.1021/ic991325n |
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10-Vertex closo-Boranes as Potential Linkers for Electronic Materials Serhii Pakhomov, Piotr Kaszynski, and Victor G. Young, Jr. pp 2243 - 2245; DOI: 10.1021/ic991350t |
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Direct Synthesis of a Bis(pyrazolyl)boratocopper(I) Complex: Synthesis and Characterization of [H2B(3,5-(CF3)2Pz)2]Cu(PPh3)2 Displaying an Unusual Coordination Mode for a Poly(pyrazolyl)borate Ligand H. V. Rasika Dias and Hui-Ling Lu pp 2246 - 2248; DOI: 10.1021/ic991385t |
Issue 11
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Guanidinium and Imidazolium Borates Containing the First Examples of an Isolated Nonaborate Oxoanion: [B9O12(OH)6]3- David M. Schubert, Mandana Z. Visi, and Carolyn B. Knobler pp 2250 - 2251; DOI: 10.1021/ic000217u |
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Synthesis, Characterization, Crystal Structures, and Reactions of Trigonal Bipyramidal Tin(IV) Complexes Containing a Tetradentate Tripodal Tristhiolatophosphine Ligand. Use in the One-Step Synthesis of an Iron(IV) Complex Kerry A. (Fusie) Clark, T. Adrian George, Tom J. Brett, Charles R. Ross, II, and Richard K. Shoemaker pp 2252 - 2253; DOI: 10.1021/ic991371n |
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Model for the Cofactor Formation Reaction of E. Coli Ribonucleotide Reductase. From a Diiron(II) Precursor to an FeIIIFeIV Species via a Peroxo Intermediate Vicki L. MacMurdo, Hui Zheng, and Lawrence Que Jr. pp 2254 - 2255; DOI: 10.1021/ic991482m |
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Symmetry-Lowering of the Phthalocyanine Chromophore by a C2 Type Axial Ligand Nagao Kobayashi, Atsuya Muranaka, and Kazuyuki Ishii pp 2256 - 2257; DOI: 10.1021/ic9914950 |
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Programming the Assembly of Two- and Three-Dimensional Architectures with DNA and Nanoscale Inorganic Building Blocks Chad A. Mirkin pp 2258 - 2272; DOI: 10.1021/ic991123r |
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Control of Oxo-Molybdenum Reduction and Ionization Potentials by Dithiolate Donors Matthew E. Helton, Nadine E. Gruhn, Rebecca L. McNaughton, and Martin L. Kirk pp 2273 - 2278; DOI: 10.1021/ic9912878 |
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Confined Space Synthesis. A Novel Route to Nanosized Zeolites Iver Schmidt, Claus Madsen, and Claus J. H. Jacobsen pp 2279 - 2283; DOI: 10.1021/ic991280q |
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Formation of a Novel Trinuclear Spirostannoxane Tin(IV) Compound. Crystal and Molecular Structure of [Sn(nBu)(Cl){(OCH2CH2S)2Sn(nBu)}2] and the Stannolane [(nBu)Sn(SCH2CH2O)SCH2CH2OH] Raymundo Cea-Olivares, L. Adriana Gómez-Ortiz, Verónica García-Montalvo, Rubén L. Gaviño-Ramírez, and Simón Hernández-Ortega pp 2284 - 2288; DOI: 10.1021/ic991318z |
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Crystal Structure and Optical Spectroscopy of Er2[Pt(CN)4]3·21H2O and Er2[Pt(CN)4]2·SO4·11.5H2O Andreas Loosli, Markus Wermuth, Hans-Ueli Güdel, Silvia Capelli, Jürg Hauser, and Hans-Beat Bürgi pp 2289 - 2293; DOI: 10.1021/ic991137x |
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A Controlled NO-Releasing Compound: Synthesis, Molecular Structure, Spectroscopy, Electrochemistry, and Chemical Reactivity of R,R,S,S-trans-[RuCl(NO)(cyclam)]2+(1,4,8,11-tetraazacyclotetradecane) D. R. Lang, J. A. Davis, L. G. F. Lopes, A. A. Ferro, L. C. G. Vasconcellos, D. W. Franco, E. Tfouni, A. Wieraszko, and M. J. Clarke pp 2294 - 2300; DOI: 10.1021/ic9912979 |
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Self-Assembly of Palladium(II) and Platinum(II) Complexes of 2-Hydroxypyrimidine to Novel Metallacalix[4]arenes. Receptor Properties through Multiple H-Bonding Interactions Jorge A. R. Navarro, Eva Freisinger, and Bernhard Lippert pp 2301 - 2305; DOI: 10.1021/ic991411n |
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Metallocyclopeptide Complexes with MII(S·Cys)4 Chromophores Alexander L. Nivorozhkin, Brent M. Segal, Kristin B. Musgrave, Steven A. Kates, Britt Hedman, Keith O. Hodgson, and R. H. Holm pp 2306 - 2313; DOI: 10.1021/ic990421l |
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Theoretical Studies of Molybdenum Peroxo Complexes [MoOn(O2)3-n(OPH3)] as Catalysts for Olefin Epoxidation Dirk V. Deubel, Jörg Sundermeyer, and Gernot Frenking pp 2314 - 2320; DOI: 10.1021/ic000204g |
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Ruthenium Bisbipyridine Complexes of Horse Heart Cytochrome c: Characterization and Comparative Intramolecular Electron-Transfer Rates Determined by Pulse Radiolysis and Flash Photolysis Jian Luo, K. Bal Reddy, Abdu S. Salameh, James F. Wishart, and Stephan S. Isied pp 2321 - 2329; DOI: 10.1021/ic9913381 |
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A Novel -Helix-Liked Metallohelicate Series and Their Structural Adjustments for the Isomorphous Substitution Yugen Zhang, Jianmin Li, Jinhua Chen, Qibin Su, Wei Deng, Masayoshi Nishiura, Tsuneo Imamoto, Xintao Wu, and Quanming Wang pp 2330 - 2336; DOI: 10.1021/ic990911d |
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Cs3AgAs4Se8 and CsAgAs2Se4: Selenoarsenates with Infinite 1[AsSe2]- Chains in Different Ag+ Coordination Environments M. Wachhold and M. G. Kanatzidis pp 2337 - 2343; DOI: 10.1021/ic000027j |
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Addition and Metathesis Reactions of Zirconium and Hafnium Imido Complexes Joseph L. Thorman, Ilia A. Guzei, Victor G. Young, Jr., and L. Keith Woo pp 2344 - 2351; DOI: 10.1021/ic9910007 |
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Nitric Oxide Binding to Ferric Cytochrome P450: A Computational Study Damián A. Scherlis, Cora B. Cymeryng, and Darío A. Estrin pp 2352 - 2359; DOI: 10.1021/ic991191d |
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Experimental Electron Density Analysis of Mn2(CO)10: Metal-Metal and Metal-Ligand Bond Characterization Riccardo Bianchi, Giuliana Gervasio, and Domenica Marabello pp 2360 - 2366; DOI: 10.1021/ic991316e |
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Synthesis and Characterization of the Dimethyl-Substituted Bisbenzimidazole Ligand and Its Manganese Complex Wai Him Kwok, Huichang Zhang, Pramatha Payra, Maosheng Duan, Shao-ching Hung, Dean H. Johnston, Judith Gallucci, Ewa Skrzypczak-Jankun, and Michael K. Chan pp 2367 - 2376; DOI: 10.1021/ic991322a |
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Synthesis and Characterization of Calcium Complexes Containing 2-Pyrazolato Ligands Dirk Pfeiffer, Mary Jane Heeg, and Charles H. Winter pp 2377 - 2384; DOI: 10.1021/ic991049c |
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Controlling Substitution Chemistry in Ruthenium(II) Systems. Synthesis of Heteroleptic Complexes Incorporating the [Ru([9]aneS3)]2+ Metal Center Sue Roche, Harry Adams, Sharon E. Spey, and James A. Thomas pp 2385 - 2390; DOI: 10.1021/ic991336g |
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Solid-State Synthesis and Characterization of Novel Aluminophosphates, A3Al2P3O12 (A = Na, K, Rb, Tl): Influence of A+ Ions on the Coordination of Aluminum R. Nandini Devi and K. Vidyasagar pp 2391 - 2396; DOI: 10.1021/ic991395u |
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Syntheses, Structures, and Fluxionality of Blue Luminescent Zinc(II) Complexes: Zn(2,2',2' '-tpa)Cl2, Zn(2,2',2' '-tpa)2(O2CCF3)2, and Zn(2,2',3' '-tpa)4(O2CCF3)2 (tpa = Tripyridylamine) Wenyu Yang, Hartmut Schmider, Qingguo Wu, You-sheng Zhang, and Suning Wang pp 2397 - 2404; DOI: 10.1021/ic991436m |
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Synthesis and Characterization of Four Ethylenediamine-Templated Iron Arsenates S. Ekambaram and Slavi C. Sevov pp 2405 - 2410; DOI: 10.1021/ic991367b |
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Magnetic Ordering and Spin-Glass Behavior in First-Row Transition Metal Hexacyanomanganate(IV) Prussian Blue Analogues Wayne E. Buschmann and Joel S. Miller pp 2411 - 2421; DOI: 10.1021/ic991308y |
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An NMR Study of H(-H)Os3(CO)11 Silvio Aime, Walter Dastrù, Roberto Gobetto, and Alessandra Viale pp 2422 - 2425; DOI: 10.1021/ic9907359 |
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Molecular Charge-Transfer Salt of BEDT-TTF [Bis(ethylenedithio)tetrathiafulvalene] with the Oxalate-Bridged Dimeric Anion [Fe2(C2O4)5]4- Samina Rashid, Scott S. Turner, Peter Day, Mark E. Light, and Michael B. Hursthouse pp 2426 - 2428; DOI: 10.1021/ic991409w |
Issue 12
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Applications of Laser Desorption and Electrospray Ionization Mass Spectrometry at the Transition between Clusters and Colloids Paul J. Dyson, Brian F. G. Johnson, J. Scott McIndoe, and Patrick R. R. Langridge-Smith pp 2430 - 2431; DOI: 10.1021/ic991114i |
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A Homologous Series of Redox-Active, Dinuclear Cations with the Bridging Ligand 2-(2-Pyridyl)-1,8-naphthyridine Cristian Saul Campos-Fernández, Xiang Ouyang, and Kim R. Dunbar pp 2432 - 2433; DOI: 10.1021/ic991406j |
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Mechanistic Role of Benzylic Bromides in the Catalytic Autoxidation of Methylarenes Peter D. Metelski, Victor A. Adamian, and James H. Espenson pp 2434 - 2439; DOI: 10.1021/ic990653k |
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Aminopyridine Iron Catecholate Complexes as Models for Intradiol Catechol Dioxygenases. Synthesis, Structure, Reactivity, and Spectroscopic Studies Pierre Mialane, Luba Tchertanov, Frédéric Banse, Joelle Sainton, and Jean-Jacques Girerd pp 2440 - 2444; DOI: 10.1021/ic981236v |
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Synthesis and Structural Characterization of Configurational Isomers of Tungsten-Palladium Complexes with Bridging Diphenyl(dithioalkoxycarbonyl)phosphine as a Ligand and Phosphine Transfer from Tungsten to Palladium Kuang-Hway Yih, Gene-Hsiang Lee, and Yu Wang pp 2445 - 2451; DOI: 10.1021/ic9904438 |
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Synthesis and Characterization of Rhodium(III) Dichloro Complexes with Unsymmetrically Bound Salen-Type Ligands Renee A. Stinziano-Eveland, SonBinh T. Nguyen, Louise M. Liable-Sands, and Arnold L. Rheingold pp 2452 - 2455; DOI: 10.1021/ic990548a |
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Synthesis, Characterization, and Structure of Macrocyclic Mono- and C2-Symmetric, Binuclear Nickel Calixsalen Complexes Zengmin Li and Chet Jablonski pp 2456 - 2461; DOI: 10.1021/ic990935k |
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Ligand Binding inside the Cavities of Lacunar and Saddle-Shaped Cyclidene Complexes: Molecular Mechanics and Molecular Dynamics Studies Elena V. Rybak-Akimova and Krzysztof Kuczera pp 2462 - 2472; DOI: 10.1021/ic990738l |
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Fluoride Ion Donor Properties of TcO2F3 and ReO2F3: X-ray Crystal Structures of MO2F3·SbF5 (M = Tc, Re) and TcO2F3·XeO2F2 and Raman and NMR Spectroscopic Characterization of MO2F3·PnF5 (Pn = As, Sb), [ReO2F2(CH3CN)2][SbF6], and [Re2O4F5][Sb2F11] Nicolas LeBlond, David A. Dixon, and Gary J. Schrobilgen pp 2473 - 2487; DOI: 10.1021/ic9908221 |
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Structures and Magnetism of Two Novel Heptanuclear Lanthanide-Centered Trigonal Prismatic Clusters: [LnCu6(3-OH)3(HL)2(L)4](ClO4)2·25H2O (Ln = La, Tb; H2L = Iminodiacetic Acid) Qin-De Liu, Song Gao, Jun-Ran Li, Qing-Zhong Zhou, Kai-Bei Yu, Bao-Qing Ma, Shi-Wei Zhang, Xi-Xiang Zhang, and Tian-Zhu Jin pp 2488 - 2492; DOI: 10.1021/ic990860k |
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Studies of the Synthesis and Thermochemistry of Coordinatively Unsaturated Chelate Complexes (5-C5Me5)IrL2 (L2 = TsNCH2CH2NTs, TsNCH2CO2, CO2CO2) Douglas B. Grotjahn, H. Christine Lo, Jason Dinoso, Charles D. Adkins, Chunbang Li, Steven P. Nolan, and John L. Hubbard pp 2493 - 2499; DOI: 10.1021/ic990870l |
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Automated Solid-Phase Synthesis and Photophysical Properties of Oligodeoxynucleotides Labeled at 5'-Aminothymidine with Ru(bpy)2(4-m-4'-cam-bpy)2+ Xi Hu, Gregory D. Smith, Milan Sykora, Stephen J. Lee, and Mark W. Grinstaff pp 2500 - 2504; DOI: 10.1021/ic991078n |
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Polylithiated Tetraaminosilanes: Synthesis and Characterization of (Et2O·Li)4[Si(Nnaph)4] and X-ray Structure of {THF·Li3[Si(NiPr)3(NHiPr)]}2 Justin K. Brask, Tristram Chivers, and Masood Parvez pp 2505 - 2508; DOI: 10.1021/ic991238v |
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Synthesis of Stable Crystals of a Self-Assembled Centered Icosahedral Samarium Cluster Formed by Bis(L-prolinato)nickel(II) Ligands Satoshi Igarashi, Yoshimasa Hoshino, Yoshio Masuda, and Yasuhiko Yukawa pp 2509 - 2515; DOI: 10.1021/ic991027q |
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Electron Paramagnetic Resonance and Spectroscopic Characteristics of Electrogenerated Mixed-Valent Systems [(5-C5Me5)M(-L)M(5-C5Me5)]+ (M = Rh, Ir; L = 2,5-Diiminopyrazines) in Relation to the Radicals [(5-C5Me5)ClM(-L)MCl(5-C5Me5)]+ and [(5-C5Me5)M(-L)MCl(5-C5Me5)]2+ Sascha Berger, Axel Klein, Matthias Wanner, Wolfgang Kaim, and Jan Fiedler pp 2516 - 2521; DOI: 10.1021/ic991110d |
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Ferromagnetism in an Extended Three-Dimensional, Diamond-like Copper(II) Network: A New Copper(II)/1-Hydroxybenzotriazolato Complex Exhibiting Soft-Magnet Properties and Two Transitions at 6.4 and 4.4 K Vassilis Tangoulis, Catherine P. Raptopoulou, Vassilis Psycharis, Aris Terzis, Konstantina Skorda, Spyros P. Perlepes, Olivier Cador, Olivier Kahn, and Evangelos G. Bakalbassis pp 2522 - 2529; DOI: 10.1021/ic991149i |
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19F NMR Study of the Equilibria and Dynamics of the Al3+/F- System A. Bodor, I. Tóth, I. Bányai, Z. Szabó, and G. T. Hefter pp 2530 - 2537; DOI: 10.1021/ic991248w |
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Uranium(VI) Sulfilimine Complexes: A New Class of Nitrogen Analogues of the Uranyl Ion V. Cliff Williams, Matthias Müller, Michael A. Leech, Robert G. Denning, and Malcolm L. H. Green pp 2538 - 2541; DOI: 10.1021/ic991294w |
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Synthesis, Structure, and Single-Crystal EPR Study of [Cp(t-Bu3PN)Ti(-Cl)]2 Raymond C. W. Sung, Silke Courtenay, Bruce R. McGarvey, and Douglas W. Stephan pp 2542 - 2546; DOI: 10.1021/ic991305l |
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Preparation, Characterization, and X-ray Crystal Structures of Helical and Syndiotactic Zinc-Based Coordination Polymers William W. Ellis, Marion Schmitz, Atta A. Arif, and Peter J. Stang pp 2547 - 2557; DOI: 10.1021/ic991315m |
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Synthesis, Characterization, and Redox Behavior of New Selenium Coronands and of Copper(I) and Copper(II) Complexes of Selenium Coronands Raymond J. Batchelor, Frederick W. B. Einstein, Ian D. Gay, Jian-Hua Gu, Seema Mehta, B. Mario Pinto, and Xue-Min Zhou pp 2558 - 2571; DOI: 10.1021/ic991345p |
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Synthesis, Structure, and Magnetic Properties of Two New Ferromagnetic/Antiferromagnetic One-Dimensional Nickel(II) Complexes. Magnetostructural Correlations Montserrat Monfort, Immaculada Resino, Joan Ribas, Xavier Solans, Merce Font-Bardia, Pierre Rabu, and Marc Drillon pp 2572 - 2576; DOI: 10.1021/ic991366j |
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Unusual 9 10 Rearrangement of the Substituted Cage Carbon in the Ferratricarbollide Series. Synthesis of the Isomeric Complexes [2-5-(C5H5)-10-X-closo-2,1,7,10-FeC3B8H10] (Where X = H2N, MeHN, Me2N, and ButHN) Bohumír Grüner, Ari Lehtonen, Raikko Kivekäs, Reijo Sillanpää, Josef Holub, Francesc Teixidor, Clara Viñas, and Bohumil  tíbrpp 2577 - 2580; DOI: 10.1021/ic991375s |
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Completion of the Series of M2(hpp)4Cl2 Compounds from W to Pt: The W, Os, and Pt Compounds Rodolphe Clérac, F. Albert Cotton, Lee M. Daniels, James P. Donahue, Carlos A. Murillo, and Daren J. Timmons pp 2581 - 2584; DOI: 10.1021/ic991370v |
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Lowest Electronic Excited States of Platinum(II) Diimine Complexes William B. Connick, Vincent M. Miskowski, Virginia H. Houlding, and Harry B. Gray pp 2585 - 2592; DOI: 10.1021/ic991369w |
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Polysulfide Anions II: Structure and Vibrational Spectra of the S42- and S52- Anions. Influence of the Cations on Bond Length, Valence, and Torsion Angle Omar El Jaroudi, Eric Picquenard, Antoine Demortier, Jean-Pierre Lelieur, and Jacques Corset pp 2593 - 2603; DOI: 10.1021/ic991419x |
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Binding and Redox Properties of Iron(II) Bonded to an Oxo Surface Modeled by Calix[4]arene Vittorio Esposito, Euro Solari, Carlo Floriani, Nazzareno Re, Corrado Rizzoli, and Angiola Chiesi-Villa pp 2604 - 2613; DOI: 10.1021/ic991467h |
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General-Acid-Catalyzed Reactions of Hypochlorous Acid and Acetyl Hypochlorite with Chlorite Ion Zhongjiang Jia, Dale W. Margerum, and Joseph S. Francisco pp 2614 - 2620; DOI: 10.1021/ic991486r |
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An EPR and 1H NMR Active Mixed-Valence Manganese (III/II/III) Trinuclear Compound Vasilis Tangoulis, Dora A. Malamatari, Georgios A. Spyroulias, Catherine P. Raptopoulou, Aris Terzis, and Dimitris P. Kessissoglou pp 2621 - 2630; DOI: 10.1021/ic991430x |
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New Calcium Germanium Nitrides: Ca2GeN2, Ca4GeN4, and Ca5Ge2N6 S. J. Clarke and F. J. DiSalvo pp 2631 - 2634; DOI: 10.1021/ic991427d |
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Lanthanide Chalcogenolate Complexes: Synthesis and Crystal Structures of the Isoleptic Series [Sm(TpMe,Me)2ER] (E = O, S, Se, Te; TpMe,Me = tris-3,5-Dimethylpyrazolylborate) Anna C. Hillier, Sung-Ying Liu, Andrea Sella, and Mark R. J. Elsegood pp 2635 - 2644; DOI: 10.1021/ic9914793 |
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M+(12-crown-4) Supramolecular Cations (M+ = Na+, K+, Rb+, and NH4+) within Ni(2-thioxo-1,3-dithiole-4,5-dithiolate)2 Molecular Conductor Tomoyuki Akutagawa, Tatsuo Hasegawa, Takayoshi Nakamura, Sadamu Takeda, Tamotsu Inabe, Ken-ichi Sugiura, Yoshiteru Sakata, and Allan E. Underhill pp 2645 - 2651; DOI: 10.1021/ic000104a |
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Synthesis of a Ligand Based upon a New Entry into the 3-Hydroxy-N-alkyl-2(1H)-pyridinone Ring System and Thermodynamic Evaluation of Its Gadolinium Complex Adam R. Johnson, Brendon O'Sullivan, and Kenneth N. Raymond pp 2652 - 2660; DOI: 10.1021/ic991471t |
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Kinetics of Silicate Exchange in Alkaline Aluminosilicate Solutions Michael R. North and Thomas W. Swaddle pp 2661 - 2665; DOI: 10.1021/ic0000707 |
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EPR and Ligand Field Studies of Iron Superoxide Dismutases and Iron-Substituted Manganese Superoxide Dismutases: Relationships between Electronic Structure of the Active Site and Activity Jean Philippe Renault, Catherine Verchère-Béaur, Irène Morgenstern-Badarau, Fumiyuki Yamakura, and Malcolm Gerloch pp 2666 - 2675; DOI: 10.1021/ic0000451 |
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Reactions of the Dirhenium(II) Complexes Re2X4(-dppm)2 (X = Cl, Br; dppm = Ph2PCH2PPh2) with Isocyanides. 21.1 A Comparison with the Complexes Re2Cl4(-dppE)2 and Re2Cl4(-dcpm)2 (dppE = Ph2PC(=CH2)PPh2; dcpm = Cy2PCH2PCy2) and the Structural Characterization of Complexes of the Types Re2Cl4(-LL)2(CNR), Re2Cl4(-LL)2(CNR)2, and [Re2Cl3(-LL)2(CNR)3]+ (LL = dppm, dppE, dcpm; R = t-Bu, Xyl) Yan Ding, Shan-Ming Kuang, Michael J. Siwajek, Phillip E. Fanwick, and Richard A. Walton pp 2676 - 2683; DOI: 10.1021/ic000064a |
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Self-Assembling Molecular Wires of Halogen-Bridged Platinum Complexes in Organic Media. Mesoscopic Supramolecular Assemblies Consisting of a Mixed Valent Pt(II)/Pt(IV) Complex and Anionic Amphiphiles Nobuo Kimizuka, Noriko Oda, and Toyoki Kunitake pp 2684 - 2689; DOI: 10.1021/ic000189f |
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Crystal Structure of the Molecular Addition Compound Diphenylchloroborane·Tetrahydrofuran Wendy I. Cross, Matthew P. Lightfoot, Francis S. Mair, and Robin G. Pritchard pp 2690 - 2692; DOI: 10.1021/ic991148q |
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Synthesis and Characterization of a Homoleptic Thiolate Complex of Titanium(IV) Claire J. Carmalt, Christopher W. Dinnage, Ivan P. Parkin, and Jonathan W. Steed pp 2693 - 2695; DOI: 10.1021/ic991382g |
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Unusual Redox State Dependent Fermi Resonances in the Infrared Spectra of Trinuclear Ruthenium Clusters with Isocyanide Ligands Igor S. Zavarine, Clifford P. Kubiak, Tadashi Yamaguchi, Ken-ichiro Ota, Taeko Matsui, and Tasuku Ito pp 2696 - 2698; DOI: 10.1021/ic991404z |
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Self-Association in Gold Chemistry: A Tetragold(I) Complex Linked by Both Aurophilic and Hydrogen Bonding William J. Hunks, Michael C. Jennings, and Richard J. Puddephatt pp 2699 - 2702; DOI: 10.1021/ic991497k |
Issue 13
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Coordination Chemistry of the Novel 5,10,15-Tris(pentafluorophenyl)corrole: Synthesis, Spectroscopy, and Structural Characterization of Its Cobalt(III), Rhodium(III), and Iron(IV) Complexes Liliya Simkhovich, Nitsa Galili, Irena Saltsman, Israel Goldberg, and Zeev Gross pp 2704 - 2705; DOI: 10.1021/ic991342c |
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(NH4)15[H3Mo57V6(NO)6O189(H2O)12(VO)6]·~60H2O: New Nanocompound Obtained by Chemical Embellishment of {M57V6} Wenbin Yang, Xiang Lin, Canzhong Lu, Honghui Zhuang, and Jinshun Huang pp 2706 - 2707; DOI: 10.1021/ic991249o |
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Multiple Ligand-Based Emissions from a Platinum(II) Terpyridine Complex Attached to Pyrene Joseph F. Michalec, Stephanie A. Bejune, and David R. McMillin pp 2708 - 2709; DOI: 10.1021/ic000304m |
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Three-Dimensional Framework Constructed Using Nanometer-Sized Metallamacrocycle as a Secondary Building Unit Mooshin Moon, Inhoe Kim, and Myoung Soo Lah pp 2710 - 2711; DOI: 10.1021/ic991079f |
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To What Extent Can Cyclometalation Promote Associative or Dissociative Ligand Substitution at Platinum(II) Complexes? A Combined Kinetic and Theoretical Approach Maria Rosaria Plutino, Luigi Monsù Scolaro, Raffaello Romeo, and Antonio Grassi pp 2712 - 2720; DOI: 10.1021/ic9914894 |
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Protonation Studies of Reduced Ruthenium(II) Complexes with Polypyridyl Ligands Peter A. Anderson, Robert F. Anderson, Masaoki Furue, Peter C. Junk, F. Richard Keene, Bradley T. Patterson, and Brett D. Yeomans pp 2721 - 2728; DOI: 10.1021/ic991070d |
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EPR Studies of Chromium(V) Intermediates Generated via Reduction of Chromium(VI) by DOPA and Related Catecholamines: Potential Role for Oxidized Amino Acids in Chromium-Induced Cancers David I. Pattison, Peter A. Lay, and Michael J. Davies pp 2729 - 2739; DOI: 10.1021/ic991443a |
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Optical Properties of Se2- and Se2 Color Centers in the Red Selenium Ultramarine with the Sodalite Structure H. Schlaich, G.-G. Lindner, J. Feldmann, E. O. Göbel, and D. Reinen pp 2740 - 2746; DOI: 10.1021/ic990223u |
Ligand Substitution Reactions of W6S8L6 with Tricyclohexylphosphine (L = 4-tert-Butylpyridine or n-Butylamine): 31P NMR and Structural Studies of W6S8(PCy3)n(4-tert-butylpyridine)6-n (0 < n  6) ComplexesSong Jin, D. Venkataraman, and Francis J. DiSalvo pp 2747 - 2757; DOI: 10.1021/ic991426l |
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Preparation and Characterization of {[M(dmb)2]TCNQ·xTCNQ}n Polymers (M = Cu,Ag; dmb = 1,8-Diisocyano-p-menthane; x = 0, 0.5, 1.0, 1.5; TCNQ = 7,7,8,8-Tetracyano-p-quinodimethane) and Design of New Semi- and Photoconducting Organometallic Materials Daniel Fortin, Marc Drouin, and Pierre D. Harvey pp 2758 - 2769; DOI: 10.1021/ic990975o |
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A Rational Design for Imidazolate-Bridged Linear Trinuclear Compounds from Mononuclear Copper(II) Complexes with 2-[((Imidazol-2-ylmethylidene)amino)ethyl]pyridine (HL): Syntheses, Structures, and Magnetic Properties of [Cu(L)(hfac)M(hfac)2Cu(hfac)(L)] (M = ZnII, CuII, MnII) Enrique Colacio, Mustapha Ghazi, Raikko Kivekäs, Martti Klinga, Francesc Lloret, and José María Moreno pp 2770 - 2776; DOI: 10.1021/ic991401m |
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New Synthetic Routes to Biscarbonylbipyridinerhenium(I) Complexes cis,trans-[Re(X2bpy)(CO)2(PR3)(Y)]n+ (X2bpy = 4,4'-X2-2,2'-bipyridine) via Photochemical Ligand Substitution Reactions, and Their Photophysical and Electrochemical Properties Kazuhide Koike, Junji Tanabe, Shigeki Toyama, Hideaki Tsubaki, Kazuhiko Sakamoto, Jeremy R. Westwell, Frank P. A. Johnson, Hisao Hori, Hideki Saitoh, and Osamu Ishitani pp 2777 - 2783; DOI: 10.1021/ic991190l |
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The Trifluorophosphonium Ion, PF3H+, Preparation and Structure Ralf Küster, Thomas Drews, and Konrad Seppelt pp 2784 - 2786; DOI: 10.1021/ic991420w |
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Gas-Phase Molecular Structures of Third Row Transition-Metal Hexafluorides WF6, ReF6, OsF6, IrF6, and PtF6. An Electron-Diffraction and ab Initio Study Alan D. Richardson, Kenneth Hedberg, and George M. Lucier pp 2787 - 2793; DOI: 10.1021/ic000003c |
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M-F Interatomic Distances and Effective Volumes of Second and Third Transition Series MF6- and MF62- Anions Oliver Graudejus, Angus P. Wilkinson, Lisa C. Chacón, and Neil Bartlett pp 2794 - 2800; DOI: 10.1021/ic000041w |
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Gold Complexes with Potentially Tri- and Tetradentate Phosphinothiolate Ligands Kirstin Ortner, Louise Hilditch, Yifan Zheng, Jonathan R. Dilworth, and Ulrich Abram pp 2801 - 2806; DOI: 10.1021/ic000015y |
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Crystal and Molecular Structures of Trifluoroacrylonitrile, F2C=CF-CN, and Trifluorovinyl Isocyanide, F2C=CF-NC, by Low-Temperature X-ray Crystallography and ab Initio Calculations Jürgen Buschmann, Sven Kleinhenz, Dieter Lentz, Peter Luger, Krishnan V. Madappat, Dagmar Preugschat, and Joseph S. Thrasher pp 2807 - 2812; DOI: 10.1021/ic000264m |
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Tetrachloro- and Tetrabromoarsonium(V) Cations: Raman and 75As, 19F NMR Spectroscopic Characterization and X-ray Crystal Structures of [AsCl4][As(OTeF5)6] and [AsBr4][AsF(OTeF5)5] Michael Gerken, Peter Kolb, Andreas Wegner, Hélène P. A. Mercier, Horst Borrmann, David A. Dixon, and Gary J. Schrobilgen pp 2813 - 2824; DOI: 10.1021/ic000118g |
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Mechanistic Control of Product Selectivity. Reactions between cis-/trans-[OsVI(tpy)(Cl)2(N)]+ and Triphenylphosphine Sulfide My Hang V. Huynh, Peter S. White, and Thomas J. Meyer pp 2825 - 2830; DOI: 10.1021/ic991425t |
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Multiple Bonding in Four-Coordinated Titanium(IV) Compounds J. A. Dobado, José Molina Molina, Rolf Uggla, and Markku R. Sundberg pp 2831 - 2836; DOI: 10.1021/ic000013d |
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Delocalized TCNQ Stacks in Nickel and Copper Tetraazamacrocyclic Systems Loreto Ballester, Ana M. Gil, Angel Gutiérrez, M. Felisa Perpiñán, M. Teresa Azcondo, Ana E. Sánchez, Eugenio Coronado, and Carlos J. Gómez-García pp 2837 - 2842; DOI: 10.1021/ic9912070 |
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Oxo/Sulfidotungstate(VI) as Precursors to WVIO2, WVIOS, and WVIS2 Complexes and WIV-Dithiolene Chelate Rings Mingming Miao, Michael W. Willer, and R. H. Holm pp 2843 - 2849; DOI: 10.1021/ic000047l |
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Electrochemical Studies of Corrphycenes and Metallocorrphycenes Jean-Paul Gisselbrecht, Maurice Gross, Emanuel Vogel, and Jonathan L. Sessler pp 2850 - 2854; DOI: 10.1021/ic9913031 |
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A Monolayer Complex of Cu2(OH)3C12H25SO4 Directly Precipitated from an Aqueous SDS Solution Masaharu Okazaki, Kazumi Toriyama, Shinji Tomura, Taiji Kodama, and Eiji Watanabe pp 2855 - 2860; DOI: 10.1021/ic000088h |
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Topological Relationships and Building Blocks in Zintl Phases of the Composition Ban+l(Mg,Li)2nSi2(n+l) Steffen Wengert and Reinhard Nesper pp 2861 - 2865; DOI: 10.1021/ic991299t |
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On the Adiabaticity Contribution to the Rate of Outer-Sphere Electron Transfers. Reactions of Cytochrome c and Related Transition Metal Compounds G. Ferraudi pp 2866 - 2873; DOI: 10.1021/ic991174o |
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Crystal Structure of Bis(4-methylimidazole)tetraphenylporphyrinatoiron(III) Chloride and Related Compounds. Correlation of Ground State with Fe-N Bond Lengths Jack Silver, Paul J. Marsh, Martyn C. R. Symons, Dimitri A. Svistunenko, Christopher S. Frampton, and George R. Fern pp 2874 - 2881; DOI: 10.1021/ic990848s |
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Helical-Chain Copper(II) Complexes and a Cyclic Tetranuclear Copper(II) Complex with Single Syn-Anti Carboxylate Bridges and Ferromagnetic Exchange Interactions Enrique Colacio, Mustapha Ghazi, Raikko Kivekäs, and José Maria Moreno pp 2882 - 2890; DOI: 10.1021/ic991209k |
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Molecular Structures and Magnetic Properties of the Mixed-Ligand Complexes of Bis(hexafluoroacetylacetonato)manganese(II), -copper(II), and -zinc(II) with 4,4'-Bis(N-tert-butyl-N-oxylamino)-2,2'-bipyridine. Isosceles Triangular Hetero-Three-Spin Systems Consisting of Aminoxyls and Metal Ions Akira Sakane, Harumi Kumada, Satoru Karasawa, Noboru Koga, and Hiizu Iwamura pp 2891 - 2896; DOI: 10.1021/ic991205f |
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Effect of Conformational Constraints on Gated Electron-Transfer Kinetics. 3. Copper(II/I) Complexes with cis- and trans-Cyclopentanediyl-1,4,8,11-tetrathiacyclotetradecane Prabodha Wijetunge, Chandrika P. Kulatilleke, Luke T. Dressel, Mary Jane Heeg, L. A. Ochrymowycz, and D. B. Rorabacher pp 2897 - 2905; DOI: 10.1021/ic0000909 |
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Chemical Applications of Topology and Group Theory. 34. Structure and Bonding in Titanocarbohedrene Cages R. B. King pp 2906 - 2908; DOI: 10.1021/ic991151+ |
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Chemical Properties of the Pd4(dppm)4(H)22+ Cluster and the Homogeneous Electrocatalytical Behavior of Hydrogen Evolution and Formate Decomposition Daniel Meilleur, Dominique Rivard, Pierre D. Harvey, Isabelle Gauthron, Dominique Lucas, and Yves Mugnier pp 2909 - 2914; DOI: 10.1021/ic9913987 |
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Sandwich-Type Silicotungstates: Structure and Magnetic Properties of the Dimeric Polyoxoanions [{SiM2W9O34(H2O)}2]12- (M = Mn2+, Cu2+, Zn2+) Ulrich Kortz, Samih Isber, Michael H. Dickman, and Didier Ravot pp 2915 - 2922; DOI: 10.1021/ic000078g |
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Theoretical Models for the Oxygen Radical Mechanism of Water Oxidation and of the Water Oxidizing Complex of Photosystem II Per E. M. Siegbahn pp 2923 - 2935; DOI: 10.1021/ic9911872 |
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Molecular and Electronic Structures of Bis(pyridine-2,6-diimine)metal Complexes [ML2](PF6)n (n = 0, 1, 2, 3; M = Mn, Fe, Co, Ni, Cu, Zn) Bas de Bruin, Eckhard Bill, Eberhard Bothe, Thomas Weyhermüller, and Karl Wieghardt pp 2936 - 2947; DOI: 10.1021/ic000113j |
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Electrochemistry in Benzotrifluoride: Redox Studies in a "Noncoordinating" Solvent Capable of Bridging the Organic and Fluorous Phases Carl Ohrenberg and William E. Geiger pp 2948 - 2950; DOI: 10.1021/ic000007h |
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Total Diastereoselective Opening of Chiral Hydridophosphorane "Triquinphosphoranes" by Hexacarbonylmolybdenum: An Entry to Mo(CO)5: Chiral Oxazaphospholidine Complex Caroline Marchi and Gérard Buono pp 2951 - 2953; DOI: 10.1021/ic0000101 |
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Synthesis and Structure of Dimeric Silver Azooximates. Hydrogen Bonding and Nonbonded Ag···Ag Interaction Sanjib Ganguly, Surajit Chattopadhyay, Chittaranjan Sinha, and Animesh Chakravorty pp 2954 - 2956; DOI: 10.1021/ic000056u |
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Reactivity of Pd(0) Complexes with the Phosphino Ylide [Ph2PCH2PPh2=C(H)C(O)Me]. Molecular Structure of [Pd(PPh2CHPPh2C(H)C(O)Me)2] Larry R. Falvello, Susana Fernández, Rafael Navarro, and Esteban P. Urriolabeitia pp 2957 - 2960; DOI: 10.1021/ic990923z |
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Inversion of the Cis Geometry Requirement for Cytotoxicity in Structurally Novel Platinum(II) Complexes Containing the Bidentate N,O-Donor Pyridin-2-yl-acetate. Ulrich Bierbach, Michal Sabat, and Nicholas Farrell: pp 2960 - 2960; DOI: 10.1021/ic0004840 |
Issue 14
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XAS Investigation of the Nickel Active Site Structure in Escherichia coli Glyoxalase I Gerard Davidson, Susan L. Clugston, John F. Honek, and Michael J. Maroney pp 2962 - 2963; DOI: 10.1021/ic0001208 |
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Elemental Solvothermal Reaction To Produce Ternary Semiconductor CuInE2 (E = S, Se) Nanorods Yang Jiang, Yue Wu, Xiao Mo, Weichao Yu, Yi Xie, and Yitai Qian pp 2964 - 2965; DOI: 10.1021/ic000126x |
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Strong Differences in the in Vitro Cytotoxicity of Three Isomeric Dichlorobis(2-phenylazopyridine)ruthenium(II) Complexes Aldrik H. Velders, Huub Kooijman, Anthony L. Spek, Jaap G. Haasnoot, Dick de Vos, and Jan Reedijk pp 2966 - 2967; DOI: 10.1021/ic000167t |
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Involvement of Multiply Bonded Dirhenium Complexes in Mixed-Metal Assemblies. Isolation and Characterization of a New Type of Re4Pd2 Cluster Shan-Ming Kuang, Phillip E. Fanwick, and Richard A. Walton pp 2968 - 2969; DOI: 10.1021/ic000250g |
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Synthesis and Structural Characterization of Quaternary Thorium Selenophosphates: A2ThP3Se9 (A = K, Rb) and Cs4Th2P5Se17 Paula M. Briggs Piccoli, Kent D. Abney, Jon R. Schoonover, and Peter K. Dorhout pp 2970 - 2976; DOI: 10.1021/ic990767w |
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Model Investigations of Vanadium-Protein Interactions: Novel Vanadium(III) and Oxovanadium(IV) Compounds with the Diamidate Ligand 1,2-Bis(2-pyridinecarboxamide)benzene (H2bpb) Antonis T. Vlahos, Evagelos I. Tolis, Catherine P. Raptopoulou, Alexandros Tsohos, Michael P. Sigalas, Aris Terzis, and Themistoklis A. Kabanos pp 2977 - 2985; DOI: 10.1021/ic990837z |
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A Systematic Evaluation of Molecular Recognition Phenomena. 1. Interaction between Phosphates and Nucleotides with Hexaazamacrocyclic Ligands Containing m-Xylylic Spacers Carmen Anda, Antoni Llobet, Victoria Salvado, Joseph Reibenspies, Ramunas J. Motekaitis, and Arthur E. Martell pp 2986 - 2999; DOI: 10.1021/ic990818p |
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A Systematic Evaluation of Molecular Recognition Phenomena. 2. Interaction between Phosphates and Nucleotides with Hexaazamacrocyclic Ligands Containing Diethylic Ether Spacers Carmen Anda, Antoni Llobet, Victoria Salvado, Arthur E. Martell, and Ramunas J. Motekaitis pp 3000 - 3008; DOI: 10.1021/ic9908468 |
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"Bridging Hydroxide Effect" on -Carboxylato Coordination and Electrochemical Potentials of Bimetallic Centers: Mn2(II,II) and Mn2(III,III) Complexes as Functional Models of Dimanganese Catalases A. E. M. Boelrijk, S. V. Khangulov, and G. C. Dismukes pp 3009 - 3019; DOI: 10.1021/ic9911769 |
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Mechanism of Hydrogen Peroxide Dismutation by a Dimanganese Catalase Mimic: Dominant Role of an Intramolecular Base on Substrate Binding Affinity and Rate Acceleration A. E. M. Boelrijk and G. C. Dismukes pp 3020 - 3028; DOI: 10.1021/ic9911771 |
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Binding of -Acceptor Ligands to (Triamine)iron(II) Complexes Andrew C. Moreland and Thomas B. Rauchfuss pp 3029 - 3036; DOI: 10.1021/ic9912629 |
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Syntheses and Structures of Heterobicyclic Bis(tert-butylamido)cyclodiphosph(III)azane Compounds Having Phosphorus(III) and Arsenic(III) Centers Ingo Schranz, Luke P. Grocholl, Lothar Stahl, Richard J. Staples, and Alison Johnson pp 3037 - 3041; DOI: 10.1021/ic991405r |
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Structurally Diverse Copper(II)-Carboxylato Complexes: Neutral and Ionic Mononuclear Structures and a Novel Binuclear Structure George Psomas, Catherine P. Raptopoulou, Lykourgos Iordanidis, Catherine Dendrinou-Samara, Vassilis Tangoulis, and Dimitris P. Kessissoglou pp 3042 - 3048; DOI: 10.1021/ic991476q |
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Supramolecular Complex of Cytochrome c with Lariat Ether: Solubilization, Redox Behavior and Catalytic Activity of Cytochrome c in Methanol Takashi Yamada, Satoshi Shinoda, Koichi Kikawa, Akio Ichimura, Junji Teraoka, Takeji Takui, and Hiroshi Tsukube pp 3049 - 3056; DOI: 10.1021/ic991286f |
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Isothermal Titration Calorimetry Measurements of Ni(II) and Cu(II) Binding to His, GlyGlyHis, HisGlyHis, and Bovine Serum Albumin: A Critical Evaluation Yi Zhang, Shreeram Akilesh, and Dean E. Wilcox pp 3057 - 3064; DOI: 10.1021/ic000036s |
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New Linear Tricobalt Complex of Di(2-pyridyl)amide (dpa), [Co3(dpa)4(CH3CN)2][PF6]2 Rodolphe Clérac, F. Albert Cotton, Kim R. Dunbar, Tongbu Lu, Carlos A. Murillo, and Xiaoping Wang pp 3065 - 3070; DOI: 10.1021/ic000042o |
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Synthesis, Structure, and Multi-NMR Studies of (Me4N)[A{M(SC{O}Ph)3}2] (A = Na, M = Hg; A = K, M = Cd or Hg) Theivanayagam C. Deivaraj, Philip A. W. Dean, and Jagadese J. Vittal pp 3071 - 3074; DOI: 10.1021/ic0000810 |
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Mechanism and Molecular-Electronic Structure Correlations in a Novel Series of Osmium(V) Hydrazido Complexes My Hang V. Huynh, El-Sayed El-Samanody, Konstantinos D. Demadis, Peter S. White, and Thomas J. Meyer pp 3075 - 3085; DOI: 10.1021/ic000058e |
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Synthesis, Structure, and Bonding of A5Cd2Tl11, A = Cs, Rb. Naked Pentagonal Antiprismatic Columns Centered by Cadmium Stefan Kaskel and John D. Corbett pp 3086 - 3091; DOI: 10.1021/ic000061y |
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Synthesis and Structures of New Ternary Aluminum Chalcogenides: LiAlSe2, -LiAlTe2, and -LiAlTe2 Joonyeong Kim and Timothy Hughbanks pp 3092 - 3097; DOI: 10.1021/ic000210c |
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Time-Resolved Infrared Spectroscopic Study of Reactive Acyl Intermediates Relevant to Cobalt-Catalyzed Carbonylations Steven M. Massick, Julienne G. Rabor, Stefan Elbers, Jon Marhenke, Stefan Bernhard, Jon R. Schoonover, and Peter C. Ford pp 3098 - 3106; DOI: 10.1021/ic000378y |
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Time-Resolved IR Studies of [Re(LL)(CO)4]+ Stefan Bernhard, Kristin M. Omberg, Geoffrey F. Strouse, and Jon R. Schoonover pp 3107 - 3110; DOI: 10.1021/ic991175g |
Issue 15
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Influencing the Size of Giant Rings by Manipulating Their Curvatures: Na6[Mo120O366(H2O)48H12{Pr(H2O)5}6]·(~200H2O) with Open Shell Metal Centers at the Cluster Surface Achim Müller, Christian Beugholt, Hartmut Bögge, and Marc Schmidtmann pp 3112 - 3113; DOI: 10.1021/ic000168l |
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Supramolecular Coordination Chemistry in Aqueous Solution: Lanthanide Ion-Induced Triple Helix Formation Jeremy J. Lessmann and William DeW. Horrocks, Jr. pp 3114 - 3124; DOI: 10.1021/ic990698l |
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Mechanistic Studies of (Porphinato)Iron-Catalyzed Isobutane Oxidation. Comparative Studies of Three Classes of Electron-Deficient Porphyrin Catalysts Kevin T. Moore, István T. Horváth, and Michael J. Therien pp 3125 - 3139; DOI: 10.1021/ic000284o |
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Molecular Mechanics Calculations of 10-Vertex Boron Cage Compounds Kyrill Yu. Suponitsky, Tatjana V. Timofeeva, and Norman L. Allinger pp 3140 - 3147; DOI: 10.1021/ic991155e |
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Encapsulating Bis(-Ketoiminato) Polyethers. Volatile, Fluorine-Free Barium Precursors for Metal-Organic Chemical Vapor Deposition Daniel B. Studebaker, Deborah A. Neumayer, Bruce J. Hinds, Charlotte L. Stern, and Tobin J. Marks pp 3148 - 3157; DOI: 10.1021/ic991161a |
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Luminescent Chains Formed from Neutral, Triangular Gold Complexes Sandwiching TlI and AgI. Structures of {Ag([Au(-C2,N3-bzim)]3)2}BF4·CH2Cl2, {Tl([Au(-C2,N3-bzim)]3)2}PF6·0.5THF (bzim = 1-Benzylimidazolate), and {Tl([Au(-C(OEt)=NC6H4CH3)]3)2}PF6·THF, with MAu6 (M = Ag+, Tl+) Cluster Cores Alfredo Burini, Rita Bravi, John P. Fackler, Jr., Rossana Galassi, Tiffany A. Grant, Mohammad A. Omary, Bianca R. Pietroni, and Richard J. Staples pp 3158 - 3165; DOI: 10.1021/ic991492n |
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Through-Ring Bonding in Edge Sharing Dimers of Octahedral Complexes Ana A. Palacios, Gabriel Aullón, Pere Alemany, and Santiago Alvarez pp 3166 - 3175; DOI: 10.1021/ic000017i |
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Syntheses, Structures, and Physical Properties of LnAsTe (Ln = La, Pr, Sm, Gd, Dy, Er) Fu Qiang Huang, Paul Brazis, Carl R. Kannewurf, and James A. Ibers pp 3176 - 3180; DOI: 10.1021/ic000187v |
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Water Adsorption and Hydrolysis on Molecular Transition Metal Oxides and Oxyhydroxides J. R. Tobias Johnson and Itai Panas pp 3181 - 3191; DOI: 10.1021/ic991150h |
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Hydrolysis on Transition Metal Oxide Clusters and the Stabilities of M-O-M Bridges J. R. Tobias Johnson and Itai Panas pp 3192 - 3204; DOI: 10.1021/ic991144l |
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Selective Imidazolidine Ring Opening during Complex Formation of Iron(III), Copper(II), and Zinc(II) with a Multidentate Ligand Obtained from 2-Pyridinecarboxaldehyde N-Oxide and Triethylenetetramine M. Bo a, P. Baran, R. Boa, H. Fuess, G. Kickelbick, W. Linert, F. Renz, and I. Svobodapp 3205 - 3212; DOI: 10.1021/ic9914037 |
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Reactivity of "Eu(OiPr)2" with Phenols: Formation of Linear Eu3, Square Pyramidal Eu5, Cubic Eu8, and Capped Cubic Eu9 Polymetallic Europium Complexes William J. Evans, Michael A. Greci, and Joseph W. Ziller pp 3213 - 3220; DOI: 10.1021/ic9909532 |
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Magnetic Coupling in End-to-End Azido-Bridged Copper and Nickel Binuclear Complexes: A Theoretical Study Fabrizia Fabrizi de Biani, Eliseo Ruiz, Joan Cano, Juan J. Novoa, and Santiago Alvarez pp 3221 - 3229; DOI: 10.1021/ic000005x |
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A Hydrothermal Investigation of the 1/2V2O5-H2C2O4/H3PO4/NH4OH System: Synthesis and Structures of (NH4)VOPO4·1.5H2O, (NH4)0.5VOPO4·1.5H2O, (NH4)2[VO(H2O)3]2[VO(H2O)][VO(PO4)2]2·3H2O, and (NH4)2[VO(HPO4)]2(C2O4)·5H2O Junghwan Do, Ranko P. Bontchev, and Allan J. Jacobson pp 3230 - 3237; DOI: 10.1021/ic0000303 |
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Formation of a Tetranuclear Copper (II) Cluster Assembled by Metal-Assisted Hydrolysis and Desulfurization of Bis(3,5-dimethylpyrazolyl)methylphosphine Sulfide, MeP(S)(3,5-Me2Pz)2 V. Chandrasekhar, S. Kingsley, A. Vij, K. C. Lam, and A. L. Rheingold pp 3238 - 3242; DOI: 10.1021/ic991255k |
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Self-Propagating Metathesis Routes to Metastable Group 4 Phosphides Robert F. Jarvis, Jr., Richard M. Jacubinas, and Richard B. Kaner pp 3243 - 3246; DOI: 10.1021/ic000057m |
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Peroxo and Ferryl Intermediates Detected by 1H NMR Spectroscopy during the Oxygenation of Iron(II) Porphycene Krystyna Rachlewicz, Lechos  aw Latos-Gra y ski, and Emanuel Vogelpp 3247 - 3251; DOI: 10.1021/ic991417c |
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Structural Influences of Organonitrogen Ligands on Vanadium Oxide Solids. Hydrothermal Syntheses and Structures of the Terpyridine Vanadates [V2O4(Terpy)2]3[V10O28], [VO2(Terpy)][V4O10], and [V9O22(Terpy)3] Pamela J. Hagrman and Jon Zubieta pp 3252 - 3260; DOI: 10.1021/ic991473d |
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Oxidative Scission of a Mo-Mo Quadruple Bond F. Albert Cotton, Carlos A. Murillo, and Hong-Cai Zhou pp 3261 - 3264; DOI: 10.1021/ic000092t |
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Preparations, Structures, and Electrochemical Studies of Aryldiazene Complexes of Rhenium: Syntheses of the First Heterobinuclear and Heterotrinuclear Derivatives with Bis(diazene) or Bis(diazenido) Bridging Ligands Gabriele Albertin, Stefano Antoniutti, Alessia Bacchi, Giovanni B. Ballico, Emilio Bordignon, Giancarlo Pelizzi, Maria Ranieri, and Paolo Ugo pp 3265 - 3279; DOI: 10.1021/ic991393+ |
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Synthesis of Monohalogeno Derivatives of closo-[B9H9]2-. Crystal Structures of (Ph4P)2[1-XB9H8]·CH3CN (X = Cl, Br, I) Katja Siegburg and Wilhelm Preetz pp 3280 - 3282; DOI: 10.1021/ic9913334 |
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Diazo Complexes of Rhenium: Preparations and Crystal Structures of the Bis(dinitrogen), [Re(N2)2{PPh(OEt)2}4][BPh4] and Methyldiazenido [ReCl(CH3N2)(CH3NHNH2){PPh(OEt)2}3][BPh4] Derivatives Gabriele Albertin, Stefano Antoniutti, Alessia Bacchi, Emilio Bordignon, Francesca Miani, and Giancarlo Pelizzi pp 3283 - 3293; DOI: 10.1021/ic990970r |
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Syntheses, Structures, and Properties of Tetrakis(-acetato)dirhodium(II) Complexes with Axial Pyridine Nitrogen Donor Ligands with or without Assistance of Hydrogen Bonds Hideki Kitamura, Tomohiro Ozawa, Koichiro Jitsukawa, Hideki Masuda, Yasuhiro Aoyama, and Hisahiko Einaga pp 3294 - 3300; DOI: 10.1021/ic991200i |
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Synthesis and Characterization of Water-Soluble Silver(I) Complexes with L-Histidine (H2his) and (S)-(-)-2-Pyrrolidone-5-carboxylic Acid (H2pyrrld) Showing a Wide Spectrum of Effective Antibacterial and Antifungal Activities. Crystal Structures of Chiral Helical Polymers [Ag(Hhis)]n and {[Ag(Hpyrrld)]2}n in the Solid State Kenji Nomiya, Satoshi Takahashi, Ryusuke Noguchi, Satomi Nemoto, Toshio Takayama, and Munehiro Oda pp 3301 - 3311; DOI: 10.1021/ic990526o |
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Corroles with Group 15 Metal Ions. Synthesis and Characterization of Octaethylcorroles Containing As, Sb, and Bi Ions in +3, +4, and +5 Oxidation States Karl M. Kadish, Christoph Erben, Zhongping Ou, Victor A. Adamian, Stefan Will, and Emanuel Vogel pp 3312 - 3319; DOI: 10.1021/ic991361m |
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Synthesis and Characterization of the Layered Vanadium Borophosphate (Imidazolium)3.8(H3O)1.2[(VO)4(BO)2(PO4)5]·0.3H2O Ranko P. Bontchev, Junghwan Do, and Allan J. Jacobson pp 3320 - 3324; DOI: 10.1021/ic000177u |
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Syntheses, Characterizations, and Single-Crystal X-ray Structures of Soluble Titanium Alkoxide Phosphonates Michael Mehring, Gilles Guerrero, Françoise Dahan, P. Hubert Mutin, and André Vioux pp 3325 - 3332; DOI: 10.1021/ic000002k |
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Synthesis and Characterization of Sulfide, Sulfide-Sulfonium, and Bissulfide Derivatives of [B12H12]2-. Additivity of Me2S and MeS- Substituent Effects in 11B NMR Spectra of Disubstituted Icosahedral Boron Clusters Roman G. Kultyshev, Jianping Liu, Edward A. Meyers, and Sheldon G. Shore pp 3333 - 3341; DOI: 10.1021/ic000198o |
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Copper(II) and Copper(I) Complexes with an Open-Chain N4 Schiff Base Ligand Modeling CuZn Superoxide Dismutase: Structural and Spectroscopic Characterization and Kinetics of Electron Transfer Jürgen Lange, Horst Elias, Helmut Paulus, Jörg Müller, and Ulrich Weser pp 3342 - 3349; DOI: 10.1021/ic000097q |
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Synthesis, Characterization, and Spontaneous Resolution of Chiral Nickel(II) Complexes with the Tripod Ligand Tris[2-(((2-phenylimidazol-4-yl)methylidene)amino)ethyl]amine Ikuko Katsuki, Naohide Matsumoto, and Masaaki Kojima pp 3350 - 3354; DOI: 10.1021/ic9909025 |
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1,2-Bis(pyridine-2-carboxamido)benzenate(2-), (bpb)2-: A Noninnocent Ligand. Syntheses, Structures, and Mechanisms of Formation of [(n-Bu)4N][FeIV2(-N)(bpb)2(X)2] (X = CN-, N3-) and the Electronic Structures of [MIII(bpbox1)(CN)2] (M = Co, Fe) Sujit K. Dutta, Udo Beckmann, Eckhard Bill, Thomas Weyhermüller, and Karl Wieghardt pp 3355 - 3364; DOI: 10.1021/ic0001107 |
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Reactivity of -Hydroxodizinc(II) Centers in Enzymatic Catalysis through Model Studies Natalia V. Kaminskaia, Chuan He, and Stephen J. Lippard pp 3365 - 3373; DOI: 10.1021/ic000169d |
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Synthesis and Characterization of (R-C5H14N2)2[Ga4(C2O4)(H2PO4)2(PO4)4]·2H2O, a Layered Gallium Phosphatooxalate Containing a Chiral Amine Kwang-Hwa Lii and Ching-Yeh Chen pp 3374 - 3378; DOI: 10.1021/ic991356i |
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An Electron Paramagnetic Resonance Study of Mn2(H2O)(OAc)4(tmeda)2 (tmeda = N,N,N',N'-Tetramethylethylenediamine): A Model for Dinuclear Manganese Enzyme Active Sites Timothy Howard, Joshua Telser, and Victoria J. DeRose pp 3379 - 3385; DOI: 10.1021/ic0000247 |
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Cation Disorder in Ga1212 Kevin B. Greenwood, Donggeun Ko, Douglas A. Vander Griend, Gregory M. Sarjeant, John W. Milgram, Elizabeth S. Garrity, Deborah I. DeLoach, Kenneth R. Poeppelmeier, Paul A. Salvador, and Thomas O. Mason pp 3386 - 3391; DOI: 10.1021/ic0002667 |
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Cooperative Diastereoselectivity of Palladium- and Platinum-Promoted Intramolecular [4+2] Diels-Alder Cycloaddition Reactions of 3,4-Dimethyl-1-phenylphosphole Kent D. Redwine, William L. Wilson, Donald G. Moses, Vincent J. Catalano, and John H. Nelson pp 3392 - 3402; DOI: 10.1021/ic990885j |
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Similarities and Differences between Cobalamins and Cobaloximes. Accurate Structural Determination of Methylcobalamin and of LiCl- and KCl-Containing Cyanocobalamins by Synchrotron Radiation Lucio Randaccio, Michela Furlan, Silvano Geremia, Miroslav louf, Ivana Srnova, and Daniele Toffolipp 3403 - 3413; DOI: 10.1021/ic0001199 |
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Linear Trichromium Complexes with the Anion of 2,6-Di(phenylimino)piperidine Rodolphe Clérac, F. Albert Cotton, Lee M. Daniels, Kim R. Dunbar, Carlos A. Murillo, and Hong-Cai Zhou pp 3414 - 3417; DOI: 10.1021/ic0001964 |
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Straightforward Conversion Route to Nanocrystalline Monothiooxides of Rare Earths through a High-Temperature Colloid Technique Yadong Li, Yu Huang, Tao Bai, and Longquan Li pp 3418 - 3420; DOI: 10.1021/ic9912169 |
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Synthesis of Arene-Soluble Dizirconium Nonaisopropoxide Lanthanide Cations Involving Divalent Ytterbium William J. Evans, Matthew A. Johnston, and Joseph W. Ziller pp 3421 - 3423; DOI: 10.1021/ic991437e |
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Synthesis, Characterization, and Properties of a Lithium 21-Thiaporphyrin Complex Andreas Gebauer, Joseph A. R. Schmidt, and John Arnold pp 3424 - 3427; DOI: 10.1021/ic000202w |
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On the Failure To Observe Isotropic Electron Paramagnetic Resonance Spectra for Certain Chromium(I) Carbonyl Complexes Alan M. Bond, Bruce R. McGarvey, Anne L. Rieger, and Philip H. Rieger pp 3428 - 3429; DOI: 10.1021/ic000178m |
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Intervalence Transfer at the Localized-to-Delocalized, Mixed-Valence Transition in Osmium Polypyridyl Complexes. Konstantinos D. Demadis, Gregory A. Neyhart, EdwardM. Kober, Peter S. White, and Thomas J. Meyer: pp 3430 - 3430; DOI: 10.1021/ic0002216 |
Issue 16
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Neutral Macrocycles via Halide-Induced Ring Opening of Binuclear Condensed Intermediates Felicia M. Dixon, Adam H. Eisenberg, Joshua R. Farrell, Chad A. Mirkin, Louise M. Liable-Sands, and Arnold L. Rheingold pp 3432 - 3433; DOI: 10.1021/ic000062q |
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Preparation of a Chiral, 2-Dimensional Network Containing Metallacrown and Copper Benzoate Building Blocks Jeffrey J. Bodwin and Vincent L. Pecoraro pp 3434 - 3435; DOI: 10.1021/ic000562j |
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Novel Biomimetic Calix[6]arene-Based Copper(II) Complexes Loïc Le Clainche, Michel Giorgi, and Olivia Reinaud pp 3436 - 3437; DOI: 10.1021/ic000072r |
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Novel Photoisomerization Behavior of Rh Binuclear Complexes Involving an Azobenzene-Bridged Bis(terpyridine) Ligand. Strong Effects of Counterion and Solvent and the Induction of Redox Potential Shift Tomona Yutaka, Masato Kurihara, Kenya Kubo, and Hiroshi Nishihara pp 3438 - 3439; DOI: 10.1021/ic000123k |
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(Tetrakis(2-pyridylmethyl)ethylenediamine)iron(II) Perchlorate. Study of Density Functional Methods Guangju Chen, G. Espinosa-Perez, A. Zentella-Dehesa, I. Silaghi-Dumitrescu, and F. Lara-Ochoa pp 3440 - 3448; DOI: 10.1021/ic990676z |
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Infrared and Raman Spectroscopic Investigations of the Nb(V) Fluoro and Oxofluoro Complexes in the LiF-NaF-KF Eutectic Melt with Development of a Diamond IR Cell K. B. Andersen, E. Christensen, R. W. Berg, N. J. Bjerrum, and J. H. von Barner pp 3449 - 3454; DOI: 10.1021/ic991057t |
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Mixed-Addenda Vanadium-Substituted Polyfluorooxometalates: Synthesis, Characterization, and Catalytic Aerobic Oxidation Alexander M. Khenkin and Ronny Neumann pp 3455 - 3462; DOI: 10.1021/ic990606s |
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Determination of Metal-Ligand Stoichiometries for Inorganic Complexes Using Total Reflection X-ray Fluorescence E. D. Greaves, L. Bennun, J. Gomez, P. Nemeth, and L. Sajo-Bohus pp 3463 - 3465; DOI: 10.1021/ic990628e |
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NMR and EPR Investigations of Iron Corrolates: Iron(III) Corrolate Cation Radicals or Iron(IV) Corrolates? Sheng Cai, F. Ann Walker, and Silvia Licoccia pp 3466 - 3478; DOI: 10.1021/ic990784l |
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Crystal Structures of a Family of Silver Cyanide Complexes of Thiourea and Substituted Thioureas Fred B. Stocker, Doyle Britton, and Victor G. Young, Jr. pp 3479 - 3484; DOI: 10.1021/ic990859l |
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Vanadium Complexes of the N(CH2CH2S)33- and O(CH2CH2S)22- Ligands with Coligands Relevant to Nitrogen Fixation Processes Sian C. Davies, David L. Hughes, Zofia Janas, Lucjan B. Jerzykiewicz, Raymond L. Richards, J. Roger Sanders, James E. Silverston, and Piotr Sobota pp 3485 - 3498; DOI: 10.1021/ic9909476 |
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Solid-State and Solution Structure of Lanthanide Complexes of a New Nonadentate Tripodal Ligand Containing Phenanthroline Binding Units Yann Bretonnière, Raphaël Wietzke, Colette Lebrun, Marinella Mazzanti, and Jacques Pécaut pp 3499 - 3505; DOI: 10.1021/ic991115a |
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Synthesis and Mossbauer Spectroscopic Studies of Chemically Oxidized Ferrocenyl(phenyl)phosphines Daniel A. Durfey, Rein U. Kirss, Christoph Frommen, and William Feighery pp 3506 - 3514; DOI: 10.1021/ic991147y |
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Pentadentate Terpyridine-Catechol Linked Ligands and Their Cobalt(III) Complexes Toshi Nagata and Koji Tanaka pp 3515 - 3521; DOI: 10.1021/ic9912880 |
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Effects of Substituents on the Thermodynamic and Kinetic Stabilities of HCGeX (X = H, CH3, F, and Cl) Isomers. A Theoretical Study Hsin-Yi Liao, Ming-Der Su, and San-Yan Chu pp 3522 - 3525; DOI: 10.1021/ic991324v |
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pH-Controlled Change of the Metal Coordination in a Dicopper(II) Complex of the Ligand H-BPMP: Crystal Structures, Magnetic Properties, and Catecholase Activity S. Torelli, C. Belle, I. Gautier-Luneau, J. L. Pierre, E. Saint-Aman, J. M. Latour, L. Le Pape, and D. Luneau pp 3526 - 3536; DOI: 10.1021/ic991450z |
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Syntheses and Electronic Spectroscopy of [PtL(L')][ClO4] Complexes (HL = 6-Phenyl-2,2'-bipyridine; L' = Pyridine, 4-Aminopyridine, 2-Aminopyridine, and 2,6-Diaminopyridine) John H. K. Yip, Suwarno, and Jagadese J. Vittal pp 3537 - 3543; DOI: 10.1021/ic9913482 |
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Dimolybdenum Bis((S,S,S)-triisopropanolaminate(3-)): A Blue Compound with an Unusual Mo-Mo Triple Bond Malcolm H. Chisholm, Ann M. Macintosh, John C. Huffman, Dedong Wu, Ernest R. Davidson, Robin J. H. Clark, and Steven Firth pp 3544 - 3550; DOI: 10.1021/ic991352d |
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Surface-Enhanced Raman Scattering and Surface-Enhanced Resonance Raman Scattering Excitation Profiles of Ag-2,2'-Bipyridine Surface Complexes and of [Ru(bpy)3]2+ on Ag Colloidal Surfaces: Manifestations of the Charge-Transfer Resonance Contributions to the Overall Surface Enhancement of Raman Scattering Ivana Srnová- loufová, Blanka Vlková, Theo L. Snoeck, Derk J. Stufkens, and Pavel Mat jkapp 3551 - 3559; DOI: 10.1021/ic991372f |
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Synthesis and Structural Characterization of Luminescent Trinuclear Gold(I) Complexes with Dithiocarbamates Manuel Bardají, Antonio Laguna, Peter G. Jones, and Axel K. Fischer pp 3560 - 3566; DOI: 10.1021/ic9914342 |
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Electrophilic Substitution of (Diamine)tetrahydroxoplatinum(IV) with Carboxylic Anhydrides. Synthesis and Characterization of (Diamine)platinum(IV) Complexes of Mixed Carboxylates Rita Song, Kwan Mook Kim, Sung Sil Lee, and Youn Soo Sohn pp 3567 - 3571; DOI: 10.1021/ic9913886 |
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Syntheses and Structures of Rhenium(IV) and Rhenium(V) Complexes with Ethanedithiolato Ligands Gábor Lente, Xiaopeng Shan, Ilia A. Guzei, and James H. Espenson pp 3572 - 3576; DOI: 10.1021/ic991446n |
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Detection of the EPR Spectra of NO in Ruthenium(II) Complexes Bruce R. McGarvey, Alessander Acacio Ferro, Elia Tfouni, Cicero Wellington Brito Bezerra, Izilda Bagatin, and Douglas W. Franco pp 3577 - 3581; DOI: 10.1021/ic9914701 |
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Synthesis and Structural Characterization of Highly Chlorinated, Brominated, Iodinated, and Methylated Carborane Anions, 1-H-CB9X9-, 1-NH2-CB9X9- (X = Cl, Br, I), and 1-H-CB9(CH3)9- Chi-Wing Tsang, Qingchuan Yang, Eric Tung-Po Sze, Thomas C. W. Mak, Dominic T. W. Chan, and Zuowei Xie pp 3582 - 3589; DOI: 10.1021/ic000137q |
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Mono- and Dinuclear Ruthenium(II) and Osmium(II) Polypyridine Complexes Built around Spiro-Bridged Bis(phenanthroline) Ligands: Synthesis, Electrochemistry, and Photophysics Alberto Juris, Luca Prodi, Anthony Harriman, Raymond Ziessel, Muriel Hissler, Abdelkrim El-ghayoury, Feiyue Wu, Elvira C. Riesgo, and Randolph P. Thummel pp 3590 - 3598; DOI: 10.1021/ic0000202 |
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Analysis of the Spin Exchange Interactions in the Three Phases of Vanadium Pyrophosphate, (VO)2P2O7, in Terms of Spin-Orbital Interaction Energy H.-J. Koo and M.-H. Whangbo pp 3599 - 3604; DOI: 10.1021/ic000046t |
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Stabilization of High-Valent Metals by Corroles: Oxo[tris(pentafluorophenyl)corrolato]chromium(V) Alexandre E. Meier-Callahan, Harry B. Gray, and Zeev Gross pp 3605 - 3607; DOI: 10.1021/ic000180d |
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Countercomplementarity and Strong Ferromagnetic Coupling in a Linear Mixed -Acetato, -Hydroxo Trinuclear Copper(II) Complex. Synthesis, Structure, Magnetic Properties, EPR, and Theoretical Studies L. Gutierrez, G. Alzuet, J. A. Real, J. Cano, J. Borrás, and A. Castiñeiras pp 3608 - 3614; DOI: 10.1021/ic000218m |
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Single-Molecule Magnets: A New Class of Tetranuclear Manganese Magnets Jae Yoo, Euan K. Brechin, Akira Yamaguchi, Motohiro Nakano, John C. Huffman, A. L. Maniero, Louis-Claude Brunel, Kunio Awaga, Hidehiko Ishimoto, George Christou, and David N. Hendrickson pp 3615 - 3623; DOI: 10.1021/ic000237w |
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Catecholate/Salicylate Heteropodands: Demonstration of a Catecholate to Salicylate Coordination Change Seth M. Cohen and Kenneth N. Raymond pp 3624 - 3631; DOI: 10.1021/ic990608c |
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Band Deconvolution Analysis of the Absorption and Magnetic Circular Dichroism Spectral Data of a Planar Phthalocyanine Dimer Nagao Kobayashi, Takamitsu Fukuda, and Dominique Lelièvre pp 3632 - 3637; DOI: 10.1021/ic991496s |
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Structural and Photophysical Studies of Cu(NN)2+ Systems in the Solid State. Emission at Last from Complexes with Simple 1,10-Phenanthroline Ligands Corey T. Cunningham, Jeffrey J. Moore, Kurstan L. H. Cunningham, Phillip E. Fanwick, and David R. McMillin pp 3638 - 3644; DOI: 10.1021/ic000082s |
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Mesogenic Palladium Complexes with Pincer Ligands Derived from Dipicolinic Acid Pablo Espinet, Esther García-Orodea, and Jesús A. Miguel pp 3645 - 3651; DOI: 10.1021/ic0001457 |
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N-Porphyrinylamino and -amido Compounds by Addition of an Amino or Amido Nitrogen to a Porphyrin Meso Position K. Jayaraj, A. Gold, L. M. Ball, and P. S. White pp 3652 - 3664; DOI: 10.1021/ic000112r |
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Definitive Assignment of the g Tensor of [Fe(OEP)(NO)] by Single-Crystal EPR Robert G. Hayes, Mary K. Ellison, and W. Robert Scheidt pp 3665 - 3668; DOI: 10.1021/ic000159c |
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meso-Aryl Smaragdyrins: Novel Anion and Metal Receptors Bashyam Sridevi, Seenichamy Jeyaprakash Narayanan, Rohini Rao, Tavarekere K. Chandrashekar, Ulrich Englich, and Karin Ruhlandt-Senge pp 3669 - 3677; DOI: 10.1021/ic000031v |
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Syntheses and Structures of the Arylaluminum Chalcogenides (ArAlE)2 (Ar = 2-(NEt2CH2)-6-MeC6H3, E = Se; Ar = 2,6-(NEt2CH2)2C6H3, E = Se, Te) Chunming Cui, Herbert W. Roesky, Mathias Noltemeyer, and Hans-Georg Schmidt pp 3678 - 3681; DOI: 10.1021/ic000255d |
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Raman Study of the Hexafluoroaluminate Ion in Solid and Molten FLINAK Murray H. Brooker, Rolf W. Berg, Jens H. von Barner, and Niels J. Bjerrum pp 3682 - 3689; DOI: 10.1021/ic000260h |
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Electronic and Resonance Raman Spectra of [Au2(CS3)2]2-. Spectroscopic Properties of a "Short" Au(I)-Au(I) Bond Eddie Chung-Chin Cheng, King-Hung Leung, Vincent M. Miskowski, Vivian Wing-Wah Yam, and David Lee Phillips pp 3690 - 3695; DOI: 10.1021/ic000265e |
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Ortho-Linked Polyaryloxide Ligands and Their Titanium Complexes Ajay Kayal, Andrew F. Ducruet, and Sonny C. Lee pp 3696 - 3704; DOI: 10.1021/ic000275f |
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Solvothermal Construction of a Coordination Polymer around in Situ Generated Pyroglutamic Acid: Preparation, Crystal Structure, and Magnetic Behavior of [Mn(C5H6NO3)2] Siegfried O. H. Gutschke, Daniel J. Price, Annie K. Powell, and Paul T. Wood pp 3705 - 3707; DOI: 10.1021/ic9912427 |
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Model Complexes for the Active Form of Galactose Oxidase. Physicochemical Properties of Cu(II)- and Zn(II)-Phenoxyl Radical Complexes Shinobu Itoh, Masayasu Taki, Hideyuki Kumei, Shigehisa Takayama, Shigenori Nagatomo, Teizo Kitagawa, Norio Sakurada, Ryuichi Arakawa, and Shunichi Fukuzumi pp 3708 - 3711; DOI: 10.1021/ic9910211 |
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Reactivity of Organometallic Molybdate toward Lanthanide Cations. Synthesis and Structure of Polynuclear Lanthanide-Molybdate Complexes M. Hashimoto, M. Takata, and A. Yagasaki pp 3712 - 3714; DOI: 10.1021/ic991221c |
Synthesis and Molecular Structure of (TTP)Ti(1,2-2-PhC C-CCPh)Jinyuan Chen, Ilia A. Guzei, and L. Keith Woo pp 3715 - 3717; DOI: 10.1021/ic9912575 |
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Conjugation Involving Nitrogen Lone-Pair Electrons: Can It Lead to Stable Multiply Charged Cations? C. H. Suresh and Nobuaki Koga pp 3718 - 3721; DOI: 10.1021/ic000001s |
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Nitrosyl Transfer from Manganese to Iron in Tropocoronand Complexes Katherine J. Franz and Stephen J. Lippard pp 3722 - 3723; DOI: 10.1021/ic000360n |
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Ethylene Oxide and Propylene Sulfide Complexes of Silver(I): Synthesis and Characterization of [HB(3,5-(CF3)2Pz)3]Ag(OC2H4) and [HB(3,5-(CF3)2Pz)3]Ag(SC3H6) H. V. Rasika Dias and Ziyun Wang pp 3724 - 3727; DOI: 10.1021/ic991334w |
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A Dichromium(II,II) Compound with a Strong Antiferromagnetic Coupling but Little or No Cr-Cr Bonding F. Albert Cotton, Carlos A. Murillo, and Hong-Cai Zhou pp 3728 - 3730; DOI: 10.1021/ic0002115 |
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The Propionate of Heme Binds N4O2 Schiff Base Antimalarial Drug Complexes James Ziegler, Theresa Schuerle, Lisa Pasierb, Crystal Kelly, Ashraf Elamin, Kelly A. Cole, and David W. Wright pp 3731 - 3733; DOI: 10.1021/ic000295h |
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Inversion of the Cis Geometry Requirement for Cytotoxicity in Structurally Novel Platinum(II) Complexes Containing the Bidentate N,O-Donor Pyridin-2-yl-acetate. Ulrich Bierbach, Michal Sabat, and Nicholas Farrell: pp 3734 - 3734; DOI: 10.1021/ic0004535 |
Issue 17
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Synthesis and Magnetic and Structural Characterization of the First Homoleptic Lanthanide -Ketoiminate William S. Rees, Jr., Oliver Just, Stephanie L. Castro, and Jason S. Matthews pp 3736 - 3737; DOI: 10.1021/ic000203o |
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Dual Pathways for TiO2 Sensitization by Na2[Fe(bpy)(CN)4] Mei Yang, David W. Thompson, and Gerald J. Meyer pp 3738 - 3739; DOI: 10.1021/ic000415l |
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Ligand-Centered Near-Infrared Luminescence from Lanthanide Complexes with Chelating Nitronyl Nitroxide Free Radicals Christophe Lescop, Dominique Luneau, Guillaume Bussière, Myriam Triest, and Christian Reber pp 3740 - 3741; DOI: 10.1021/ic0004941 |
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Syntheses and Characterization of Anti-inflammatory Dinuclear and Mononuclear Zinc Indomethacin Complexes. Crystal Structures of [Zn2(Indomethacin)4(L)2] (L = N,N-Dimethylacetamide, Pyridine, 1-Methyl-2-pyrrolidinone) and [Zn(Indomethacin)2(L1)2] (L1 = Ethanol, Methanol) Qingdi Zhou, Trevor W. Hambley, Brendan J. Kennedy, Peter A. Lay, Peter Turner, Barry Warwick, John R. Biffin, and Hubertus L. Regtop pp 3742 - 3748; DOI: 10.1021/ic991477i |
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Reactivity of [RuHCl(PiPr3)2]2 with Functionalized Vinyl Substrates. The H2 Ligand as a Sensitive Probe of Electronic Structure Joseph N. Coalter, III, William E. Streib, and Kenneth G. Caulton pp 3749 - 3756; DOI: 10.1021/ic9905998 |
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A New Class of Electron-Rich Unsaturated Molecules: Ru2HnX4-n(PiPr3)4, X = Anion Joseph N. Coalter, III, John C. Huffman, William E. Streib, and Kenneth G. Caulton pp 3757 - 3764; DOI: 10.1021/ic991112y |
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Tuning Charge Recombination Rate Constants through Inner-Sphere Coordination in a Copper(I) Donor-Acceptor Compound Donald V. Scaltrito, Craig A. Kelly, Mark Ruthkosky, Mark C. Zaros, and Gerald J. Meyer pp 3765 - 3770; DOI: 10.1021/ic000197w |
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Oxalato-Bridged Dinuclear Complexes of Cr(III) and Fe(III): Synthesis, Structure, and Magnetism of [(C2H5)4N]4[MM'(ox)(NCS)8] with MM' = CrCr, FeFe, and CrFe Smaïl Triki, Florence Bérézovsky, Jean Sala Pala, Eugenio Coronado, Carlos J. Gómez-García, Juan Modesto Clemente, Amédée Riou, and Philippe Molinié pp 3771 - 3776; DOI: 10.1021/ic990439w |
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Ligand Substitution Behavior of a Simple Model for Coenzyme B12 Mohamed S. A. Hamza, Carlos Dücker-Benfer, and Rudi van Eldik pp 3777 - 3783; DOI: 10.1021/ic000023e |
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Importance of Multiple-Scattering Phenomena in XAS Structural Determinations of [Ni(CN)4]2- in Condensed Phases Adela Muñoz-Páez, Sofía Díaz-Moreno, Enrique Sánchez Marcos, and John J. Rehr pp 3784 - 3790; DOI: 10.1021/ic000274n |
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Hydrothermal Synthesis of (C6N2H14)2(UVI2UIVO4F12), a Mixed-Valent One-Dimensional Uranium Oxyfluoride Simon Allen, Stephen Barlow, P. Shiv Halasyamani, J. Frederick W. Mosselmans, Dermot O'Hare, Susan M. Walker, and Richard I. Walton pp 3791 - 3798; DOI: 10.1021/ic000193r |
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Single-Crystal Polarized Optical Absorption Spectroscopy of the One-Dimensional Ferrimagnet MnIICuII(pba)(H2O)3·2H2O (pba = 1,3-Propylenebis(oxamato)) Olivier Cador, Corine Mathonière, and Olivier Kahn pp 3799 - 3804; DOI: 10.1021/ic991264t |
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Synthesis and Structures of Heterocyclic Azidogallanes [(CH3)ClGaN3]4 and [(CH3)BrGaN3]3 en Route to [(CH3)HGaN3]x: An Inorganic Precursor to GaN J. Kouvetakis, J. McMurran, Cory Steffek, T. L. Groy, and John L. Hubbard pp 3805 - 3809; DOI: 10.1021/ic000053h |
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1:1 Complexes of Dimethylthio- and Ethylenedithio-tetrathiafulvalenothioquinone- 1,3-dithiolemethides with CuBr2 as a New Type of /d Molecular System Masaki Iwamatsu, Tsuyoshi Kominami, Kazumasa Ueda, Toyonari Sugimoto, Tomohiro Adachi, Hideo Fujita, Harukazu Yoshino, Yoshiyuki Mizuno, Keizo Murata, and Motoo Shiro pp 3810 - 3815; DOI: 10.1021/ic0001098 |
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Structure and Reactivity of Aquacarbonylruthenium(II) Complexes. An X-ray and Oxygen-17 NMR Study Urs C. Meier, Rosario Scopelliti, Euro Solari, and André E. Merbach pp 3816 - 3822; DOI: 10.1021/ic0002317 |
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Structural Characterization of the Picket Fence (TpivPP) Porphyrins Co(TpivPP), Co(TpivPP)(NO2)(1-MeIm), and Co(TpivPP)(NO2)(1,2-Me2Im) Paul G. Jene and James A. Ibers pp 3823 - 3827; DOI: 10.1021/ic000127p |
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A Dimeric Titanium-Containing Polyoxometalate. Synthesis, Characterization, and Catalysis of H2O2-Based Thioether Oxidation Oxana A. Kholdeeva, Gennadii M. Maksimov, Raisa I. Maksimovskaya, Lyubov A. Kovaleva, Martin A. Fedotov, Vladimir A. Grigoriev, and Craig L. Hill pp 3828 - 3837; DOI: 10.1021/ic0000653 |
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Synthesis, Characterization, and Crystal Structure of -[Ru(azpy)2(NO3)2] (azpy = 2-(Phenylazo)pyridine) and the Products of Its Reactions with Guanine Derivatives Anna C. G. Hotze, Aldrik H. Velders, Franco Ugozzoli, Marina Biagini-Cingi, Anna M. Manotti-Lanfredi, Jaap G. Haasnoot, and Jan Reedijk pp 3838 - 3844; DOI: 10.1021/ic000066v |
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Magnetic Coupling through the Carbon Skeleton of Malonate in Two Polymorphs of {[Cu(bpy)(H2O)][Cu(bpy)(mal)(H2O)]}(ClO4)2 (H2mal = Malonic Acid; bpy = 2,2'-Bipyridine) Catalina Ruiz-Pérez, María Hernández-Molina, Pablo Lorenzo-Luis, Francesc Lloret, Juan Cano, and Miguel Julve pp 3845 - 3852; DOI: 10.1021/ic000314n |
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Synthesis, Spectroscopic, and Structural Studies on Transition Metal Complexes Involving Homoleptic Tripodal Selenoether and Telluroether Coordination William Levason, Simon D. Orchard, and Gillian Reid pp 3853 - 3859; DOI: 10.1021/ic991330r |
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Sterically Encumbered Systems for Two Low-Coordinate Phosphorus Centers Shashin Shah, Tom Concolino, Arnold L. Rheingold, and John D. Protasiewicz pp 3860 - 3867; DOI: 10.1021/ic0001558 |
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The Flash-Quench Technique in Protein-DNA Electron Transfer: Reduction of the Guanine Radical by Ferrocytochrome c Eric D. A. Stemp and Jacqueline K. Barton pp 3868 - 3874; DOI: 10.1021/ic0000698 |
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Syntheses, Structures, and Reactivities of Heteroleptic Magnesium Amide Thiolates Weijie Teng, Ulrich Englich, and Karin Ruhlandt-Senge pp 3875 - 3880; DOI: 10.1021/ic9913738 |
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Interaction of Oxo-Bridged Vanadium(III) Phenanthroline and Bipyridine Dimers with DNA Shiela J. Heater, Mary W. Carrano, Douglas Rains, Ronald B. Walter, David Ji, Quing Yan, Roman S. Czernuszewicz, and Carl J. Carrano pp 3881 - 3889; DOI: 10.1021/ic000389r |
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Adduct Formation or Metathesis Reactions of Silver Complexes Containing the Fluorinated Ligands [HB(3,5-(CF3)2Pz)3]- and [CF3SO3]-: Formation of Silver Adducts Containing Unsupported Silver-Germanium Bonds H. V. Rasika Dias and Ziyun Wang pp 3890 - 3893; DOI: 10.1021/ic000414t |
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Copper and Silver Complexes Containing Organic Azide Ligands: Syntheses, Structures, and Theoretical Investigation of [HB(3,5-(CF3)2Pz)3]CuNNN(1-Ad) and [HB(3,5-(CF3)2Pz)3]AgN(1-Ad)NN (Where Pz = Pyrazolyl and 1-Ad = 1-Adamantyl) H. V. Rasika Dias, Sharon A. Polach, Sor-Koon Goh, Edet F. Archibong, and Dennis S. Marynick pp 3894 - 3901; DOI: 10.1021/ic0004232 |
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Symmetry of Metal Chelates Charles L. Perrin and Yeong-Joon Kim pp 3902 - 3910; DOI: 10.1021/ic000382+ |
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Resonance Raman and Semiempirical Electronic Structure Studies of an Odd-Electron Dinickel Tetraiminoethylenedimacrocycle Complex Gerald M. Sando, Anandhi Ray, Larry O. Spreer, Kenneth G. Spears, and Joseph T. Hupp pp 3911 - 3914; DOI: 10.1021/ic991326f |
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Crystal Structures and Solution Behavior of Paramagnetic Divalent Transition Metal Complexes (Fe, Co) of the Sterically Encumbered Tridentate Macrocycles 1,4,7-R3-1,4,7-Triazacyclononane: Coordination Numbers 5 (R = i-Pr) and 6 (R = i-Bu) Alain Diebold, Abdelaziz Elbouadili, and Karl S. Hagen pp 3915 - 3923; DOI: 10.1021/ic000456h |
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The First Mixed-Valence Fluorotin Alkoxides: New Sol-Gel Precursors of Fluorine-Doped Tin Oxide Materials D. Boegeat, B. Jousseaume, T. Toupance, G. Campet, and L. Fournès pp 3924 - 3927; DOI: 10.1021/ic000111z |
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Synthesis of Bis-Thiolato-Bridged Ru(III) Dimers. The Crystal Structure of [Ru(H2edta)(-SC6H5)]2 Beth R. Cameron, Gary J. Bridger, Kevin P. Maresca, and Jon Zubieta pp 3928 - 3930; DOI: 10.1021/ic990787y |
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Synthesis and Characterization of Chelating Triamide Complexes of Bismuth and Antimony Mark R. Mason, Stanley S. Phulpagar, Mark S. Mashuta, and John F. Richardson pp 3931 - 3933; DOI: 10.1021/ic991462k |
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A New Structural Class of Lanthanide Carbonates: Synthesis, Properties, and X-ray Structure of the One-Dimensional Chain Complex [Co(NH3)6]6[K2(H2O)10]-[Nd2(CO3)8]2·20H2O Deborah L. Bond, David L. Clark, Robert J. Donohoe, John C. Gordon, Pamela L. Gordon, D. Webster Keogh, Brian L. Scott, C. Drew Tait, and John G. Watkin pp 3934 - 3937; DOI: 10.1021/ic0001255 |
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Oxidative Additions of cyclo-Octasulfur and cyclo-Octaselenium to the Cobalt(II) Complex of 1,3-Bis(dimethylphosphino)propane (dmpp): Crystal Structures and Spectroscopic Properties of [Co(S2O)(dmpp)2]PF6 and [Co(Se2)(dmpp)2]BF4 Takayoshi Suzuki, Naoki Tsuji, Kazuo Kashiwabara, and Kazuyuki Tatsumi pp 3938 - 3941; DOI: 10.1021/ic000289l |
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Bimetallic Pt/Ru Complexes as Catalysts for the Electrooxidation of Methanol Mark E. Tess, Pamela L. Hill, Karen E. Torraca, Margaret E. Kerr, Khalil A. Abboud, and Lisa McElwee-White pp 3942 - 3944; DOI: 10.1021/ic0004434 |
Issue 18
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The Structure-Directing Properties of [VOF5]2- Margaret E. Welk, Alexander J. Norquist, Charlotte L. Stern, and Kenneth R. Poeppelmeier pp 3946 - 3947; DOI: 10.1021/ic000416d |
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Syntheses of Ketonated Disulfide-Bridged Diruthenium Complexes via C-H Bond Activation and C-S Bond Formation Hiroyasu Sugiyama, Md. Munkir Hossain, Yong-Shou Lin, and Kazuko Matsumoto pp 3948 - 3956; DOI: 10.1021/ic0000855 |
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Unsaturated Ru(0) Species with a Constrained Bis-Phosphine Ligand: [Ru(CO)2(tBu2PCH2CH2PtBu2)]2. Comparison to [Ru(CO)2(PtBu2Me)2] Torsten Gottschalk-Gaudig, John C. Huffman, Hélène Gérard, Odile Eisenstein, and Kenneth G. Caulton pp 3957 - 3962; DOI: 10.1021/ic9911320 |
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Preparation of Polyetherol-Appended Sulfur Porphyrazines and Investigations of Peripheral Metal Ion Binding in Polar Solvents Lori A. Ehrlich, Peter J. Skrdla, Wade K. Jarrell, John W. Sibert, Neal R. Armstrong, S. Scott Saavedra, Anthony G. M. Barrett, and Brian M. Hoffman pp 3963 - 3969; DOI: 10.1021/ic991033m |
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Vanadium(IV) and -(V) Complexes with O,N-Chelating Aminophenolate and Pyridylalkoxide Ligands Henk Hagen, Chris Bezemer, Jaap Boersma, Huub Kooijman, Martin Lutz, Anthony L. Spek, and Gerard van Koten pp 3970 - 3977; DOI: 10.1021/ic991415s |
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An Integrated Approach to the Mid-Spin State (S = 3/2) in Six-Coordinate Iron(III) Chiroporphyrins Jean-Pierre Simonato, Jacques Pécaut, Laurent Le Pape, Jean-Louis Oddou, Claudine Jeandey, Maoyu Shang, W. Robert Scheidt, Jacek Wojaczy ski, Stanisaw Woowiec, Lechosaw Latos-Grayski, and Jean-Claude Marchonpp 3978 - 3987; DOI: 10.1021/ic000150a |
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Syntheses of Novel Exo and Endo Isomers of Ansa-Substituted Fluorophosphazenes and Their Facile Transformations into Spiro Isomers in the Presence of Fluoride Ions K. Muralidharan, N. Dastagiri Reddy, and Anil J. Elias pp 3988 - 3994; DOI: 10.1021/ic0001863 |
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Application of n-Bu4NHF2 as a Fluorinating Agent for the Preparation of Fluoroanions: Synthesis and Crystal Structure of the Anions [t-BuPO3AlF2]22-, [PhPO3AlF2]22-, and [(O-i-Pr)3Ti(-F)2(-O-i-Pr)Ti(O-i-Pr)3]- Debashis Chakraborty, Sabine Horchler, Herbert W. Roesky, Mathias Noltemeyer, and Hans-Georg Schmidt pp 3995 - 3998; DOI: 10.1021/ic991453b |
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TAS+(Z)-Me3CNSN- and TAS+(E)-Me3SiNSN-: Does the Anion-Cation Interaction Influence the Configuration? Tobias Borrmann, Andrey V. Zibarev, Enno Lork, Gerd Knitter, Shan-Jia Chen, Paul G. Watson, Edgardo Cutin, Makhmut M. Shakirov, Wolf-Dieter Stohrer, and Rüdiger Mews pp 3999 - 4005; DOI: 10.1021/ic0004030 |
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Steric Effects Control the Structure of the Solvated Lanthanum(III) Ion in Aqueous, Dimethyl Sulfoxide, and N,N'-Dimethylpropyleneurea Solution. An EXAFS and Large-Angle X-ray Scattering Study Jan Näslund, Patric Lindqvist-Reis, Ingmar Persson, and Magnus Sandström pp 4006 - 4011; DOI: 10.1021/ic991208s |
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Solvation of the Bismuth(III) Ion by Water, Dimethyl Sulfoxide, N,N'-Dimethylpropyleneurea, and N,N-Dimethylthioformamide. An EXAFS, Large-Angle X-ray Scattering, and Crystallographic Structural Study Jan Näslund, Ingmar Persson, and Magnus Sandström pp 4012 - 4021; DOI: 10.1021/ic000022m |
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Luminescent Langmuir-Blodgett Films of Platinum(II) Complex [Pt(L18)Cl](PF6) (L18 = 2,6-Bis(1-octadecylbenzimidazol-2-yl)pyridine) Kezhi Wang, Masa-aki Haga, Hideaki Monjushiro, Masaharu Akiba, and Yoichi Sasaki pp 4022 - 4028; DOI: 10.1021/ic990880m |
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M(-CN)Fe(-CN)M' Chains with Phthalocyanine Iron Centers: Preparation, Structures, and Isomerization Andreas Geiss and Heinrich Vahrenkamp pp 4029 - 4036; DOI: 10.1021/ic0001412 |
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M(-CN)Fe(-CN)M' Chains with Phthalocyanine Iron Centers: Redox, Spin-State, and Mixed-Valence Properties Andreas Geiss, Mario J. Kolm, Christoph Janiak, and Heinrich Vahrenkamp pp 4037 - 4043; DOI: 10.1021/ic000096y |
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Manganese Citrate Chemistry: Syntheses, Spectroscopic Studies, and Structural Characterizations of Novel Mononuclear, Water-Soluble Manganese Citrate Complexes M. Matzapetakis, N. Karligiano, A. Bino, M. Dakanali, C. P. Raptopoulou, V. Tangoulis, A. Terzis, J. Giapintzakis, and A. Salifoglou pp 4044 - 4051; DOI: 10.1021/ic9912631 |
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Metal vs Ligand Reduction in Complexes of 1,3-Dimethylalloxazine (DMA) with Copper(I), Ruthenium(II), and Tungsten(VI). Crystal Structures of (DMA)WO2Cl2 and (Bis(1-methylimidazol-2-yl)ketone)WO2Cl2 Fridmann M. Hornung, Oliver Heilmann, Wolfgang Kaim, Stanislav Zalis, and Jan Fiedler pp 4052 - 4058; DOI: 10.1021/ic0001816 |
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Ligand Macrocycle Structural Effects on Copper-Dioxygen Reactivity Bernice M. T. Lam, Jason A. Halfen, Victor G. Young, Jr., John R. Hagadorn, Patrick L. Holland, Agustí Lledós, Lourdes Cucurull-Sánchez, Juan J. Novoa, Santiago Alvarez, and William B. Tolman pp 4059 - 4072; DOI: 10.1021/ic000248p |
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Tuning the Rotational Behavior of Lopsided Heterocyclic Nitrogen Ligands (L) in Octahedral cis-[Ru(bpy)2(L)2](PF6)2 Complexes. A Variable-Temperature 1H NMR Study Aldrik H. Velders, Anna C. G. Hotze, Gerard A. van Albada, Jaap G. Haasnoot, and Jan Reedijk pp 4073 - 4080; DOI: 10.1021/ic000152v |
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Aminotroponiminates as Ligands for Potential Metal-Based Nitric Oxide Sensors Katherine J. Franz, Nisha Singh, Bernhard Spingler, and Stephen J. Lippard pp 4081 - 4092; DOI: 10.1021/ic000344q |
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Trithiacyclononane as a Ligand for Potential Technetium and Rhenium Radiopharmaceuticals: Synthesis of [M(9S3)(SC2H4SC2H4S)][BF4] (M = 99Tc, Re, 188Re) via C-S Bond Cleavage Gregory E. D. Mullen, Philip J. Blower, Daniel J. Price, Anne K. Powell, Mark J. Howard, and Michael J. Went pp 4093 - 4098; DOI: 10.1021/ic991240m |
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Calix[4]arene Rhenium(V) Complexes as Potential Radiopharmaceuticals Kjeld J. C. van Bommel, Willem Verboom, Ron Hulst, Huub Kooijman, Anthony L. Spek, and David N. Reinhoudt pp 4099 - 4106; DOI: 10.1021/ic000172x |
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Hydrolysis, Hydrosulfidolysis, and Aminolysis of Imido(methyl)rhenium Complexes Wei-Dong Wang, Ilia A. Guzei, and James H. Espenson pp 4107 - 4112; DOI: 10.1021/ic0000956 |
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Kinetics and Mechanisms of Reactions of Methyldioxorhenium(V) in Aqueous Solutions: Dimer Formation and Oxygen-Atom Abstraction Reactions James H. Espenson and Douglas Tak Yeung Yiu pp 4113 - 4118; DOI: 10.1021/ic000128h |
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Electron Transfer. 144. Reductions with Germanium(II) Olga A. Babich and Edwin S. Gould pp 4119 - 4122; DOI: 10.1021/ic0004582 |
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C-Substituted Macrocycles as Candidates for Radioimmunotherapy Paul V. Bernhardt and Philip C. Sharpe pp 4123 - 4129; DOI: 10.1021/ic000315f |
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Characterization of a New Hexasodium Diphosphopentamolybdate Hydrate, Na6[P2Mo5O23]·7H2O, by 23Na MQMAS NMR Spectroscopy and X-ray Powder Diffraction J rgen Skibsted, Michael Brorson, Jrgen Villadsen, and Hans J. Jakobsenpp 4130 - 4136; DOI: 10.1021/ic000309j |
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Speciation and Kinetics Related to Catalytic Carbonylation in the Presence of cis-[Ir(CO)2I2]P(C6H5)4 under CO and H2 Pressures Raphaël Churlaud, Urban Frey, François Metz, and André E. Merbach pp 4137 - 4142; DOI: 10.1021/ic000269j |
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Sc6MTe2 (M = Mn, Fe, Co, Ni): Members of the Flexible Zr6CoAl2-Type Family of Compounds Paul A. Maggard and John D. Corbett pp 4143 - 4146; DOI: 10.1021/ic0003269 |
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Azido Derivatives of Low-Valent Group 14 Elements: Synthesis, Characterization, and Electronic Structure of [(n-Pr)2ATI]GeN3 and [(n-Pr)2ATI]SnN3 Featuring Heterobicyclic 10--Electron Ring Systems Ashley E. Ayers, Dennis S. Marynick, and H. V. Rasika Dias pp 4147 - 4151; DOI: 10.1021/ic000545u |
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Synthesis and Molecular Structure of a Plutonium(IV) Coordination Complex: [Pu(NO3)2{2,6-[(C6H5)2P(O)CH2]2C5H3NO}2](NO3)21.5H2O0.5MeOH Evelyn M. Bond, Eileen N. Duesler, Robert T. Paine, Mary P. Neu, John H. Matonic, and Brian L. Scott pp 4152 - 4155; DOI: 10.1021/ic000146z |
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Plutonium(IV) Sequestration: Structural and Thermodynamic Evaluation of the Extraordinarily Stable Cerium(IV) Hydroxypyridinonate Complexes Jide Xu, Emil Radkov, Marco Ziegler, and Kenneth N. Raymond pp 4156 - 4164; DOI: 10.1021/ic000063i |
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Syntheses, Structures and Magnetic Behaviors of Di- and Trinuclear Pivalate Complexes Containing Both Cobalt(II) and Lanthanide(III) Ions Yong Cui, Gang Chen, Jin Ren, Yitai Qian, and Jinshun Huang pp 4165 - 4168; DOI: 10.1021/ic000230e |
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Three-Dimensional Manganese(II) Coordination Polymers Based on m-Pyridinecarboxylates: Synthesis, X-ray Structures, and Magnetic Properties Wenbin Lin, Mary E. Chapman, Zhiyong Wang, and Gordon T. Yee pp 4169 - 4173; DOI: 10.1021/ic000227v |
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A New Porous Three-Dimensional Lanthanide Coordination Polymer Long Pan, E. Brice Woodlock, Xiaotai Wang, and Chong Zheng pp 4174 - 4178; DOI: 10.1021/ic000209d |
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The Vanadium(V) Borophosphate (NH4)5[V3BP3O19]·H2O Ranko P. Bontchev, Junghwan Do, and Allan J. Jacobson pp 4179 - 4181; DOI: 10.1021/ic000436f |
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Weak Ferromagnetism in a Three-Dimensional Manganese(II) Azido Complex, [Mn(4,4'-bipy)(N3)2]n (bipy = Bipyridine) Sujin Han, Jamie L. Manson, Jinkwon Kim, and Joel S. Miller pp 4182 - 4185; DOI: 10.1021/ic000307z |
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Conversion of Core Oxos to Water Molecules by 4e-/4H+ Reductive Dehydration of the Mn4O26+ Core in the Manganese-Oxo Cubane Complex Mn4O4(Ph2PO2)6: A Partial Model for Photosynthetic Water Binding and Activation. Wolfgang F. Ruettinger and G. Charles Dismukes: pp 4186 - 4186; DOI: 10.1021/ic000692s |
Issue 19
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Monodentate-Bridged Phosphodiester and Sulfate Complexes: Structural Insights into the Biological Activation of Phosphodiesters, Sulfate, and Sulfate Esters Chuan He, Victoria Gomez, Bernhard Spingler, and Stephen J. Lippard pp 4188 - 4189; DOI: 10.1021/ic000391i |
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Varying Coordination Modes and Magnetic Properties of Copper(II) Complexes with Diazamesocyclic Ligands by Altering Additional Donor Pendants on 1,5-Diazacyclooctane Xian-He Bu, Miao Du, Zhi-Liang Shang, Ruo-Hua Zhang, Dai-Zheng Liao, Mitsuhiko Shionoya, and Thomas Clifford pp 4190 - 4199; DOI: 10.1021/ic000094d |
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Electronic Structures of M21S8 (M = Nb, Zr) and (M,M')21S8 (M, M' = Hf, Ti; Nb, Ta) Phases and Reasons for Variations in the Metal Site Occupations Martin Köckerling and Enric Canadell pp 4200 - 4205; DOI: 10.1021/ic991218t |
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Ab Initio Study of Rearrangements on the (CH)2(BR)2, R=H, and NH2 Potential Energy Surfaces Michael L. McKee pp 4206 - 4210; DOI: 10.1021/ic000240f |
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Synthesis and Characterization of Mixed-Ligand Oxorhenium Complexes with the SNN Type of Ligand. Isolation of a Novel ReO[SN][S][S] Complex A. Rey, I. Pirmettis, M. Pelecanou, M. Papadopoulos, C. P. Raptopoulou, L. Mallo, C. I. Stassinopoulou, A. Terzis, E. Chiotellis, and A. León pp 4211 - 4218; DOI: 10.1021/ic991491v |
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Mercury(I) Molybdates and Tungstates: Hg2WO4 and Two Modifications of Hg2MoO4 Thomas J. Mormann and Wolfgang Jeitschko pp 4219 - 4223; DOI: 10.1021/ic000331c |
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Preparation and Oxygenation of (Flavonolato)copper Isoindoline Complexes with Relevance to Quercetin Dioxygenase Éva Balogh-Hergovich, József Kaizer, Gábor Speier, Gottfried Huttner, and Albrecht Jacobi pp 4224 - 4229; DOI: 10.1021/ic990521r |
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New Antitumor-Active Azole-Bridged Dinuclear Platinum(II) Complexes: Synthesis, Characterization, Crystal Structures, and Cytotoxic Studies Seiji Komeda, Martin Lutz, Anthony L. Spek, Masahiko Chikuma, and Jan Reedijk pp 4230 - 4236; DOI: 10.1021/ic000273v |
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Synthesis of SnSe in Various Alkaline Media under Mild Conditions C. Wang, Y. D. Li, G. H. Zhang, J. Zhuang, and G. Q. Shen pp 4237 - 4239; DOI: 10.1021/ic991332b |
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Bis(mercaptoimidazolyl)(pyrazolyl)hydroborato Complexes of Zinc, Cadmium, and Cobalt: Structural Evidence for the Enhanced Tendency of Zinc in Biological Systems to Adopt Tetrahedral M[S4] Coordination Clare Kimblin, Brian M. Bridgewater, David G. Churchill, Tony Hascall, and Gerard Parkin pp 4240 - 4243; DOI: 10.1021/ic000093l |
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The OsO4F-, OsO4F22-, and OsO3F3- Anions, Their Study by Vibrational and NMR Spectroscopy and Density Functional Theory Calculations, and the X-ray Crystal Structures of [N(CH3)4][OsO4F] and [N(CH3)4][OsO3F3] Michael Gerken, David A. Dixon, and Gary J. Schrobilgen pp 4244 - 4255; DOI: 10.1021/ic000259i |
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Ruthenium(II) Complexes of Redox-Related, Modified Dipyridophenazine Ligands: Synthesis, Characterization, and DNA Interaction Arounaguiry Ambroise and Bhaskar G. Maiya pp 4256 - 4263; DOI: 10.1021/ic991468+ |
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Ruthenium(II) Complexes of 6,7-Dicyanodipyridoquinoxaline: Synthesis, Luminescence Studies, and DNA Interaction Arounaguiry Ambroise and Bhaskar G. Maiya pp 4264 - 4272; DOI: 10.1021/ic9914692 |
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2-D Interwoven and 3-D 5-fold Interpenetrating Silver(I) Complexes of 1-(Isocyanidomethyl)-1H-benzotriazole and 1,3-Bis(dicyanomethylidene)indan Ichiro Ino, Jian Chu Zhong, Megumu Munakata, Takayoshi Kuroda-Sowa, Masahiko Maekawa, Yusaku Suenaga, and Yoshinobu Kitamori pp 4273 - 4279; DOI: 10.1021/ic000459u |
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Synthesis, Structure, Luminescence, and Theoretical Studies of Tetranuclear Gold Clusters with Phosphinocarborane Ligands M. José Calhorda, Olga Crespo, M. Concepción Gimeno, Peter G. Jones, Antonio Laguna, José M. López-de-Luzuriaga, Juán L. Perez, Miguel A. Ramón, and Luís F. Veiros pp 4280 - 4285; DOI: 10.1021/ic000136y |
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Kinetics and Mechanism for Reversible Chloride Transfer between Mercury(II) and Square-Planar Platinum(II) Chloro Ammine, Aqua, and Sulfoxide Complexes. Stabilities, Spectra, and Reactivities of Transient Metal-Metal Bonded Platinum-Mercury Adducts Östen Gröning, Alan M. Sargeson, Robert J. Deeth, and Lars I. Elding pp 4286 - 4294; DOI: 10.1021/ic000320j |
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Formation of One-, Two-, and Three-Dimensional Open-Framework Zinc Phosphates in the Presence of a Tetramine Amitava Choudhury, Srinivasan Natarajan, and C. N. R. Rao pp 4295 - 4304; DOI: 10.1021/ic000366c |
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Influence of Hydrogen Bonding on the Assembly of Six-Membered Vanadium Borophosphate Cluster Anions: Synthesis and Structures of (NH4)2(C2H10N2)6[Sr(H2O)5]2[V2P2BO12]6·10H2O, (NH4)2(C3H12N2)6[Sr(H2O)4]2[V2P2BO12]6·17H2O, and (NH4)3(C4H14N2)4.5[Sr(H2O)5]2[Sr(H2O)4][V2P2BO12]6·10H2O Junghwan Do, Ranko P. Bontchev, and Allan J. Jacobson pp 4305 - 4310; DOI: 10.1021/ic000435n |
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Ligand Influences on the Structures of Molybdenum Oxide Networks Pamela J. Hagrman, Robert L. LaDuca, Jr., H.-J. Koo, Randy Rarig, Jr., Robert C. Haushalter, Myung-Hwan Whangbo, and Jon Zubieta pp 4311 - 4317; DOI: 10.1021/ic000496l |
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Multiple-Path Dissociation Mechanism for Mono- and Dinuclear Tris(hydroxamato)iron(III) Complexes with Dihydroxamic Acid Ligands in Aqueous Solution Hakim Boukhalfa and Alvin L. Crumbliss pp 4318 - 4331; DOI: 10.1021/ic0001659 |
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Chemistry of Metal-Bound Anion Radicals. A Family of Mono- and Bis(azopyridine) Chelates of Bivalent Ruthenium Maya Shivakumar, Kausikisankar Pramanik, Indranil Bhattacharyya, and Animesh Chakravorty pp 4332 - 4338; DOI: 10.1021/ic000356b |
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Mixed Hydroxypyridinonate Ligands as Iron Chelators Seth M. Cohen, Brendon O'Sullivan, and Kenneth N. Raymond pp 4339 - 4346; DOI: 10.1021/ic000239g |
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Synthetic Models for the Zinc Sites in the Methionine Synthases Show-Jen Chiou, Julie Innocent, Charles G. Riordan, Kin-Chung Lam, Louise Liable-Sands, and Arnold L. Rheingold pp 4347 - 4353; DOI: 10.1021/ic000505q |
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Heterogeneous Electron-Transfer Rate Constants for M2(O2CR)40/+, Where M = Mo, W, Ru, or Rh and R = Alkyl or Aryl M. H. Chisholm, K. C. Glasgow, L. J. Klein, A. M. Macintosh, and D. G. Peters pp 4354 - 4357; DOI: 10.1021/ic9910108 |
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Synthesis, Structure, and H2O2-Dependent Catalytic Functions of Disulfide-Bridged Dicopper(I) and Related Thioether-Copper(I) and Thioether-Copper(II) Complexes Takehiro Ohta, Takashi Tachiyama, Kazunari Yoshizawa, Tokio Yamabe, Takeshi Uchida, and Teizo Kitagawa pp 4358 - 4369; DOI: 10.1021/ic000018a |
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Synthesis and Crystal Structure Determination of a New Pressure-Induced Iridium Ditelluride Phase, m-IrTe2, and Comparison of the Crystal Structures and Relative Stabilities of Various IrTe2 Polymorphs S. Jobic, R. Brec, C. Chateau, J. Haines, J.-M. Léger, H.-J. Koo, and M.-H. Whangbo pp 4370 - 4373; DOI: 10.1021/ic000351e |
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Synthesis and Characterization of a Novel Asymmetric Ferrocene Alkoxycarboxylate of Titanium, Ti4O2(OiPr)6{(5-O2CC5H4)Fe(5-C5H5)}6 Alec Bailey, Maoyu Shang, and Thomas P. Fehlner pp 4374 - 4376; DOI: 10.1021/ic000790d |
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Interaction of [Pt(en)(phen)]2+ and [Pt(en)(phi)]2+ with the Hexanucleotide d(GTCGAC)2: Evidence for Minor Groove Binding J. Grant Collins, Rhonda M. Rixon, and Janice R. Aldrich-Wright pp 4377 - 4379; DOI: 10.1021/ic991488b |
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Hydrothermal Evolution of the Thiourea-Cerium(III) Nitrate System: Formation of Cerium Hydroxycarbonate and Hydroxysulfate Zhaohui Han, Yitai Qian, Shuhong Yu, Kaibin Tang, Huaqiao Zhao, and Neng Guo pp 4380 - 4382; DOI: 10.1021/ic0001309 |
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New Antitumor-Active Azole-Bridged Dinuclear Platinum(II) Complexes: Synthesis, Characterization, Crystal Structures, and Cytotoxic Studies Seiji Komeda, Martin Lutz, Anthony L. Spek, Masahiko Chikuma, and Jan Reedijk pp 4382 - 4382; DOI: 10.1021/ic000955i |
Issue 20
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Synthesis and Structural Characterization of a New Class of Macrocycles Based on a Cyclodiphosphazane Skeleton Praveen Kommana and K. C. Kumara Swamy pp 4384 - 4385; DOI: 10.1021/ic000359o |
The Oxo-Gate Hypothesis and DMSO Reductase: Implications for a Psuedo- Bonding Interaction Involved in Enzymatic Electron TransferRebecca L. McNaughton, Matthew E. Helton, Nick D. Rubie, and Martin L. Kirk pp 4386 - 4387; DOI: 10.1021/ic000474z |
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Mixed-Valent Heptairon Chloride Cluster Supported by the Porphyrin-Linked Dicarboxylate Ligand PDK Xiao-Xiang Zhang and Stephen J. Lippard pp 4388 - 4389; DOI: 10.1021/ic000466i |
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Amide Alcoholysis in Mononuclear Zinc and Cadmium Complexes Ligated by Thioether Sulfur and Nitrogen Donors Lisa M. Berreau, Magdalena M. Makowska-Grzyska, and Atta M. Arif pp 4390 - 4391; DOI: 10.1021/ic000547e |
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Organometallic- and Organic-Based Magnets: New Chemistry and New Materials for the New Millennium Joel S. Miller pp 4392 - 4408; DOI: 10.1021/ic000540x |
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Aqueous Chemistry of Ammonium (Dipicolinato)oxovanadate(V): The First Organic Vanadium(V) Insulin-Mimetic Compound Debbie C. Crans, Luqin Yang, Tamas Jakusch, and Tamas Kiss pp 4409 - 4416; DOI: 10.1021/ic9908367 |
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Laser Photolysis of Chromium(III) Porphyrins with Axial Pyridines in Dichloromethane and Toluene Solutions. Novel Effects of a Hydrogen Bond in the Ligand Exchange Reaction Masahiko Inamo, Hideyuki Nakaba, Kiyohiko Nakajima, and Mikio Hoshino pp 4417 - 4423; DOI: 10.1021/ic0002059 |
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Bis(carbonyl)platinum(II) Derivatives: Molecular Structure of cis-Pt(CO)2(SO3F)2, Complete Vibrational Analysis of cis-Pt(CO)2Cl2, and Attempted Synthesis of cis-Pt(CO)2F2 Britta von Ahsen, Rudolf Wartchow, Helge Willner, Volker Jonas, and Friedhelm Aubke pp 4424 - 4432; DOI: 10.1021/ic000280j |
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Glutathione Interaction with SNS/S Mixed-Ligand Complexes of Oxorhenium(V): Kinetic Aspects and Characterization of the Products Berthold Nock, Theodosia Maina, Achilleas Tsortos, Maria Pelecanou, Catherine P. Raptopoulou, Minas Papadopoulos, Hans-Jürgen Pietzsch, Chariklia I. Stassinopoulou, Aris Terzis, Hartmut Spies, Georgios Nounesis, and Efstratios Chiotellis pp 4433 - 4441; DOI: 10.1021/ic000350m |
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Quantitative Photochemistry and Mechanisms for a Series of Rhodium Dicarbonyl Derivatives Nicholas Dunwoody, Shih-Sheng Sun, and Alistair J. Lees pp 4442 - 4451; DOI: 10.1021/ic000395n |
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Synthesis and Structural, Spectroscopic, and Magnetic Characterization of (NH4)[Fe3(3-OH)(H2L)3(HL)3] (H3L = Orotic Acid) Presenting Two Novel Metal-Binding Modes of the Orotate Ligand: The Case of a Spin-Frustrated System Catherine P. Raptopoulou, Vaslis Tangoulis, and Vassilis Psycharis pp 4452 - 4459; DOI: 10.1021/ic9914084 |
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Synthesis and Luminescence Properties of a Nonsymmetrical Ligand-Bridged ReI-ReI Chromophore W.-M. Xue, N. Goswami, David M. Eichhorn, Peter L. Orizondo, and D. Paul Rillema pp 4460 - 4467; DOI: 10.1021/ic000134d |
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Synthesis and Crystal Structures of Ru(II) Complexes Containing Chelating (Phosphinomethyl)oxazoline P,N-Type Ligands and Asymmetric Catalytic Transfer Hydrogenation of Acetophenone in Propan-2-ol Pierre Braunstein, Claudia Graiff, Frédéric Naud, Andreas Pfaltz, and Antonio Tiripicchio pp 4468 - 4475; DOI: 10.1021/ic0000754 |
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Yttrium and Neodymium Di- and Monohalide Complexes Based on Scorpionate (Poly(pyrazolyl)borate) Ligands David P. Long, A. Chandrasekaran, Roberta O. Day, Patricia A. Bianconi, and Arnold L. Rheingold pp 4476 - 4487; DOI: 10.1021/ic991179l |
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An Infinite Zigzag Chain and the First Linear Chain of Four Copper Atoms; Still No Copper-Copper Bonding Rodolphe Clérac, F. Albert Cotton, Lee M. Daniels, Jiande Gu, Carlos A. Murillo, and Hong-Cai Zhou pp 4488 - 4493; DOI: 10.1021/ic000208l |
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Syntheses and Structures of TcOF5 and the Tc2O2F9+ Cation and Formation of the TcOF4+ Cation in Solution Nicolas LeBlond, Hélène P. A. Mercier, David A. Dixon, and Gary J. Schrobilgen pp 4494 - 4509; DOI: 10.1021/ic991397e |
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Rhodium-Hydrogen-Tin Three-Center Bonds. NMR (1H, 31P, 103Rh, 119Sn) Study of [Rh(Cl)(H)(SnPh3)(PPh3)(py)] and Related Compounds Laurence Carlton pp 4510 - 4519; DOI: 10.1021/ic991054g |
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A Heterodinuclear CoIICuI Complex with Co(salen) in a Macrocyclic Framework. Oxygenation Studies in Comparison with Analogous CuIICuI and CoIIPbII Complexes Misato Shinoura, Satoru Kita, Masaaki Ohba, Hisashi  kawa, Hideki Furutachi, and Masatatsu Suzukipp 4520 - 4526; DOI: 10.1021/ic000305e |
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Tunable Energy Transfer from Dicyanoaurate(I) and Dicyanoargentate(I) Donor Ions to Terbium(III) Acceptor Ions in Pure Crystals Manal A. Rawashdeh-Omary, C. L. Larochelle, and Howard H. Patterson pp 4527 - 4534; DOI: 10.1021/ic990510y |
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Luminescence Spectroscopy and Emitting-State Properties of Pd(SCN)42- in Crystals Yanick Pelletier and Christian Reber pp 4535 - 4541; DOI: 10.1021/ic000133l |
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Determination of pKa Values of 4-Phosphonato-2,2':6',2' '-Terpyridine and Its Ruthenium(II)-Based Photosensitizer by NMR, Potentiometric, and Spectrophotometric Methods Md. K. Nazeeruddin, S. M. Zakeeruddin, R. Humphry-Baker, T. A. Kaden, and M. Grätzel pp 4542 - 4547; DOI: 10.1021/ic000215+ |
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Crystal Structures and Vibrational Spectroscopy of [NBu4][Cu(CN)X] (X = Br, I) and [NBu4][Cu3(CN)4]·CH3CN Graham A. Bowmaker, Hans Hartl, and Victoria Urban pp 4548 - 4554; DOI: 10.1021/ic000399s |
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Bis(benzonitrile)palladium(II) Dihalides: Structures and Cocrystallization of the Cubic Cluster Pd6Cl12 with (E)-Stilbene and with Bis(benzonitrile)palladium(II) Dichloride Marilyn M. Olmstead, Pin-pin Wei, Arwa S. Ginwalla, and Alan L. Balch pp 4555 - 4559; DOI: 10.1021/ic0000597 |
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Ferromagnetic Copper(II) Complex Containing Ferrocenecarboxylato Bridging Ligands Concepción López, Ramon Costa, Francesc Illas, Elies Molins, and Enric Espinosa pp 4560 - 4565; DOI: 10.1021/ic000521n |
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Synthesis and Proton-Coupled Electron-Transfer Reaction of Self-Assembled Monolayers of a Ruthenium(II) Complex Containing Tridentate 2,6-Bis(benzimidazol-2-yl)pyridine on a Gold Surface: Comparison of Acid/Base Chemistry with Bulk Solution Chemistry Masa-aki Haga, Hun-Gi Hong, Yoichi Shiozawa, Yasushi Kawata, Hideaki Monjushiro, Tsuyoshi Fukuo, and Ryuichi Arakawa pp 4566 - 4573; DOI: 10.1021/ic990934s |
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A Reliable Method of Preparation of Diiridium Paddlewheel Complexes: Structures of the First Compounds with Ir25+ Cores F. Albert Cotton, Chun Lin, and Carlos A. Murillo pp 4574 - 4578; DOI: 10.1021/ic000527c |
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Examination of Cobalt "Picket Fence" Porphyrin and Its Complex with 1-Methylimidazole as Catalysts for the Electroreduction of Dioxygen Beat Steiger and Fred C. Anson pp 4579 - 4585; DOI: 10.1021/ic000537d |
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One-Dimensional Coordination Polymers of Silver(I) with Aminomethylpyridines. Example of a Triple Helical Infinite Chain Sunkari Sailaja and M. V. Rajasekharan pp 4586 - 4590; DOI: 10.1021/ic000139a |
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Synthesis, Characterization, and Coordination Chemistry of a New Geometrically Hindered Trifunctional Ligand, 4,5-Bis(diphenylphosphino)-sym-octahydroacridine N,P,P'-Trioxide Xin-Min Gan, Sahrah Parveen, Wayne L. Smith, Eileen N. Duesler, and Robert T. Paine pp 4591 - 4598; DOI: 10.1021/ic000153n |
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Rare-Earth Gallium Antimonides La13Ga8Sb21 and RE12Ga4Sb23 (RE = La-Nd, Sm): Linking Sb Ribbons by Ga6-Rings or Ga2-Pairs Allison M. Mills and Arthur Mar pp 4599 - 4607; DOI: 10.1021/ic000519w |
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Kinetics and Mechanism of the Initial Phase of the Bromine-Chlorite Ion Reaction in Aqueous Solution Zsuzsanna Tóth and István Fábián pp 4608 - 4614; DOI: 10.1021/ic990329p |
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Synthesis and Structural Characterization of Metalated 1,8-Bis(silylamino)naphthalene Derivatives Christian H. Galka, Dominique J. M. Trösch, Ina Rüdenauer, Lutz H. Gade, Ian Scowen, and Mary McPartlin pp 4615 - 4620; DOI: 10.1021/ic000296+ |
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Crystal Structures of Nitronium Tetranitratogallate and Its Reversible Solid-State Phase Transition Mediated by Nonmerohedral Twinning Daniel G. Colombo, Victor G. Young, Jr., and Wayne L. Gladfelter pp 4621 - 4624; DOI: 10.1021/ic0002418 |
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Competitive Reaction of Axial Ligands during Biomimetic Oxygenations James P. Collman, Allis S. Chien, Todd A. Eberspacher, Min Zhong, and John I. Brauman pp 4625 - 4629; DOI: 10.1021/ic000071z |
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Comparison between Iron and Ruthenium Reagents Mediating GifIV-Type Oxygenation of Cyclohexane Scott B. Marr, Richard O. Carvel, David T. Richens, Hyun-Jin Lee, Michael Lane, and Pericles Stavropoulos pp 4630 - 4638; DOI: 10.1021/ic0001560 |
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Direct Evidence for O-H···NC Hydrogen Bonding in a Cyanide-Bridged Lanthanide-Transition-Metal Complex (H2O)6(DMF)6Ho2[Ni(CN)4]3: An Eight-Coordinated Holmium Center with a Bicapped (Square Face) Trigonal Prismatic Geometry Bin Du, Edward A. Meyers, and Sheldon G. Shore pp 4639 - 4645; DOI: 10.1021/ic000207t |
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Preparation of Diazoalkane Complexes of Osmium(II) Gabriele Albertin, Stefano Antoniutti, Emilio Bordignon, and Barbara Carrera pp 4646 - 4650; DOI: 10.1021/ic991335o |
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Effect of Zn Substitution on the Crystal Structure of (ND4)2[Cu[Zn](D2O)6](SO4)2 Charles Simmons, Michael A. Hitchman, Horst Stratemeier, and Tim Astley pp 4651 - 4653; DOI: 10.1021/ic000329l |
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Synthesis and Characterization of Rb2(MoO2)3(As2O7)2·2H2O: The First Rubidium Molybdenum(VI) Diarsenate with a Porous Structure Kuei-Fang Hsu and Sue-Lein Wang pp 4654 - 4657; DOI: 10.1021/ic000283w |
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Alcoholysis of 2,2'-Pyridil, (2-C5H4N)C(O)C(O)(2-C5H4N), in the Presence of Copper(II): A Family of Planar Pentanuclear Copper(II) Complexes Stabilized by [(2-C5H4N)C(O)(OR)C(O)(OR)(2-C5H4N)]2- and Carboxylate Ligands Giannis S. Papaefstathiou, Catherine P. Raptopoulou, Alexandros Tsohos, Aris Terzis, Evangelos G. Bakalbassis, and Spyros P. Perlepes pp 4658 - 4662; DOI: 10.1021/ic991169k |
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Synthesis of a Flexible Ligand for Assembling Two Metal Ions in Close Proximity. Crystal Structures of Binuclear Nickel and Copper Complexes Paolo Dapporto, Mauro Formica, Vieri Fusi, Mauro Micheloni, Paola Paoli, Roberto Pontellini, and Patrizia Rossi pp 4663 - 4665; DOI: 10.1021/ic0000799 |
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An Octanuclear Copper(II) Complex Containing the gem-Diol Anionic Form of Di-2-pyridyl Ketone (dpd-2H) and 2-Hydroxypyridine: Synthesis, Crystal Structure, and Properties of [Cu8(dpd-2H)4(2-O2CMe)4{2-(OH)C5H4N}4]- (ClO4)4·4H2O Ming-Liang Tong, Hung Kay Lee, Ye-Xiang Tong, Xiao-Ming Chen, and Thomas C. W. Mak pp 4666 - 4669; DOI: 10.1021/ic000114b |
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Difluorodioxirane, a Possible Intermediate in the Reaction of Bis(fluoroxy)difluoromethane with Cesium Trifluoromethoxide Qun Huang and Darry D. DesMarteau pp 4670 - 4672; DOI: 10.1021/ic0003224 |
Issue 21
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Structural, Electronic, and Magnetic Properties of {Fe[HC(3,5-Me2pz)3]2}(BF4)2 (pz = Pyrazolyl): Observation of Unusual Spin-Crossover Behavior Daniel L. Reger, Christine A. Little, Arnold L. Rheingold, Matthew Lam, Tom Concolino, Amitabh Mohan, and Gary J. Long pp 4674 - 4675; DOI: 10.1021/ic000721z |
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An Isolable, Oxygen-Coordinated Silver(I) Complex of Dimethyl Diazomalonate: Synthesis and Characterization of [HB(3,5-(CF3)2Pz)3]Ag[OC(OCH3)]2CN2 (Where Pz = Pyrazolyl) H. V. Rasika Dias and Sharon A. Polach pp 4676 - 4677; DOI: 10.1021/ic0002521 |
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Calixarenes as Scaffolds: Introduction of Tridentate Rare Earth Metal Binding Units into Calix[4]arene Pascal Froidevaux, Jack M. Harrowfield, and Alexander N. Sobolev pp 4678 - 4687; DOI: 10.1021/ic000353z |
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Synthesis, Structural Characterization, and Monte Carlo Simulation of the Magnetic Properties of Two New Alternating MnII Azide 2-D Honeycombs. Study of the Ferromagnetic Ordered Phase below 20 K Albert Escuer, Joan Cano, Mohamed A. S. Goher, Yves Journaux, Francesc Lloret, Franz A. Mautner, and Ramon Vicente pp 4688 - 4695; DOI: 10.1021/ic000335h |
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Reactions of M(CO)5X (M = Mn, Re; X = Cl, Br) with {Ph2PCH2}3CCH3 (P3) and {Ph2P(CH2)2}3P (P3P'): Synthetic, Spectroscopic, Electrochemical, and Electrospray Mass Spectrometric Studies Alan M. Bond, Ray Colton, Adrian van den Bergen, and Jacky N. Walter pp 4696 - 4703; DOI: 10.1021/ic0000294 |
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Main-Group-Element Calix[4]arenes: Variable Coordination and Conformational Isomerism at Phosphorus and Silicon Maomian Fan, Igor V. Shevchenko, R. Harmony Voorhies, Scott F. Eckert, Hongming Zhang, and Michael Lattman pp 4704 - 4712; DOI: 10.1021/ic000349n |
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Yttrium Calix[4]arene Complexes. Silylation and Silylamine Elimination Reactions on Model Oxo Surfaces Reiner Anwander, Jörg Eppinger, Iris Nagl, Wolfgang Scherer, Maxim Tafipolsky, and Peter Sirsch pp 4713 - 4720; DOI: 10.1021/ic000147r |
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Polyhedral Members of the Mg2nP2m Family Derived from Dimeric Magnesium Trialkylsilylphosphandiide Matthias Westerhausen, Mathias Krofta, Peter Mayer, Marcus Warchhold, and Heinrich Nöth pp 4721 - 4724; DOI: 10.1021/ic000038c |
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Matrix-Isolated Al2OF62- Ion in Molten and Solid LiF/NaF/KF Murray H. Brooker, Rolf W. Berg, Jens H. von Barner, and Niels J. Bjerrum pp 4725 - 4730; DOI: 10.1021/ic000489x |
Crucial Role of Cu-S Bonding for Structural Changes Accompanying the Reversible CuI/CuII Transition in an Unrestrained Cu(N S)2 Coordination Arrangement. An Experimental and DFT StudyMarkus Albrecht, Klaus Hübler, Stanislav Zalis, and Wolfgang Kaim pp 4731 - 4734; DOI: 10.1021/ic000021u |
Organic-Inorganic Hybrids Based on Polyoxometalates. 6.1 Syntheses, Structure, and Reactivity of the Bis(tert-butylsilyl)decatungstophosphate [( -PW10O36)(t-BuSiOH)2]3-Agnès Mazeaud, Yves Dromzee, and René Thouvenot pp 4735 - 4740; DOI: 10.1021/ic0004784 |
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Synthesis and Structural Characterization of Sm(II) and Yb(II) Complexes Containing Sterically Demanding, Chelating Secondary Phosphide Ligands Keith Izod, Paul O'Shaughnessy, Joanne M. Sheffield, William Clegg, and Stephen T. Liddle pp 4741 - 4748; DOI: 10.1021/ic0002871 |
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Role of Cyclometalation in Controlling the Rates of Ligand Substitution at Platinum(II) Complexes Raffaello Romeo, Maria Rosaria Plutino, Luigi Monsù Scolaro, Sergio Stoccoro, and Giovanni Minghetti pp 4749 - 4755; DOI: 10.1021/ic0004479 |
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Covalent Metal-Organic Networks: Pyridines Induce 2-Dimensional Oligomerization of (-OC6H4O)2Mpy2 (M = Ti, V, Zr) Joseph M. Tanski, Thomas P. Vaid, Emil B. Lobkovsky, and Peter T. Wolczanski pp 4756 - 4765; DOI: 10.1021/ic0003473 |
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Crystal Structure of (Difluoro)methoxyoxo Iodine(V) IF2(O)OCH3 Rolf Minkwitz, Michael Berkei, Marc Studentkowski, and Ralf Ludwig pp 4766 - 4768; DOI: 10.1021/ic000525s |
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Kinetic Origin of the Chelate Effect. Base Hydrolysis, H-Exchange Reactivity, and Structures of syn,anti-[Co(cyclen)(NH3)2]3+ and syn,anti-[Co(cyclen)(diamine)]3+ Ions (diamine = H2N(CH2)2NH2, H2N(CH2)3NH2) Andrea J. Clarkson, David A. Buckingham, Andrew J. Rogers, Allan G. Blackman, and Charles R. Clark pp 4769 - 4775; DOI: 10.1021/ic000325g |
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Structure and Bonding of Transition Metal-Boryl Compounds. Theoretical Study of [(PH3)2(CO)ClOs-BR2] and [(PH3)2(CO)2ClOs-BR2] (BR2 = BH2, BF2, B(OH)2, B(OCH=CHO), Bcat) Kalathingal T. Giju, F. Matthias Bickelhaupt, and Gernot Frenking pp 4776 - 4785; DOI: 10.1021/ic9913637 |
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Experimental and Theoretical Studies of the d8-d10 Interaction between Pd(II) and Au(I): Bis(chloro[(phenylthiomethyl)diphenylphosphine]gold(I))-dichloropalladium(II) and Related Systems Olga Crespo, Antonio Laguna, Eduardo J. Fernández, José M. López-de-Luzuriaga, Peter G. Jones, Markus Teichert, Miguel Monge, Pekka Pyykkö, Nino Runeberg, Martin Schütz, and Hans-Joachim Werner pp 4786 - 4792; DOI: 10.1021/ic000420p |
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Structural Characterization and Formation Mechanism of Sitting-Atop (SAT) Complexes of 5,10,15,20-Tetraphenylporphyrin with Divalent Metal Ions. Structure of the Cu(II)-SAT Complex As Determined by Fluorescent Extended X-ray Absorption Fine Structure Yasuhiro Inada, Yuko Nakano, Masahiko Inamo, Masaharu Nomura, and Shigenobu Funahashi pp 4793 - 4801; DOI: 10.1021/ic000479w |
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Ion-Pair Interactions of Lanthanide(III) Complexes in Aqueous Solutions Daniele M. Corsi, Herman van Bekkum, and Joop A. Peters pp 4802 - 4808; DOI: 10.1021/ic000278s |
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Kinetics and Mechanism of Oxygen Transfer to Methyloxo(dithiolato)rhenium(V) Complexes Gábor Lente and James H. Espenson pp 4809 - 4814; DOI: 10.1021/ic000148j |
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Preparation and Properties of Cyclopentadienyl- and Pentamethylcyclopentadienyl-Titanium(IV) Complexes with the C8H4S8 Ligand, Electrical Conductivities of Their Oxidized Species, and X-ray Crystal Structure of Ti(C5Me5)2(C8H4S8) Koyu Saito, Motohiro Nakano, Hatsue Tamura, and Gen-etsu Matsubayashi pp 4815 - 4820; DOI: 10.1021/ic0000348 |
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Unprecedented Stabilization of Cobalt(II) in a Tetrahedral S2O2 Environment: The Use of a Redox-Noninnocent Ligand Núria Duran, William Clegg, Lourdes Cucurull-Sánchez, Robert A. Coxall, Hermas R. Jiménez, José-María Moratal, Francesc Lloret, and Pilar González-Duarte pp 4821 - 4832; DOI: 10.1021/ic000223q |
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((Fluoroformyl)imido)(trifluoromethyl)sulfur Fluoride, FC(O)N=S(F)CF3: Unexpected Conformational Properties Frank Trautner, Edgardo H. Cutin, Carlos O. Della Vedova, Rüdiger Mews, and Heinz Oberhammer pp 4833 - 4837; DOI: 10.1021/ic000253t |
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Reactions of (Carbonylimido)sulfur(IV) Derivatives with TAS-Fluoride, (Me2N)3S+Me3SiF2- Enno Lork, Detlef Viets, Rüdiger Mews, and Heinz Oberhammer pp 4838 - 4842; DOI: 10.1021/ic0002824 |
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Formation of Mono-, Bi-, Tri-, and Tetranuclear Ag(I) Complexes of C3-Symmetric Tripodal Benzimidazole Ligands Cheng-Yong Su, Bei-Sheng Kang, Chen-Xia Du, Qing-Chuan Yang, and Thomas C. W. Mak pp 4843 - 4849; DOI: 10.1021/ic991140g |
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Structure and Photochemistry of Dicyanocobalt(III) Tetraphenylporphyrin. Photochromic Reaction Caused by Photodissociation of Axial Ligand Mikio Hoshino, Hirotaka Sonoki, Yoshio Miyazaki, Yasuhiro Iimura, and Kiyoko Yamamoto pp 4850 - 4857; DOI: 10.1021/ic000408x |
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Coordination of Lanthanide Triflates and Perchlorates with N,N,N',N'-Tetramethylsuccinamide Brian M. Rapko, Bruce K. McNamara, Robin D. Rogers, Grant A. Broker, Gregg J. Lumetta, and Benjamin P. Hay pp 4858 - 4867; DOI: 10.1021/ic000244k |
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Key Factors Determining the Course of Methyl Iodide Oxidative Addition to Diamidonaphthalene-Bridged Diiridium(I) and Dirhodium(I) Complexes M. Victoria Jiménez, Eduardo Sola, M. Angeles Egea, Aline Huet, Ana C. Francisco, Fernando J. Lahoz, and Luis A. Oro pp 4868 - 4878; DOI: 10.1021/ic000497d |
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Columnar Mesomorphism of Bi- and Trinuclear Ni(II), Cu(II), and VO(II) cis-Enamonoketone Complexes with Low Symmetry Jadwiga Szyd owska, Adam Krówczyski, Ewa Górecka, and Damian Pociechapp 4879 - 4885; DOI: 10.1021/ic0000808 |
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Preparation and Characterization of Oxorhenium(V) Complexes with 2,2'-Biimidazole: The Strong Affinity of Coordinated Biimidazole for Chloride Ions via N-H···Cl- Hydrogen Bonding Sébastien Fortin and André L. Beauchamp pp 4886 - 4893; DOI: 10.1021/ic000328t |
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Copper(II) Benzoate Nitroxide Dimers and Chains: Structure and Magnetic Studies Rico E. Del Sesto, Atta M. Arif, and Joel S. Miller pp 4894 - 4902; DOI: 10.1021/ic0007106 |
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Oxo Complexes of Osmium(IV) Formed via Dioxygen Activation. X-ray Structures of [OsX(dcpe)2]PF6 (X = Cl, Br), [OsCl(2-O2)(dcpe)2]BPh4, and [OsCl(O)(dcpe)2]BPh4 (dcpe = 1,2-Bis(dicyclohexylphosphino)ethane) Peter Barthazy, Michael Wörle, Heinz Rüegger, and Antonio Mezzetti pp 4903 - 4912; DOI: 10.1021/ic0002420 |
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Copper(II) Complexes of Pyridyl-Appended Diazacycloalkanes: Synthesis, Characterization, and Application to Catalytic Olefin Aziridination Jason A. Halfen, Joseph M. Uhan, Derek C. Fox, Mark P. Mehn, and Lawrence Que, Jr. pp 4913 - 4920; DOI: 10.1021/ic000664+ |
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Selective Tin-Carbon Bond Cleavage Reactions of Trimethylstannylzirconocene Dichloride with Electrophiles Xu Cheng, Carla Slebodnick, Paul A. Deck, Damon R. Billodeaux, and Frank R. Fronczek pp 4921 - 4926; DOI: 10.1021/ic991461s |
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New Inorganic/Organic Coordination Polymers Generated from Bidentate Schiff-Base Ligands Yu-Bin Dong, Mark D. Smith, and Hans-Conrad zur Loye pp 4927 - 4935; DOI: 10.1021/ic0006504 |
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Ternary Early-Transition-Metal Palladium Pnictides Zr3Pd4P3, Hf3Pd4P3, HfPdSb, and Nb5Pd4P4 Meitian Wang, Robert McDonald, and Arthur Mar pp 4936 - 4941; DOI: 10.1021/ic0006551 |
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Recognition of DNA Base Pair Mismatches by a Cyclometalated Rh(III) Intercalator Jennifer L. Kisko and Jacqueline K. Barton pp 4942 - 4949; DOI: 10.1021/ic000549z |
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Copper(II) and Nickel(II) Complexes of Binucleating Macrocyclic Bis(disulfide)tetramine Ligands Stephen Fox, Robert T. Stibrany, Joseph A. Potenza, Spencer Knapp, and Harvey J. Schugar pp 4950 - 4961; DOI: 10.1021/ic000380p |
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Allosteric Manipulation of Photoexcited State Relaxation in (bpy)2RuII(binicotinic acid) Marc W. Perkovic pp 4962 - 4968; DOI: 10.1021/ic000288t |
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Kinetics of Metal-Mediated One-Electron Oxidation of Guanine in Polymeric DNA and in Oligonucleotides Containing Trinucleotide Repeat Sequences Ivana V. Yang and H. Holden Thorp pp 4969 - 4976; DOI: 10.1021/ic000607g |
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Reversible and Site-Specific Reduction of the Ligand Sides in a Molecular Rectangle with up to Eight Electrons Heiko Hartmann, Sascha Berger, Rainer Winter, Jan Fiedler, and Wolfgang Kaim pp 4977 - 4980; DOI: 10.1021/ic0001006 |
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Dimeric Bridged and Chelated Alkali Metal (Li and Na) Bis(iminophosphorano)methanide Complexes with Contrasting Structures Ruppa P. Kamalesh Babu, Kasani Aparna, Robert McDonald, and Ronald G. Cavell pp 4981 - 4984; DOI: 10.1021/ic991364z |
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Synthesis and Structure of (H3NC2H4NH3)2Co7(PO4)6: A Novel Open Framework Cobalt Phosphate Ray-Kuang Chiang pp 4985 - 4988; DOI: 10.1021/ic991233y |
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ESEEM and Mims ENDOR Spectroscopies of cis,trans-(L-N2S2)MoVO(SCH2Ph): Detection of the Two Benzylthiolate Protons Andrei V. Astashkin, Michele Mader Cosper, Arnold M. Raitsimring, and John H. Enemark pp 4989 - 4992; DOI: 10.1021/ic000405k |
Issue 22
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Self-Assembly of a Noncovalently Bonded Dicopper(II) Complex in the Solid State and in Solution Paul V. Bernhardt and Philip C. Sharpe pp 4994 - 4995; DOI: 10.1021/ic000587i |
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Systematic Syntheses and Structural Characterizations of Two Isomeric Phosphadicarbaboranes: 6-R-arachno-6,8,9-PC2B7H11 and 6-R-arachno-6,5,7-PC2B7H11. The First 10-Vertex Phosphadicarbaboranes Daewon Hong, Scott E. Rathmill, Daniel E. Kadlecek, and Larry G. Sneddon pp 4996 - 4997; DOI: 10.1021/ic000728g |
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A Co(III) Complex in a Mixed Sulfur/Nitrogen Ligand Environment: Modeling the Substrate- and Product-Bound Forms of the Metalloenzyme Thiocyanate Hydrolase Jason Shearer, Irene Y. Kung, Scott Lovell, and Julie A. Kovacs pp 4998 - 4999; DOI: 10.1021/ic0005689 |
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A Cyanide-Bridged Chain of Mo6Se8 Clusters: A Product of Cyanide-Melt Cluster Synthesis Carmela Magliocchi, Xiaobing Xie, and Timothy Hughbanks pp 5000 - 5001; DOI: 10.1021/ic000833q |
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The Cubane-Type Mo2Ir2S4 Cluster Containing an Organohydrazido(2-) Ligand on the Mo Site Tadao Masumori, Hidetake Seino, Yasushi Mizobe, and Masanobu Hidai pp 5002 - 5003; DOI: 10.1021/ic991441q |
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Spectroscopic, Kinetic, and Mechanistic Study of a New Mode of Coordination of Indole Derivatives to Platinum(II) and Palladium(II) Ions in Complexes Natalia V. Kaminskaia, G. Matthias Ullmann, D. Bruce Fulton, and Nenad M. Kosti pp 5004 - 5013; DOI: 10.1021/ic000254l |
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Influence of H2S and Thiols on the Binding of Alkenes and Alkynes to ReS4-: The Spectator Sulfido Effect Joel A. Dopke, Scott R. Wilson, and Thomas B. Rauchfuss pp 5014 - 5021; DOI: 10.1021/ic0001661 |
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Topological Ferrimagnetic Behavior of Two New [Mn(L)2(N3)2]n Chains with the New AF/AF/F Alternating Sequence (L = 3-Methylpyridine or 3,4-Dimethylpyridine) Morsy A. M. Abu-Youssef, Marc Drillon, Albert Escuer, Mohamed A. S. Goher, Franz A. Mautner, and Ramon Vicente pp 5022 - 5027; DOI: 10.1021/ic000516j |
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Redox Reactivity and Reorganization Energy of Zinc Cytochrome c Cation Radical Milan M. Crnogorac and Nenad M. Kosti pp 5028 - 5035; DOI: 10.1021/ic9910514 |
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Potentiometric and Multinuclear NMR Study of the Binary and Ternary Uranium(VI)-L-Fluoride Systems, Where L Is -Hydroxycarboxylate or Glycine Zoltán Szabó and Ingmar Grenthe pp 5036 - 5043; DOI: 10.1021/ic000400n |
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Probing the Electronic Structures of Coordination Compounds by Transient Spectral Hole-Burning. Applications to Specifically Deuterated [Ru(bpy)3]2+ Complexes Hans Riesen, Lynne Wallace, and Elmars Krausz pp 5044 - 5052; DOI: 10.1021/ic0005386 |
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Cobalt-Complexed Conjugated Diyne Salts: A Family of Rigid Masked Dielectrophiles. Syntheses, Structures, and Double Nucleophilic Substitutions H. Amouri, C. Da Silva, B. Malézieux, R. Andrés, J. Vaissermann, and M. Gruselle pp 5053 - 5058; DOI: 10.1021/ic991433+ |
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Unusual Electronic Effects of Electron-Withdrawing Sulfonamide Groups in Optically and Magnetically Active Self-Assembled Noncovalent Heterodimetallic d-f Podates Carine Edder, Claude Piguet, Gérald Bernardinelli, Jiri Mareda, Christian G. Bochet, Jean-Claude G. Bünzli, and Gérard Hopfgartner pp 5059 - 5073; DOI: 10.1021/ic000687o |
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Tripodal Peptide Hydroxamates as Siderophore Models. Iron(III) Binding with Ligands Containing H-(Alanyl)n--(N-hydroxy)alanyl Strands (n = 1-3) Anchored by Nitrilotriacetic Acid Yukihiro Hara, Langtao Shen, Akira Tsubouchi, Masayasu Akiyama, and Kimiko Umemoto pp 5074 - 5082; DOI: 10.1021/ic0001210 |
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Formation and Characterization of Water-Soluble Hydrido-Ruthenium(II) Complexes of 1,3,5-Triaza-7-phosphaadamantane and Their Catalytic Activity in Hydrogenation of CO2 and HCO3- in Aqueous Solution Gábor Laurenczy, Ferenc Joó, and Levente Nádasdi pp 5083 - 5088; DOI: 10.1021/ic000200b |
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Thiocyanogen as an Intermediate in the Oxidation of Thiocyanate by Hydrogen Peroxide in Acidic Aqueous Solution James N. Figlar and David M. Stanbury pp 5089 - 5094; DOI: 10.1021/ic000561r |
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Crystal Structure and Magnetic Properties of an Octacyanometalate-Based Three-Dimensional Tungstate(V)-Manganese(II) Bimetallic Assembly Zhuang Jin Zhong, Hidetake Seino, Yasushi Mizobe, Masanobu Hidai, Michel Verdaguer, Shin-ichi Ohkoshi, and Kazuhito Hashimoto pp 5095 - 5101; DOI: 10.1021/ic0005994 |
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Structural and Electronic Characterization of Nitrosyl(Octaethylporphinato)iron(III) Perchlorate Derivatives Mary K. Ellison, Charles E. Schulz, and W. Robert Scheidt pp 5102 - 5110; DOI: 10.1021/ic000789e |
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Kinetic and Mechanistic Study with Optically Active, Four-Coordinate Nickel(II) Complexes: Stereoselectivity in Ligand Substitution Alexander Haus, Michael Raidt, Thomas A. Link, and Horst Elias pp 5111 - 5117; DOI: 10.1021/ic000339m |
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Synthesis and Characterization of a Polycarbon Organometallic Cluster, [PPN]2[Fe6(CO)18C4] D. M. Norton and D. F. Shriver pp 5118 - 5120; DOI: 10.1021/ic991256c |
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Coordination Polymers of Copper(I) Halides Peter M. Graham, Robert D. Pike, Michal Sabat, Rosa D. Bailey, and William T. Pennington pp 5121 - 5132; DOI: 10.1021/ic0005341 |
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Structural Diversity in Solvated Lithium Aryloxides. Syntheses, Characterization, and Structures of [Li(OAr)(THF)x]n and [Li(OAr)(py)x]2 Complexes Where OAr = OC6H5, OC6H4(2-Me), OC6H3(2,6-(Me))2, OC6H4(2-Pri), OC6H3(2,6-(Pri))2, OC6H4(2-But), OC6H3(2,6-(But))2 Timothy J. Boyle, Dawn M. Pedrotty, Todd M. Alam, Sara C. Vick, and Mark A. Rodriguez pp 5133 - 5146; DOI: 10.1021/ic000432a |
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The First Structurally Alternating Copper(II) Chain with Alternate Single End-on and End-to-End Azido Bridging: A Synthesis, Crystal Structure, and Low-Temperature Magnetic Study Partha Sarathi Mukherjee, Tapas Kumar Maji, Golam Mostafa, Talal Mallah, and Nirmalendu Ray Chaudhuri pp 5147 - 5150; DOI: 10.1021/ic000507a |
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Synthesis and Characterization of Monomeric Oxo Dichloro 1,3-Dialkyl p-tert-Butylcalix[4]arene Complexes of Molybdenum(VI,V) and Tungsten(VI,V) Andrew J. Millar, Jonathan M. White, Christian J. Doonan, and Charles G. Young pp 5151 - 5155; DOI: 10.1021/ic000431i |
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X-ray Evidence of CN Bridging in Bimetallic Complexes Based on [M(CN)8]4- (M = Mo, W). The Crystal Structure of {[Mn(bpy)2]2(-NC)2[Mo(CN)6]2(-CN)2[Mn(bpy)2]2}·8H2O Barbara Sieklucka, Janusz Szklarzewicz, Terence J. Kemp, and William Errington pp 5156 - 5158; DOI: 10.1021/ic0000404 |
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(THF)3LiCl as a Ligand for Low-Coordinate Fe(II): Crystal Structure of [(Me3Si)2N]2Fe(-Cl)Li(THF)3 Ulrich Siemeling, Udo Vorfeld, Beate Neumann, and Hans-Georg Stammler pp 5159 - 5160; DOI: 10.1021/ic000086x |
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Synthesis of a Clathrochelate Complex with an Appended Pyridine and Its Coordination to a Cobaloxime Complex Chaiwat Engtrakul, William J. Shoemaker, Joseph J. Grzybowski, Ilia Guzei, and Arnold Rheingold pp 5161 - 5163; DOI: 10.1021/ic0002465 |
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Group 6 Metallocalixarenes Bearing "Hydrazido(2-)" Groups Carl Redshaw and Mark R. J. Elsegood pp 5164 - 5168; DOI: 10.1021/ic000098i |
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Unexpected Synthesis of an 8-Shaped Macrocycle Instead of an Interlocking-Ring System Nicolas Belfrekh, Christiane Dietrich-Buchecker, and Jean-Pierre Sauvage pp 5169 - 5172; DOI: 10.1021/ic991502k |
Issue 23
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Hydrothermal Syntheses of Layered Uranium Oxyfluorides: Illustrations of Dimensional Reduction Catherine E. Talley, Amanda C. Bean, and Thomas E. Albrecht-Schmitt pp 5174 - 5175; DOI: 10.1021/ic000668e |
[MoV12O30(2-OH)10H2{NiII(H2O)3}4], a Highly Symmetrical  -Keggin Unit Capped with Four NiII Centers: Synthesis and MagnetismAchim Müller, Christian Beugholt, Paul Kögerler, Hartmut Bögge, Sergey Bud'ko, and Marshall Luban pp 5176 - 5177; DOI: 10.1021/ic0005285 |
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Exploratory Synthesis in the Solid State. Endless Wonders John D. Corbett pp 5178 - 5191; DOI: 10.1021/ic0007862 |
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Photobehavior of (-Diimine)dimesitylplatinum(II) Complexes Keenan E. Dungey, Brian D. Thompson, Noel A. P. Kane-Maguire, and Laura L. Wright pp 5192 - 5196; DOI: 10.1021/ic000268r |
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Oxorhenium Phosphinophenolato Complexes with Model Peptide Fragments: Synthesis, Characterization, and Stability Considerations Berthold Nock, Theodosia Maina, Francesco Tisato, Catherine P. Raptopoulou, Aris Terzis, and Efstratios Chiotellis pp 5197 - 5202; DOI: 10.1021/ic000154f |
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Discrete Dinuclear Cyano-Bridged Complexes Paul V. Bernhardt, Brendan P. Macpherson, and Manuel Martinez pp 5203 - 5208; DOI: 10.1021/ic000379q |
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New Metallodendrimers Containing an Octakis(diphenylphosphino)-Functionalized Silsesquioxane Core and Ruthenium(II)-Based Chromophores Hunter J. Murfee, Travis P. S. Thoms, John Greaves, and Bo Hong pp 5209 - 5217; DOI: 10.1021/ic000490w |
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Solid-State Coordination Chemistry: Influences of {M(terpyridyl)} (M = Fe(III), Cu(II), Ni(II)} Subunits on Molybdenum Oxide Structures Pamela J. Hagrman and Jon Zubieta pp 5218 - 5224; DOI: 10.1021/ic0002162 |
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Synthesis and Characterization of Several Dicopper(I) Complexes and a Spin-Delocalized Dicopper(I,II) Mixed-Valence Complex Using a 1,8-Naphthyridine-Based Dinucleating Ligand Chuan He and Stephen J. Lippard pp 5225 - 5231; DOI: 10.1021/ic0005339 |
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Theoretical Study of the Chemisorption of CO on Al2O3(0001) Maurizio Casarin, Chiara Maccato, and Andrea Vittadini pp 5232 - 5237; DOI: 10.1021/ic000506i |
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X-ray Spectroscopy of Enzyme Active Site Analogues and Related Molecules: Bis(dithiolene)molybdenum(IV) and -tungsten(IV,VI) Complexes with Variant Terminal Ligands Kristin B. Musgrave, Booyong S. Lim, Kie-Moon Sung, R. H. Holm, Britt Hedman, and Keith O. Hodgson pp 5238 - 5247; DOI: 10.1021/ic000601r |
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Blue-Luminescent/Electroluminescent Zn(II) Compounds of 7-Azaindole and N-(2-Pyridyl)-7-azaindole: Zn(7-azaindole)2(CH3COO)2, Zn(NPA)(CH3COO)2, and Zn(NPA)((S)-(+)-CH3CH2CH(CH3)COO)2 (NPA = N-(2-Pyridyl)-7-azaindole) Qingguo Wu, James A. Lavigne, Ye Tao, Marie D'Iorio, and Suning Wang pp 5248 - 5254; DOI: 10.1021/ic000465q |
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Ruthenium(II) Ammine and Hydrazine Complexes with [N(Ph2PQ)2]- (Q = S, Se) Ligands Qian-Feng Zhang, Hegen Zheng, Wai-Yeung Wong, Wing-Tak Wong, and Wa-Hung Leung pp 5255 - 5264; DOI: 10.1021/ic000291c |
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Synthesis and Structures of Polymeric Mn, Co, Cu, and Zn Complexes of 3-Diphenylamino-4-hydroxycyclobut-3-ene-1,2-dione (Diphenylaminosquarate) and of the Salt [Ni(H2O)6][(C6H5)2NC4O3]2·2H2O Avril R. Williams, Bert D. Alleyne, Lincoln A. Hall, Andrew J. P. White, David J. Williams, and Laurence K. Thompson pp 5265 - 5270; DOI: 10.1021/ic000390q |
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Kinetic and Computational Study of Dissociative Substitution and Phosphine Exchange at Tetrahedrally Distorted cis-Pt(SiMePh2)2(PMe2Ph)2 Ola F. Wendt, Robert J. Deeth, and Lars I. Elding pp 5271 - 5276; DOI: 10.1021/ic000492g |
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Basicity of Uranyl Oxo Ligands upon Coordination of Alkoxides Marianne P. Wilkerson, Carol J. Burns, Harry J. Dewey, Jerod M. Martin, David E. Morris, Robert T. Paine, and Brian L. Scott pp 5277 - 5285; DOI: 10.1021/ic000142u |
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Extended Rodlike Polyaromatic Receptors with Bent Tridentate Units Complexed to Lanthanide Metal Ions Homayoun Nozary, Claude Piguet, Jean-Pierre Rivera, Paul Tissot, Gérald Bernardinelli, Nathalie Vulliermet, Jacques Weber, and Jean-Claude G. Bünzli pp 5286 - 5298; DOI: 10.1021/ic000338u |
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Structural, Dynamic, and Theoretical Studies of [AunPt2(PPh3)4(-S)2-n(3-S)nL][PF6]n [n = 1, L = PPh3; n = 2, L = Ph2PCH2PPh2, (C5H4PPh2)2Fe] Zhaohui Li, Zhi-Heng Loh, K. F. Mok, and T. S. Andy Hor pp 5299 - 5305; DOI: 10.1021/ic991416k |
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Mononuclear (Nitrido)iron(V) and (Oxo)iron(IV) Complexes via Photolysis of [(cyclam-acetato)FeIII(N3)]+ and Ozonolysis of [(cyclam-acetato)FeIII(O3SCF3)]+ in Water/Acetone Mixtures Craig A. Grapperhaus, Bernd Mienert, Eckhard Bill, Thomas Weyhermüller, and Karl Wieghardt pp 5306 - 5317; DOI: 10.1021/ic0005238 |
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Sterically Demanding Diporphyrin Ligands and Rhodium(II) Porphyrin Bimetalloradical Complexes Xiao-Xiang Zhang and Bradford B. Wayland pp 5318 - 5325; DOI: 10.1021/ic0006302 |
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Monomeric and Dimeric Copper(II) Complexes of a Novel Tripodal Peptide Ligand: Structures Stabilized via Hydrogen Bonding or Ligand Sharing John M. Rowland, Marilyn M. Olmstead, and Pradip K. Mascharak pp 5326 - 5332; DOI: 10.1021/ic000471m |
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Reactions and Reactivity of Co-bpdc Coordination Polymers (bpdc = 4,4'-biphenyldicarboxylate) Long Pan, Nancy Ching, Xiaoying Huang, and Jing Li pp 5333 - 5340; DOI: 10.1021/ic0004939 |
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Selenium Imides: 77Se NMR Investigations of the SeCl2-tBuNH2 Reaction and X-ray Structures of Se3(NtBu)3, tBuNSe(-NtBu)2SO2, and tBuNSe(-NtBu)2SeO Tiina Maaninen, Tristram Chivers, Risto Laitinen, Gabriele Schatte, and Maija Nissinen pp 5341 - 5347; DOI: 10.1021/ic000598b |
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Synthesis and Characterization of Three Tetranuclear Clusters Containing a [Mo3OS3Sn]6+ Cubane-like Core Rong-Min Yu, Shao-Fang Lu, Jian-Quan Huang, Xiao-Ying Huang, Qiang-Jin Wu, and Da-Xu Wu pp 5348 - 5353; DOI: 10.1021/ic990750d |
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Structural Origin of Two Paramagnetic Species in Six-Coordinated Nitrosoiron(II) Porphyrins Revealed by Density Functional Theory Analysis of the g Tensors S. Patchkovskii and T. Ziegler pp 5354 - 5364; DOI: 10.1021/ic0005691 |
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Photophysics and Crystal Structure of a Europium(III) Cryptate Incorporating 3,3'-Biisoquinoline-2,2'-dioxide P. Gawryszewska, L. Jerzykiewicz, M. Pietraszkiewicz, J. Legendziewicz, and J. P. Riehl pp 5365 - 5372; DOI: 10.1021/ic0004683 |
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Role of the Transition Metal in Metallaborane Chemistry. Reactivity of (Cp*ReH2)2B4H4 with BH3·thf, CO, and Co2(CO)8 Sundargopal Ghosh, Xinjian Lei, Maoyu Shang, and Thomas P. Fehlner pp 5373 - 5382; DOI: 10.1021/ic0006091 |
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Heteroatomic Deltahedral Clusters of Main-Group Elements: Synthesis and Structure of the Zintl Ions [In4Bi5]3-, [InBi3]2-, and [GaBi3]2- Li Xu and Slavi C. Sevov pp 5383 - 5389; DOI: 10.1021/ic000925f |
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Spin Crossover Bistability in Three Mutually Perpendicular Interpenetrated (4,4) Nets Nicolás Moliner, Carmen Muñoz, Sylvie Létard, Xavier Solans, Nieves Menéndez, Antoine Goujon, François Varret, and José Antonio Real pp 5390 - 5393; DOI: 10.1021/ic0005588 |
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Hybrid Molecular Materials Based upon the Photochromic Nitroprusside Complex, [Fe(CN)5NO]2-, and Organic -Electron Donors. Synthesis, Structure, and Properties of the Radical Salt (TTF)7[Fe(CN)5NO]2 (TTF = Tetrathiafulvalene) M. Clemente-León, E. Coronado, J. R. Galán-Mascarós, C. J. Gómez-García, and E. Canadell pp 5394 - 5397; DOI: 10.1021/ic0002566 |
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Gas-Phase Structure of Hexakis(trifluoromethyl)- cyclotriphosphazene, [(CF3)2PN]3 Frank Trautner, Rajendra Prasad Singh, Robert L. Kirchmeier, Jean'ne M. Shreeve, and Heinz Oberhammer pp 5398 - 5399; DOI: 10.1021/ic000504y |
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Synthesis and Structure of Dimeric [(cis-Py3Im)M]2 Complexes [M = Ni, Cu, Zn; (cis-Py3Im) = cis-2,4,5-Tri(2-pyridyl)imidazoline] Miguel Parra-Hake, Martin L. Larter, Peter Gantzel, Gerardo Aguirre, Fernando Ortega, Ratnasamy Somanathan, and Patrick J. Walsh pp 5400 - 5403; DOI: 10.1021/ic000182y |
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Observation of a Large Coupling of a Bound Dihydrogen Ligand to Phosphorus Ligands in trans-[(dppe)2Ru(2-H2)(PF(OMe)2)][BF4]2 Complex Nisha Mathew and Balaji R. Jagirdar pp 5404 - 5406; DOI: 10.1021/ic000419q |
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Alkylpyridine Complexes of Tungsten(II) and Chromium(II). First Rotational Isomers of W2X4L4 Molecules with D2h and D2 Symmetries F. Albert Cotton, Evgeny V. Dikarev, Jiande Gu, Santiago Herrero, and Barbara Modec pp 5407 - 5411; DOI: 10.1021/ic000555v |
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Hydrogenolysis of a Ruthenium Carbene Complex to Yield Dihydride-Dihydrogen Tautomers: Mechanistic Implications for Tandem ROMP-Hydrogenation Catalysis Samantha D. Drouin, Glenn P. A. Yap, and Deryn E. Fogg pp 5412 - 5414; DOI: 10.1021/ic000102q |
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Ultraviolet Photochemistry of Co S. C. Gibney, G. Ferraudi, and M. Shang pp 5414 - 5414; DOI: 10.1021/ic001047o |
Issue 24
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Aqueous Preparation of Highly Dispersed Molybdenum Sulfide I. Bezverkhy, P. Afanasiev, and M. Lacroix pp 5416 - 5417; DOI: 10.1021/ic000627i |
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Hydrophobic Interactions in Metalloporphyrin-Peptide Complexes David L. Huffman and Kenneth S. Suslick pp 5418 - 5419; DOI: 10.1021/ic990405o |
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Nickel Phosphate Based Zeotype, RbNiPO4 Paul F. Henry, Mark T. Weller, and Robert W. Hughes pp 5420 - 5421; DOI: 10.1021/ic000712q |
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Arsenic(III)-Cysteine Interactions Stabilize Three-Helix Bundles in Aqueous Solution Brian T. Farrer, Craig P. McClure, James E. Penner-Hahn, and Vincent L. Pecoraro pp 5422 - 5423; DOI: 10.1021/ic0010149 |
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N-Confused Double-Decker Porphyrins Hiroyuki Furuta, Naoko Kubo, Hiromitsu Maeda, Tomoya Ishizuka, Atsuhiro Osuka, Hideki Nanami, and Takuji Ogawa pp 5424 - 5425; DOI: 10.1021/ic0010048 |
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First Synthesis and Structures of Aryltellurium(IV) Diazides Thomas M. Klapötke, Burkhard Krumm, Peter Mayer, and Oliver P. Ruscitti pp 5426 - 5427; DOI: 10.1021/ic000810b |
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Facile Synthesis of Stacked, Heteronuclear Porphyrin Arrays with Varied Architectures Michael Harmjanz and Michael J. Scott pp 5428 - 5429; DOI: 10.1021/ic0010656 |
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Bridged Silver(I) Complexes of the Polycyclic Aromatic Compounds Tetraphenylethylene and 1,1,4,4-Tetraphenyl-1,3-butadiene Ichiro Ino, Liang Ping Wu, Megumu Munakata, Takayoshi Kuroda-Sowa, Masahiko Maekawa, Yusaku Suenaga, and Ryusuke Sakai pp 5430 - 5436; DOI: 10.1021/ic000263u |
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Chiral Ferrocene Amines Derived from Amino Acids and Peptides: Synthesis, Solution and X-ray Crystal Structures and Electrochemical Investigations Alexandra Hess, Jan Sehnert, Thomas Weyhermüller, and Nils Metzler-Nolte pp 5437 - 5443; DOI: 10.1021/ic000089+ |
Characterization of the Sterically Encumbered Terphenyl-Substituted Species 2,6-Trip2H3C6 n-Sn(Me)2C6H3-2,6-Trip2, an Unsymmetric, Group 14 Element, Methylmethylene, Valence Isomer of an Alkene, Its Related Lithium Derivative 2,6-Trip2H3C6(Me)2Sn-Sn(Li)(Me)C6H3-2,6-Trip2, and the Monomer Sn(t-Bu)C6H3-2,6-Trip2 (Trip = C6H2-2,4,6-i-Pr3)Barrett E. Eichler and Philip P. Power pp 5444 - 5449; DOI: 10.1021/ic0005137 |
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Solid-State and High-Resolution Liquid 119Sn NMR Spectroscopy of Some Monomeric, Two-Coordinate Low-Valent Tin Compounds: Very Large Chemical Shift Anisotropies Barrett E. Eichler, Brian L. Phillips, Philip P. Power, and Matthew P. Augustine pp 5450 - 5453; DOI: 10.1021/ic000514z |
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A Simple Copper(II)-L-Histidine System for Efficient Hydrolytic Cleavage of DNA Rui Ren, Pin Yang, Weijuan Zheng, and Zichun Hua pp 5454 - 5463; DOI: 10.1021/ic0000146 |
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A Trigonal Bipyramidal Uranyl Amido Complex: Synthesis and Structural Characterization of [Na(THF)2][UO2(N(SiMe3)2)3] Carol J. Burns, David L. Clark, Robert J. Donohoe, Paul B. Duval, Brian L. Scott, and C. Drew Tait pp 5464 - 5468; DOI: 10.1021/ic0003168 |
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Studies on the Mechanism of the Reaction between Coenzyme B12 and Cyanide: Direct 1H NMR Spectroscopic Evidence for a (-5'-Deoxyadenosyl)(-cyano)cobalamin Intermediate Nicola E. Brasch and Rebecca J. Haupt pp 5469 - 5474; DOI: 10.1021/ic000532g |
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Copper(II) Complexes of Inverted Porphyrin and Its Methylated Derivatives Piotr J. Chmielewski, Lechos aw Latos-Grayski, and Izabela Schmidtpp 5475 - 5482; DOI: 10.1021/ic000051x |
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Macrocycle-Supported Titanium Complexes with Chelating Imido Ligands: Analogues of ansa-Metallocenes Nigel A. H. Male, Michael E. G. Skinner, Sergei Y. Bylikin, Paul J. Wilson, Philip Mountford, and Martin Schröder pp 5483 - 5491; DOI: 10.1021/ic9910357 |
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(Schiff Base) Divalent Group 14 Element Species: Manganese and Iron Complexes (Salen)M=Mn(CO)2(5-C5H5) (M14 = Ge, Sn, Pb) and (Salen)Sn=Fe(CO)4 Dominique Agustin, Ghassoub Rima, Heinz Gornitzka, and Jacques Barrau pp 5492 - 5495; DOI: 10.1021/ic9915045 |
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Photophysics and Electron Transfer in Poly(3-octylthiophene) Alternating with Ru(II)- and Os(II)-Bipyridine Complexes Keith A. Walters, Lise Trouillet, Stéphane Guillerez, and Kirk S. Schanze pp 5496 - 5509; DOI: 10.1021/ic000661x |
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Novel Square Planar Copper(II) Complexes with Imino or Nitronyl Nitroxide Radicals Exhibiting Large Ferro- and Antiferromagnetic Interactions André Cogne, Jean Laugier, Dominique Luneau, and Paul Rey pp 5510 - 5514; DOI: 10.1021/ic0005590 |
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Synthesis, Structure, and Magnetic Properties of the Low-Symmetry Tetranuclear Cubane-like Nickel Complex [Ni4(pypentO)(pym)(3-OH)2(-Oac)2(NCS)2(OH2)] Juan M. Clemente-Juan, Benoît Chansou, Bruno Donnadieu, and Jean-Pierre Tuchagues pp 5515 - 5519; DOI: 10.1021/ic0005442 |
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A Gold(I) Mononuclear Complex and Its Association into Binuclear and Cluster Compounds by Hydrogen Bonding or Metal Ion Coordination Leijun Hao, M. Adnan Mansour, Rene J. Lachicotte, Henry J. Gysling, and Richard Eisenberg pp 5520 - 5529; DOI: 10.1021/ic000396f |
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Structural and Functional Characteristics of Rhenium Clusters Derived from Redox Chemistry of the Triangular [ReIII3(-Cl)3] Core Unit Daniel Neuman, Patrina Paraskevopoulou, Nikos Psaroudakis, Konstantinos Mertis, Richard J. Staples, and Pericles Stavropoulos pp 5530 - 5537; DOI: 10.1021/ic000449t |
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Zirconium and Hafnium Hydrogen Monothiophosphates, H2Zr(PO3S)2 and H2Hf(PO3S)2. Syntheses and Selective Ion-Exchange Properties of Sulfur-Containing Analogues of H2M(PO4)2 (M = Zr, Hf) Alexander E. Gash, Peter K. Dorhout, and Steven H. Strauss pp 5538 - 5546; DOI: 10.1021/ic990775c |
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Can Octahedral t2g6 Complexes Substitute Associatively? The Case of the Isoelectronic Ruthenium(II) and Rhodium(III) Hexaaquaions David De Vito, Helena Sidorenkova, François P. Rotzinger, Jacques Weber, and André E. Merbach pp 5547 - 5552; DOI: 10.1021/ic0008262 |
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Three- and Four-Center Trans Effects in Triply Bonded Ditungsten Complexes: An ab Initio Molecular Dynamics Study of Compounds with Stoichiometry W2Cl4(NHEt)2(PMe3)2 Alessandra Magistrato, Joost VandeVondele, and Ursula Rothlisberger pp 5553 - 5560; DOI: 10.1021/ic000754e |
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Synthesis of an Se-Bridged Triiron Acyl Cluster Complex and the Fischer-Type Carbene Complex Derived from It: Isolation of Rotational Isomers Minghuey Shieh, Horng-Sun Chen, Hsin-Hung Chi, and Chuen-Her Ueng pp 5561 - 5564; DOI: 10.1021/ic000301+ |
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A New Cylindrical, Six-Membered Iron(III) Inclusion Cluster Consisting of Three Oxo-Bridged Diiron Subunits Linked by Carboxylate Bridges Thorsten Schneppensieper, Günter Liehr, Rudi van Eldik, Jürgen Ensling, and Philipp Gütlich pp 5565 - 5568; DOI: 10.1021/ic000108f |
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Dihydrobis(4-cyanopyrazol-1-yl)borate, [Bp4CN], a Functionalized Heteroscorpionate Ligand with Cross-Linking Potential Arnold L. Rheingold, Christopher D. Incarvito, and Swiatoslaw Trofimenko pp 5569 - 5571; DOI: 10.1021/ic000482f |
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Effect of Anionic Axial Ligands on the Formation of Oxoiron(IV) Porphyrin Intermediates Wonwoo Nam, Mi Hee Lim, and So-Young Oh pp 5572 - 5575; DOI: 10.1021/ic000502d |
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RhII-RhII Bond Homolysis in a [(salen)RhII]2 Derivative: Thermodynamic, Kinetic, and Reactivity Studies Andrew G. Bunn, Yaping Ni, Mingli Wei, and Bradford B. Wayland pp 5576 - 5578; DOI: 10.1021/ic000647k |
Issue 25
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Syntheses and Structures of Mg(C5H5BMe)2, Mg(3,5-Me2C5H3BNMe2)2, the 2,2'-Bipyridine Adduct Mg(C5H5BMe)2(bipy), and the N-Bonded Aminoboratabenzene Species Mg(3,5-Me2C5H3BNMe2)2(THF)2 Xiaolai Zheng, Ulli Englert, Gerhard E. Herberich, and Jörg Rosenplänter pp 5579 - 5585; DOI: 10.1021/ic000575x |
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Gas-Phase Reactions of Chromium and Chromium Fluoride Cations CrFn+ (n = 0-4) with Phosphane Ulf Mazurek and Helmut Schwarz pp 5586 - 5590; DOI: 10.1021/ic000318s |
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Kinetics and Mechanism of Iron(III) Dissociation from the Dihydroxamate Siderophores Alcaligin and Rhodotorulic Acid Hakim Boukhalfa, Timothy J. Brickman, Sandra K. Armstrong, and Alvin L. Crumbliss pp 5591 - 5602; DOI: 10.1021/ic000330k |
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Slowing of Cisplatin Aquation in the Presence of DNA but Not in the Presence of Phosphate: Improved Understanding of Sequence Selectivity and the Roles of Monoaquated and Diaquated Species in the Binding of Cisplatin to DNA Murray S. Davies, Susan J. Berners-Price, and Trevor W. Hambley pp 5603 - 5613; DOI: 10.1021/ic000847w |
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Bonding, Structure, and Energetics of Gaseous E82+ and of Solid E8(AsF6)2 (E = S, Se) T. Stanley Cameron, Robert J. Deeth, Isabelle Dionne, Hongbin Du, H. Donald B. Jenkins, Ingo Krossing, Jack Passmore, and Helen K. Roobottom pp 5614 - 5631; DOI: 10.1021/ic990760e |
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Insertion of CO2, CS2, and COS into Iron(II)-Hydride Bonds Leslie D. Field, Eric T. Lawrenz, Warren J. Shaw, and Peter Turner pp 5632 - 5638; DOI: 10.1021/ic991399z |
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Reactions of Nickel(II) 2,21-Dimethyl-2-aza-21-carbaporphyrin with Phenyl Grignard Reagents, Phenyllithium, and n-Butyllithium Piotr J. Chmielewski and Lechos aw Latos-Grayskipp 5639 - 5647; DOI: 10.1021/ic000052p |
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Synthesis and Characterization of a Series of Zinc Bis[(alkyl)(trimethylsilyl)amide] Compounds David A. Gaul, Oliver Just, and William S. Rees, Jr. pp 5648 - 5654; DOI: 10.1021/ic000234j |
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Sulfosalts with Alkaline Earth Metals. Centrosymmetric vs Acentric Interplay in Ba3Sb4.66S10 and Ba2.62Pb1.38Sb4S10 Based on the Ba/Pb/Sb Ratio. Phases Related to Arsenosulfide Minerals of the Rathite Group and the Novel Polysulfide Sr6Sb6S17 Kyoung-Shin Choi and Mercouri G. Kanatzidis pp 5655 - 5662; DOI: 10.1021/ic000632m |
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Structural, Magnetic, and Ion-Exchange Properties of a New Layered Alkaline/Alkaline Earth Iron Phosphate: NaBaFe4(HPO4)3(PO4)3·H2O Michael B. Korzenski and Joseph W. Kolis pp 5663 - 5668; DOI: 10.1021/ic0001513 |
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Cationic Re(V) Oxo Complexes with Poly(pyrazolyl)borates: Synthesis, Characterization, and Stability António Paulo, Ângela Domingos, Raquel Garcia, and Isabel Santos pp 5669 - 5674; DOI: 10.1021/ic000481n |
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Corroles with Group 15 Ions. 2. Synthesis and Characterization of Octaethylcorroles Containing a Phosphorus Central Atom Karl M. Kadish, Zhongping Ou, Victor A. Adamian, Roger Guilard, Claude P. Gros, Christoph Erben, Stefan Will, and Emanuel Vogel pp 5675 - 5682; DOI: 10.1021/ic0010196 |
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Synthesis and Structure of Cyclic Phosphate, Phosphoramidate, Phosphonates, and Phosphonium Salts. Phosphatrane Formation A. Chandrasekaran, Roberta O. Day, and Robert R. Holmes pp 5683 - 5689; DOI: 10.1021/ic000467a |
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Metal-Metal and Metal-Ligand Vibrational Interaction in Compounds of the Fe3EE'(CO)9 (E, E' = S, Se, Te) Series and the Low-Frequency Vibrational Spectra of Co2FeS(CO)9 and Os3S2(CO)9 S. F. A. Kettle, E. Diana, R. Rossetti, E. Boccaleri, U. A. Jayasooryia, and P. L. Stanghellini pp 5690 - 5696; DOI: 10.1021/ic991254s |
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Electronic Structure Studies of Oxomolybdenum Tetrathiolate Complexes: Origin of Reduction Potential Differences and Relationship to Cysteine-Molybdenum Bonding in Sulfite Oxidase Rebecca L. McNaughton, A. Alex Tipton, Nick D. Rubie, Rebecca R. Conry, and Martin L. Kirk pp 5697 - 5706; DOI: 10.1021/ic0003729 |
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Silver(I) Complexation of (Poly)aromatic Ligands. Structural Criteria for Depth Penetration into cis-Stilbenoid Cavities S. V. Lindeman, R. Rathore, and J. K. Kochi pp 5707 - 5716; DOI: 10.1021/ic000770b |
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Anomalous Stereochemistry of Pyrazolato-3,5-dicarboxylato-Bridged Dinuclear Chromate(III) Complexes Containing Ethylenediamine-N,N'-dicarboxylates with Entrapped Unstable Conformations: X-ray Structure of Na[Cr2(eddp)(-pzdc)]·6H2O Narumi Sakagami-Yoshida, Masahiro Teramoto, Ayako Hioki, Akira Fuyuhiro, and Sumio Kaizaki pp 5717 - 5724; DOI: 10.1021/ic000361f |
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Synthesis and Reaction of the Novel Complex [AsPh4][OsCl5(H2O)]. X-ray Structure Analysis of [AsPh4][OsCl5(H2O)]·2EtOH and [AsPh4][OsCl5(EtOH)]·EtOH Andrei Maiboroda, Gerd Rheinwald, and Heinrich Lang pp 5725 - 5730; DOI: 10.1021/ic000084c |
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Nature of Cysteine-Based Re(V)=O(N2S2) Radiopharmaceuticals at Physiological pH Ascertained by Investigation of a New Complex with a Meso N2S2 Ligand Having Carboxyl Groups Anti to the Oxo Group Lory Hansen, Shun Hirota, Xiaolong Xu, Andrew T. Taylor, and Luigi G. Marzilli pp 5731 - 5740; DOI: 10.1021/ic000183q |
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Synthesis, Emission, and Electrochemical Properties of Luminescent Dinuclear Zinc(II) Chalcogenolate Complexes. Dynamic 1H NMR Studies and X-ray Crystal Structure of [(bpy)Zn2(SC6H4-Cl-p)(-SC6H4-Cl-p)(-OAc)2] Vivian Wing-Wah Yam, Yung-Lin Pui, and Kung-Kai Cheung pp 5741 - 5746; DOI: 10.1021/ic000688g |
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Syntheses and Relaxation Properties of Mixed Gadolinium Hydroxypyridinonate MRI Contrast Agents Seth M. Cohen, Jide Xu, Emil Radkov, Kenneth N. Raymond, Mauro Botta, Alessandro Barge, and Silvio Aime pp 5747 - 5756; DOI: 10.1021/ic000563b |
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Syntheses of New Ionic Technetium(III) Complexes Containing Four Monodentate Phosphine Ligands. Crystal Structures of trans-[Tc(PMe2Ph)4Cl2]PF6, trans-[Tc(PMe3)4Cl2]BPh4, and trans-[Tc(PMe3)4Cl2]PF6 Fernande D. Rochon and Pi-Chang Kong pp 5757 - 5762; DOI: 10.1021/ic9906454 |
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Diverse Reactivity of Dialkylaluminum Dimesitylboryloxides [(-Mes2BO)AlR2]2. Synthetic and Structural Study Romana Anulewicz-Ostrowska, Sergiusz Luli ski, Janusz Serwatowski, and Kinga Suwiskapp 5763 - 5767; DOI: 10.1021/ic9914286 |
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Salicylaldiminato Derivatives of Cyclotriveratrylene: Flexible Strategy for New Rim-Metalated CTV Complexes D. Scott Bohle and Daniel J. Stasko pp 5768 - 5770; DOI: 10.1021/ic0005240 |
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Self-Assembly of a Diferrous Triple-Stranded Helicate with Bis(2,2'-Bipyridine) Ligands: Thermodynamic and Kinetic Intermediates Nicolas Fatin-Rouge, Sylvie Blanc, Emmanuelle Leize, Alain Van Dorsselaer, Paul Baret, Jean-Louis Pierre, and Anne-Marie Albrecht-Gary pp 5771 - 5778; DOI: 10.1021/ic000229f |
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Quantitative Wavelength-Dependent Photochemistry of the [CpFe(6-ipb)]PF6 (ipb = Isopropylbenzene) Photoinitiator Vladimír Jakúbek and Alistair J. Lees pp 5779 - 5786; DOI: 10.1021/ic000643f |
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Synthesis and Crystal Structure Determination of Some Asymmetrical and Symmetrical CR-Type Macrocyclic Schiff Base Complexes, with a Single Pendant Coordinating 2-Aminoethyl Arm Hassan Keypour, Sadegh Salehzadeh, Robin G. Pritchard, and R. V. Parish pp 5787 - 5790; DOI: 10.1021/ic000511m |
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On the Photochemical Behavior of the [Ru(NH3)4(NO)nicotinamide]3+ Cation and the Relative Stability of Light-Induced Metastable Isonitrosyl Isomers of Ru Complexes Christopher Kim, Irina Novozhilova, M. Scott Goodman, Kimberly A. Bagley, and Philip Coppens pp 5791 - 5795; DOI: 10.1021/ic000583d |
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Syntheses and Structural Characterization of the (OCnOPor) Capped Porphyrins: Co(OC2OPor)·CH2Cl2, Co(OC2OPor)(NO)out·0.46CHCl3, Co(OC3OPor)·CHCl3, and Co(OC3OPor)(MeIm)·3C7H8 Paul G. Jene and James A. Ibers pp 5796 - 5802; DOI: 10.1021/ic0006753 |
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M and P Double Helical Complexes of Copper(I) with Bis-imino Bis-quinoline Enantiomerically Pure Chiral Ligands Valeria Amendola, Luigi Fabbrizzi, Carlo Mangano, Piersandro Pallavicini, Elena Roboli, and Michele Zema pp 5803 - 5806; DOI: 10.1021/ic0005700 |
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Linkage and Redox Isomerism in Ruthenium Complexes of Catecholate, Semiquinone, and o-Acylphenolate Ligands Derived from 1,2-Dihydroxy-9,10-anthracenedione (Alizarin) and Related Species: Syntheses, Characterizations, and Photophysics Melvyn Rowen Churchill, Kim M. Keil, Frank V. Bright, Siddharth Pandey, Gary A. Baker, and Jerome B. Keister pp 5807 - 5816; DOI: 10.1021/ic000529x |
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Carboxymethylation of Cage Amines: Control of Alkylation by Metal Ion Coordination Paul S. Donnelly, Jack M. Harrowfield, Brian W. Skelton, and Allan H. White pp 5817 - 5830; DOI: 10.1021/ic000346a |
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Mechanism for the Reduction of the Mixed-Valent MnIIIMnIV[2-OHsalpn]2+ Complex by Tertiary Amines M. Tyler Caudle and Vincent L. Pecoraro pp 5831 - 5837; DOI: 10.1021/ic000727o |
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Synthesis, Characterization, and Reactivity of Ferrous and Ferric Oxo/Peroxo Pivalate Complexes in Relation to Gif-Type Oxygenation of Substrates Remle Çelenligil-Çetin, Richard J. Staples, and Pericles Stavropoulos pp 5838 - 5846; DOI: 10.1021/ic000261+ |
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Hg3AsE4X (E = S, Se; X = Cl, Br, I), a Family of Isotypic Compounds with an Acentric, Layered Structure Johannes Beck, Sylvia Hedderich, and Klaus Köllisch pp 5847 - 5850; DOI: 10.1021/ic0003527 |
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Weakly Coordinating Nature of a Carborane Cage Bearing Different Halogen Atoms. Synthesis and Structural Characterization of Icosahedral Mixed Halocarborane Anions, 1-H-CB11Y5X6- (X, Y = Cl, Br, I) Chi-Wing Tsang, Qingchuan Yang, Eric Tung-Po Sze, Thomas C. W. Mak, Dominic T. W. Chan, and Zuowei Xie pp 5851 - 5858; DOI: 10.1021/ic000354r |
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Re(V) Complexes with an Open-Chain Quadridentate Ligand Containing Two Amine and Two Amido Donors. Synthesis, Characterization, and Solution Equilibria of Re2O3(dioxo-tetH4)2 and [ReO(H2O)(dioxo-tetH4)]Cl (dioxo-tetH6 = 1,4,8,11-tetraazaundecane-5,7-dione) Lory Hansen, Yaroslaw D. Lampeka, Sergey P. Gavrish, Xiaolong Xu, Andrew T. Taylor, and Luigi G. Marzilli pp 5859 - 5866; DOI: 10.1021/ic000173p |
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Iron(II) Triflate Salts as Convenient Substitutes for Perchlorate Salts: Crystal Structures of [Fe(H2O)6](CF3SO3)2 and Fe(MeCN)4(CF3SO3)2 Karl S. Hagen pp 5867 - 5869; DOI: 10.1021/ic000444w |
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One-Dimensional Assemblies of Dirhodium Units Bridged by N,N'-Dicyanoquinonediimine Ligands Hitoshi Miyasaka, Cristian S. Campos-Fernández, José Ramón Galán-Mascarós, and Kim R. Dunbar pp 5870 - 5873; DOI: 10.1021/ic0007097 |
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Supramolecular Aggregates of Complex Cations via Unusual Purine-Purine Base Pairing in a New Organorhodium(III) Compound Containing the Antileukemic Drug Purine-6-thione. Synthesis, X-ray Structure of trans(C,N7),trans(S,S),trans(P,N7)-[Rh(C6H5)(H1,H9- H2tp)2(PPh3)][Rh(C6H5)(H1,H9-H2tp)(H9- Htp)(PPh3)]Cl3·HCl·6H2O, and Density Functional Analysis of the {H2tp···Htp}- Base Pair Renzo Cini, Maddalena Corsini, and Alessandro Cavaglioni pp 5874 - 5878; DOI: 10.1021/ic000814g |
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Halogenation and Alkylation at a MoIII2(-S) Site. Crystal Structure of the Metal-Sulfenyl Halide Complex [Mo2(5-C5Me5)2(-SMe)2(-SI)(CO)2]I5 P. Schollhammer, F. Y. Pétillon, J. Talarmin, K. W. Muir, H. K. Fun, and K. Chinnakali pp 5879 - 5882; DOI: 10.1021/ic000591u |
Issue 26
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Thank You M. Frederick Hawthorne pp 5883 - 5883; DOI: 10.1021/ic001324r |
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Dioxygen-Binding Kinetics and Thermodynamics of a Series of Dicopper(I) Complexes with Bis[2-(2-pyridyl)ethyl]amine Tridendate Chelators Forming Side-On Peroxo-Bridged Dicopper(II) Adducts Hong-Chang Liang, Kenneth D. Karlin, Raylene Dyson, Susan Kaderli, Bernhard Jung, and Andreas D. Zuberbühler pp 5884 - 5894; DOI: 10.1021/ic0007916 |
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Synthesis, Characterization, and Structural and Theoretical Analysis of Gd4B3C4: A Novel Rare Earth Metal Borocarbide Containing Two Different Boron-Carbon Arrangements Christophe Jardin, Oliver Oeckler, Hansjürgen Mattausch, Arndt Simon, Jean-François Halet, Jean-Yves Saillard, and Josef Bauer pp 5895 - 5900; DOI: 10.1021/ic000585y |
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X-ray Photoelectron Spectroscopy and Magnetic Studies on the Effect of Pore Size, Wall Thickness, and Wall Composition on Superparamagnetic Cobaltocene Mesoporous Nb, Ta, and Ti Composites S. Murray, M. Trudeau, and D. M. Antonelli pp 5901 - 5908; DOI: 10.1021/ic000678f |
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Crystal Structures of Two Polymorphs of Ca3[Al2N4] M. Ludwig, J. Jäger, R. Niewa, and R. Kniep pp 5909 - 5911; DOI: 10.1021/ic0002869 |
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Synthesis and Recognition Properties of a Ruthenium(II)-Bis(zinc) Cyclic Porphyrin Trimer Simon J. Webb and Jeremy K. M. Sanders pp 5912 - 5919; DOI: 10.1021/ic000411g |
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A Tin(IV)-Ruthenium(II)-Tin(IV) Cyclic Porphyrin Trimer with Replaceable Chiral Linings Simon J. Webb and Jeremy K. M. Sanders pp 5920 - 5929; DOI: 10.1021/ic0004129 |
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Synthesis and Characterization of A3Na10Sn23 (A = Cs, Rb, K) with a New Clathrate-Like Structure and of the Chiral Clathrate Rb5Na3Sn25 Svilen Bobev and Slavi C. Sevov pp 5930 - 5937; DOI: 10.1021/ic0007714 |
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Structure and Mesomorphism of Neodymium(III) Alkanoates Koen Binnemans, Liesbet Jongen, Claudia Bromant, Dirk Hinz, and Gerd Meyer pp 5938 - 5945; DOI: 10.1021/ic000470u |
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Formation of Ammonia in the Reactions of a Tungsten Dinitrogen with Ruthenium Dihydrogen Complexes under Mild Reaction Conditions Yoshiaki Nishibayashi, Shin Takemoto, Shotaro Iwai, and Masanobu Hidai pp 5946 - 5957; DOI: 10.1021/ic000799f |
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Seven-Coordinate [ReVON4X2]+ Complexes (X = O and Cl) Liang Xu, Ika A. Setyawati, Jason Pierreroy, Maren Pink, Victor G. Young Jr., Brian O. Patrick, Steven J. Rettig, and Chris Orvig pp 5958 - 5963; DOI: 10.1021/ic001273y |
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Synthesis, Reactivity, and X-ray Crystallographic Characterization of Mono-, Di-, and Tetranuclear Palladium(II)-Metalated Species Francisco Estevan, Abel García-Bernabé, Pascual Lahuerta, Mercedes Sanaú, M. Angeles Ubeda, and M. Carmen Ramírez de Arellano pp 5964 - 5969; DOI: 10.1021/ic991053o |
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Bonding Preferences of C2X4-Bridged Bimetallic Transition Metal Complexes of Ti, Cu, and Ag Lisa W. Mire and Dennis S. Marynick pp 5970 - 5975; DOI: 10.1021/ic000778l |
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Characterization of the Ni(III) Intermediate in the Reaction of (1,4,8,11-Tetraazacyclotetradecane)nickel(II) Perchlorate with KHSO5: Implications to the Mechanism of Oxidative DNA Modification Jeffrey N. Stuart, Adrienne L. Goerges, and Jeffrey M. Zaleski pp 5976 - 5984; DOI: 10.1021/ic000572k |
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Lead(II)-Binding Properties of the 5'-Monophosphates of Adenosine (AMP2-), Inosine (IMP2-), and Guanosine (GMP2-) in Aqueous Solution. Evidence for Nucleobase-Lead(II) Interactions Carla P. Da Costa and Helmut Sigel pp 5985 - 5993; DOI: 10.1021/ic0007207 |
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Is Ferromagnetism an Intrinsic Property of the CuII/GdIII Couple? 2. Structures and Magnetic Properties of Novel Trinuclear Complexes with -Phenolato--oximato (Cu-Ln-Cu) Cores (Ln = La, Ce, Gd) Jean-Pierre Costes, Françoise Dahan, and Arnaud Dupuis pp 5994 - 6000; DOI: 10.1021/ic000666u |
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Theoretical Study of Mixed LiLnX4 (Ln = La, Dy; X = F, Cl, Br, I) Rare Earth/Alkali Halide Complexes Cornelis Petrus Groen, Ad Oskam, and Attila Kovács pp 6001 - 6008; DOI: 10.1021/ic000581t |
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Computational Study of Analogues of the Uranyl Ion Containing the -N=U=N- Unit: Density Functional Theory Calculations on UO22+, UON+, UN2, UO(NPH3)3+, U(NPH3)24+, [UCl4{NPR3}2] (R = H, Me), and [UOCl4{NP(C6H5)3}]- Nikolas Kaltsoyannis pp 6009 - 6017; DOI: 10.1021/ic000891b |
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Defining Chemical Species in Complex Environments Using K-Edge X-ray Absorption Spectroscopy: Vanadium in Intact Blood Cells and Henze Solution from the Tunicate Ascidia ceratodes Patrick Frank and Keith O. Hodgson pp 6018 - 6027; DOI: 10.1021/ic000546m |
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The First Noncoordinated Phosphonium Diylide, [Me2P(C13H8)2]-, and Its Ylidic and Cationic Counterparts: Synthesis, Structural Characterization, and Interaction with the Heavy Group 2 Metals Erik D. Brady, Timothy P. Hanusa, Maren Pink, and Victor G. Young, Jr. pp 6028 - 6037; DOI: 10.1021/ic000838n |
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Structural Aspects, IR Study, and Molecular Photophysics of the Cumulene-Bridged Complexes with Rhenium(I), Ruthenium(II), and Osmium(II) Centers Jeffrey V. Ortega, Kay Khin, Wytze E. van der Veer, Joseph Ziller, and Bo Hong pp 6038 - 6050; DOI: 10.1021/ic0006910 |
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Selective Diphosphine Ligand Chelation and Bond Coordination in CoRu(CO)7(-PPh2): Kinetics and X-ray Structure of CoRu(CO)4(-bma)(-PPh2) Simon G. Bott, Kaiyuan Yang, Jian Cheng Wang, and Michael G. Richmond pp 6051 - 6055; DOI: 10.1021/ic991279r |
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A New Inorganic-Organic Hybrid Iron(III) Arsenate: (C2H10N2)[Fe(HAsO4)2(H2AsO4)](H2O). Hydrothermal Synthesis, Crystal Structure, and Spectroscopic and Magnetic Properties Begoña Bazán, José L. Mesa, José L. Pizarro, L. Lezama, María I. Arriortua, and Teófilo Rojo pp 6056 - 6060; DOI: 10.1021/ic000835a |
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The H93G Myoglobin Cavity Mutant as a Versatile Template for Modeling Heme Proteins: Ferrous, Ferric, and Ferryl Mixed-Ligand Complexes with Imidazole in the Cavity Alycen E. Pond, Mark P. Roach, Melissa R. Thomas, Steven G. Boxer, and John H. Dawson pp 6061 - 6066; DOI: 10.1021/ic0007198 |
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Isolation and Structural Characterization of Triethanolaminotitanatranes: X-ray Structures of Partial Hydrolysis Condensates Tim Kemmitt, Najeh I. Al-Salim, and Graeme J. Gainsford pp 6067 - 6071; DOI: 10.1021/ic000510u |
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Syntheses and Crystal Structures of "Unligated" Copper(I) and Copper(II) Trifluoroacetates F. Albert Cotton, Evgeny V. Dikarev, and Marina A. Petrukhina pp 6072 - 6079; DOI: 10.1021/ic000663h |
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Ethanol Oxidation by Imidorhenium(V) Complexes: Formation of Amidorhenium(III) Complexes Annette L. Suing, Charlotte R. Dewan, Peter S. White, and H. Holden Thorp pp 6080 - 6085; DOI: 10.1021/ic0007299 |
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N-Donor Effects on Carboxylate Binding in Mononuclear Iron(II) Complexes of a Sterically Hindered Benzoate Ligand John R. Hagadorn, Lawrence Que, Jr., and William B. Tolman pp 6086 - 6090; DOI: 10.1021/ic000531o |
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Synthesis and Structure of a Complex Having a Quartet Ground State with Three Entirely Different Spin Carriers: Nitronyl Nitroxide, o-Semiquinone, and CuII David A. Shultz, Scot H. Bodnar, Kira E. Vostrikova, and Jeff W. Kampf pp 6091 - 6093; DOI: 10.1021/ic0009122 |
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Reduction of Inner Sulfonium Salts, Thioethers, and Sulfones Derived from closo-[B12H12]2- by Lithium in Methylamine: A New Route to Mercaptododecaborates Roman G. Kultyshev, Shengming Liu, and Sheldon G. Shore pp 6094 - 6099; DOI: 10.1021/ic0011011 |
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2-Pyrrolylthiones as Monoanionic Bidentate N,S-Chelators: Synthesis and Molecular Structure of 2-Pyrrolylthionato Complexes of Nickel(II), Cobalt(III), and Mercury(II) Christian Brückner, Steven J. Rettig, and David Dolphin pp 6100 - 6106; DOI: 10.1021/ic0004636 |
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Organic-Inorganic Perovskites Containing Trivalent Metal Halide Layers: The Templating Influence of the Organic Cation Layer David B. Mitzi pp 6107 - 6113; DOI: 10.1021/ic000794i |
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Structure-Reactivity Relationships among Metallothionein Three-Metal Domains: Role of Non-Cysteine Amino Acid Residues in Lobster Metallothionein and Human Metallothionein-3 Amalia Muñoz, David H. Petering, and C. Frank Shaw, III pp 6114 - 6123; DOI: 10.1021/ic000485s |
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Influence of Deuteration on the Crystal Structure of (NH4)2[Zn(H2O)6](SO4)2 Charles J. Simmons, Michael A. Hitchman, and Horst Stratemeier pp 6124 - 6126; DOI: 10.1021/ic000536l |
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{TpRe(bpy)}: A Novel Pentaaminerhenium System That Stabilizes Both High and Low Oxidation States (Tp = Hydridotris(pyrazolyl)borate; bpy = 2,2'-Bipyridyl) T. Brent Gunnoe, Scott H. Meiere, Michal Sabat, and W. Dean Harman pp 6127 - 6130; DOI: 10.1021/ic000707m |
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Effect of Ring Size on Coordination Properties of trans-1,2-Cycloalkanediamine Ligands: Synthesis of Dinuclear Platinum(II) Complexes as Potential DNA Cross-Linkers Sandrine Ongeri, David J. Aitken, Henri-Philippe Husson, Ji  í Kozelka, and Bernard Viossatpp 6131 - 6133; DOI: 10.1021/ic000334p |
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Formation and Structure of the Oxygen-Centered Lead Thiolate Cluster Pb5O(SRF)8·2C7H8 [RF = 2,4,6-Tris(trifluoromethyl)phenyl] Frank T. Edelmann, Jan-Karel F. Buijink, Sally A. Brooker, Regine Herbst-Irmer, Ulrike Kilimann, and Frank M. Bohnen pp 6134 - 6135; DOI: 10.1021/ic000219e |
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New Series CrLn8Te13Cl (Ln = Sm, Gd, Tb): Pseudo-Misfit-Layer Compounds Olivier Tougait and James A. Ibers pp 6136 - 6138; DOI: 10.1021/ic000817t |
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The Anation by Oxalate and Isomerization of cis- and trans-[Co(en)2(OH2)OH]2+ D. A. Buckingham, C. R. Clark, and G. M. Miskelly pp 6139 - 6141; DOI: 10.1021/ic000220d |
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Synthesis, Crystal Structure, and Magnetic Properties of a One-Dimensional Polymeric Copper(II) Complex Containing an Unusual 1,1'-Bicoordinated Oxalato Bridge Oscar Castillo, Antonio Luque, Jon Sertucha, Pascual Román, and Francesc Lloret pp 6142 - 6144; DOI: 10.1021/ic000543+ |
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Ligand Substitution Behavior of a Simple Model for Coenzyme B12 Mohamed S. A. Hamza, Carlos Dücker-Benfer, and Rudi van Eldik: pp 6145 - 6145; DOI: 10.1021/ic001134g |
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Electronic Structures of M21S8 (M = Nb, Zr) and M,M, = Hf, Ti; Nb, Ta) Phases and Reasons for Variations in the Metal Site Occupations Martin Köckerling and Enric Canadell pp 6145 - 6145; DOI: 10.1021/ic0011718 |